Photocatalysis Using 2d Nanomaterials

Two-dimensional (2D) materials for photocatalytic applications have attracted attention in recent years due to their unique thickness-dependent physiochemical properties. 2D materials offer enhanced functionality over traditional three-dimensional (3D) photocatalysts due to modified chemical composition and electronic structures, as well as abundant surface active sites. This book reviews the applications of 2D-related nano-materials in solar-driven catalysis, providing an up-to-date introduction to the design and use of 2D-related photo(electro)catalysts. This includes not only application areas such as fine chemicals synthesis, water splitting, CO2 reduction, and N2 fixation, but also catalyst design and preparation. Some typical 2D and 2D-related materials (such as layered double hydroxides (LDHs), layered metal oxides, transition metal dichalcogenide (TMDs), metal–organic frameworks (MOFs), graphene, g-C3N4, etc.) are classified, and relationships between structure and property are demonstrated, with emphasis on how to improve 2D-related materials performance for practical applications. While the focus of this book will primarily be on experimental studies, computational results will serve as a necessary reference. With chapters written by expert researchers in their fields, Photocatalysis Using 2D Nanomaterials will provide advanced undergraduates, postgraduates and other researchers convenient introductions to these topics.

This book provides much-needed reviews of fast-developing areas of 2D-related photo(electro)catalytic materials.

This book explains the basic and fundamental aspects of nanotechnology and the potential use of nanostructured photocatalysts in various applications, especially in the context of the environment and energy harvesting. It describes the preparation and characterization of unique nanostructured photocatalysts and provides details of their catalytic action, and also discusses the design of new types of photocatalysts with controlled nanostructures. Given its broad scope, the book will appeal to academic and industrial researchers interested in heterogeneous photocatalysis, sustainable chemistry, energy conversion and storage, nanotechnology, chemical engineering, environmental protection, optoelectronics, sensors and surface and interface science.

This book focuses on recent developments in the field of two-dimensional nanomaterials for environmental applications. Due to their high surface area and tunable surface chemistry, two-dimensional nanomaterials are currently garnering great interest for environmental remediation applications. This book compiles contributed chapters from active international researchers dealing with the development of state-of-the-art two-dimensional nanomaterials in environmental applications such as water and wastewater treatment, adsorption, photocatalysis, membrane separation, desalination, deionization, environmental pollutants sensing/detection, carbon-dioxide capture and catalytic conversion, microbial treatment, and electrochemical remediation. Each chapter provides an essential and comprehensive overview of the recent advances in material development and application, giving special attention to preparation methods, tunning of physiochemical properties, surface and interface chemistry, structural porosity, assemblies integration for fabrication of devices, and their relationship with overall efficiency. It offers a valuable reference guide for environmental and materials scientists, engineers, and policymakers working towards environmental sustainability.

Covering the fundamentals, properties, and applications, all aspects of 2D nanomaterial composites within carbon dioxide conversion are discussed. This book will be of interest to graduate students and researchers in materials science, energy, and environmental science, as well as those in industry.

Inorganic 2D nanomaterials, or inorganic graphene analogues, are gaining great attention due to their unique properties and potential energy applications. They contain ultrathin nanosheet morphology with one-dimensional confinement, but unlike pure carbon graphene, inorganic two-dimensional nanomaterials have a more abundant elemental composition and can form different crystallographic structures. These properties contribute to their unique chemical reaction activity, tunable physical properties and facilitate applications in the field of energy conversion and storage. Inorganic Two-dimensional Nanomaterials details the development of the nanostructures from computational simulation and theoretical understanding to their synthesis and characterization. Individual chapters then cover different applications of the materials as electrocatalysts, flexible supercapicitors, flexible lithium ion batteries and thermoelectrical devices. The book provides a comprehensive overview of the field for researchers working in the areas of materials chemistry, physics, energy and catalysis.

Chalcogenide-Based Nanomaterials as Photocatalysts deals with the different types of chalcogenide-based photocatalytic reactions, covering the fundamental concepts of photocatalytic reactions involving chalcogenides for a range of energy and environmental applications. Sections focus on nanostructure control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of chalcogenide-based nanomaterials. The book offers guidelines for designing new chalcogenide-based nanoscale photocatalysts at low cost and high efficiency for efficient utilization of solar energy in the areas of energy production and environment remediation. Provides information on the development of novel chalcogenide-based nanomaterials Outlines the fundamentals of chalcogenides-based photocatalysis Includes techniques for heterogeneous catalysis based on chalcogenide-based nanomaterials

Since the discovery of graphene, two-dimensional nanomaterials including Transition metal dichalcogenides (TMDCs), Hexagonal Boron Nitride (hBN), non-layered compounds, black phosphorous, and Xenes with large lateral dimensions, have emerged as promising candidates for heterogenous electrocatalysis owing to their exceptional physical, chemical, and electronic properties. The tremendous opportunities of using 2D nanomaterials in electrochemical CO2 reduction arises from their unique properties and vast number of applications. Covering the fundamentals, properties, and applications, all aspects of 2D nanomaterial composites within carbon dioxide conversion are discussed. The industrial scale-up and new challenges that exist in the field of electrochemical reduction of carbon dioxide will also be presented. With chapters written by internationally recognized researchers, this state-of-the-art overview will serve the growing interest amongst academic and industrial researchers in understanding 2D nanomaterials composites, their hidden interfaces and nanoscale dispersion of the metal oxide with nanocomposites for specific uses in carbon dioxide conversion to chemicals for fuel applications. This book will be of interest to graduate students and researchers in materials science, energy, and environmental science, as well as those in industry.

2D NANOMATERIALS The book provides a comprehensive overview of the synthesis, modification, characterization, and application of 2D nanomaterials. In recent years, 2D nanomaterials have emerged as a remarkable cornerstone in the field of advanced materials research, with their unique properties and versatile applications captivating the attention of scientists and engineers worldwide. This book is a testament to the ever-growing interest and importance of 2D nanomaterials in the realm of materials science, nanotechnology, pharmaceuticals, and a myriad of engineering specializations. The book is structured into three sections, each delving into different aspects of 2D nanomaterials. The first section explores the synthesis of these materials, providing an overview of both top-down and bottom-up strategies. Understanding the methods by which these materials can be synthesized is crucial for advancing their potential applications. Additionally, this section details the structural characterization of 2D nanomaterials, shedding light on their intricate compositions and properties. The second section examines the diverse characteristics exhibited by 2D nanomaterials. From their magnetic and mechanical properties to their electrical, plasmonic, and optical behaviors, these materials possess an array of intriguing attributes that make them highly attractive for a wide range of applications. This section of the book provides a comprehensive understanding of these properties, enabling readers to appreciate the unique potential of 2D nanomaterials. The final section focuses on the applications of 2D nanomaterials, highlighting their use in various fields such as energy, water purification, biomedical applications, multimodal tumor therapy, and supercapacitor technology.

There are only a few discoveries and new technologies in materials science that have the potential to dramatically alter and revolutionize our material world. Discovery of two-dimensional (2D) materials, the thinnest form of materials to ever occur in nature, is one of them. After isolation of graphene from graphite in 2004, a whole other class of atomically thin materials, dominated by surface effects and showing completely unexpected and extraordinary properties, has been created. This book provides a comprehensive view and state-of-the-art knowledge about 2D materials such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMD) and so on. It consists of 11 chapters contributed by a team of experts in this exciting field and provides latest synthesis techniques of 2D materials, characterization and their potential applications in energy conservation, electronics, optoelectronics and biotechnology.