Organic Functional Group Analysis By Gas Chromatography

Organic Functional Group Analysis: Theory and Development attempts to symbolize the growth in functional groups analysis by using handpicked methods. Those methods are positioned to represent as many functional groups as possible. The book begins with the author referencing books about a quantitative organic analysis. Majority of the first few chapters highlight the oximation and carbonyl method, which support portions of Chapter 2 and the book's second half. The book then discusses the hydroxyl, amino, and alkoxysilanes groups. Chapters 3 and 4 showcase the strong analytical advantages in using base catalysis and acid catalysis with the same anhydride, while Chapters 5, 6, and 7 illustrate extremely useful functional group methods that have received impetus from research. The next chapters talk about the quantitative ring opening method and Diels-Alder addition method. Succeeding studies are about various compounds and its relevant subtopics. The text provides a very great reference for undergraduates and postgraduates of chemistry and its affiliated studies.

Gas chromatography continues to be one of the most widely used analytical techniques, since its applications today expand into fields such as biomarker research or metabolomics. This new practical textbook enables the reader to make full use of gas chromatography. Essential fundamentals and their implications for the practical work at the instrument are provided, as well as details on the instrumentation such as inlet systems, columns and detectors. Specialized techniques from all aspects of GC are introduced ranging from sample preparation, solvent-free injection techniques, and pyrolysis GC, to separation including fast GC and comprehensive GCxGC and finally detection, such as GC-MS and element-specific detection. Various fields of application such as enantiomer, food, flavor and fragrance analysis, physicochemical measurements, forensic toxicology, and clinical analysis are discussed as well as cutting-edge application in metabolomics is covered.

Monographs in Organic Functional Group Analysis, Volume 4: The Determination of Organic Peroxides focuses on the analytical chemistry of organic peroxides. The monograph first offers information on the compositions, properties, and reactions of lipid peroxides, polymers, and petrochemicals. The text then reviews the iodometric methods, including choice of solvents, reaction conditions, and titration with thiosulfate. The ferrous ion methods are also discussed. Considerations include choice of reagents and solvents and titration with titanous, dichromate, and mercurous ions. The book also focuses on titrimetric methods, including arsenious, stannous, and titanous methods, titration with anions, and sulfides and mercaptans. Numerical representations are provided. The text puts emphasis on colorimetric and polarographic methods. Polarographic techniques for peroxides; nature and concentration of peroxides; leuco base of methylene blue; and ferrous ions are described. The book also discusses paper, thin-layer, and gas chromatography. The monograph is an important guide for readers interested in the analytical chemistry of organic peroxides.

Brings together practical information previously available only innumerous separate sources. Handbook of Analytical DerivationReactions begins with an overview of analytical derivatizationwith a section on apparatus. Describes analytical derivatizationmethods organized according to the sample to be derivatized.Discussion of methods includes derivative type, reagent, sampletype, reaction, and typical procedure with comments and referencesfor each.

Monographs in Organic Functional Group Analysis, Volume 3: Determination of Carboxylic Functional Groups focuses on the quantitative determination of acid chlorides, esters, carboxylic acids, anhydrides, lactones, and amides. The monograph first takes a look at the determination of carboxylic acids. Countercurrent and electrophoretic separation of organic acids; polarography of organic acids; acid-base equilibrium in non-aqueous media; and titrimetric determination of acids are discussed. The book also examines the determination of acid anhydrides, chlorides, and esters. The characteristics and composition of acid chlorides and anhydrides, as well as the saponification and spectroscopic methods used in the identification of esters, are presented. The book also evaluates the methods and use of Grignard’s reagent in the determination of amides. The text also presents an analysis of binary and ternary mixtures. Mixtures of acids and acid chlorides, differentiation of acids, mixtures of acids and esters, and mixtures of acids and amides are discussed. The monograph is a vital reference for readers interested in the quantitative determination of acid chlorides, esters, carboxylic acids, and other related compounds.

Rapid developments in analytical techniques and the use of modern reagents in organic synthesis during the last two decades have revolutionized the approach to organic structure determination. As advanced topics in organic analysis such as spectroscopic methods are being introduced, postgraduate students (majoring in organic chemistry) have been feeling handicapped by the non-availability of a book that could uncover various aspects of qualitative and quantitative organic analysis. This book is written primarily to stimulate the interest of students of organic chemistry and pharmaceutical sciences in organic analytical chemistry. Key features: Identification and characterization of organic compounds by classical methods Mechanism of various reactions involved in the detection of functional groups and their derivatization Functional groups interfering with a given test procedure Identification of organic compounds by spectral methods (IR, UV, NMR and Mass Spectrometry) Chemical analysis by other instrumental techniques-Atomic emission spectroscopy, Electron spin resonance spectroscopy, Atomic absorption spectroscopy, flnorimetry & Phosphorimetry, Flame photometry and X-ray methods General techniques for separation and purification including Gas Chromatography and HPLC Preparation of organic compounds based on important name reactions and pharmaceutical properties Mechanism of the reactions involved in the synthesis Simple analytical techniques and specific methods of quantitative elemental, functional groups and biochemical estimations Composite spectral problems Incorporating ample modern techniques of organic analysis, this book will be of great value to graduate & postgraduate students, teachers and researchers in the field of organic chemistry and pharmaceutical sciences.