Novel Catalysts for Upgrading Coal-derived Liquids
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Release | : 1993 |
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Release | : 1993 |
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Release | : 1994 |
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Author | : Oklahoma State University. School of Chemical Engineering |
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Total Pages | : 204 |
Release | : 1976 |
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Release | : 1977 |
Genre | : Catalysts |
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Total Pages | : 5 |
Release | : 1993 |
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The principal objective of this research is to evaluate the hydrotreatment properties of [gamma]-Al2O3 supported Mo oxynitride and oxycarbide catalysts. This information will be used to assess the potential of these materials for use as commercial catalysts for hydrotreating coal-derived liquids. During this quarter, the authors evaluated the catalytic properties of a series of supported molybdenum nitride catalysts. These catalysts were prepared in the laboratory for comparison with the supported molybdenum oxynitrides. Pyridine hydrodenitrogenation (HDN) was used as the test reaction.
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Total Pages | : 21 |
Release | : 1995 |
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Research described in this report was aimed at synthesizing and evaluating supported Mo oxynitrides and oxycarbides for the selective removal of nitrogen, sulfur and oxygen from model and authentic coal-derived liquids. The Al2O3-supported oxynitrides and oxycarbides were synthesized via the temperature programmed reaction of supported molybdenum oxides or hydrogen bronzes with NH3 or an equimolar mixture of CH4 and H2. Phase constituents and composition were determined by X-ray diffraction, CHN analysis, and neutron activation analysis. Oxygen chemisorption was used to probe the surface structure of the catalysts. The reaction rate data was collected using specially designed micro-batch reactors. The Al2O3-supported Mo oxynitrides and oxycarbides were competitively active for quinoline hydrodenitrogenation (HDN), benzothiophene hydrodesulfurization (HDS) and benzofuran hydrodeoxygenation (HDO). In fact, the HDN and HDO specific reaction rates for several of the oxynitrides and oxycarbides were higher than those of a commercial Ni-Mo/Al2O3 hydrotreatment catalyst. Furthermore, the product distributions indicated that the oxynitrides and oxycarbides were more hydrogen efficient than the sulfide catalysts. For HDN and HDS the catalytic activity was a strong inverse function of the Mo loading. In contrast, the benzofuran hydrodeoxygenation (HDO) activities did not appear to be affected by the Mo loading but were affected by the heating rate employed during nitridation or carburization. This observation suggested that HDN and HDS occurred on the same active sites while HDO was catalyzed by a different type of site.
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Release | : 1982 |
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Author | : Billy L. Crynes |
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Total Pages | : 191 |
Release | : 1978 |
Genre | : Catalysts |
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Author | : Billy L. Crynes |
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Total Pages | : 30 |
Release | : 1977 |
Genre | : Catalysts |
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Release | : 1994 |
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