Liquid Fuels

In recent years, it has been important for scientists and chemical industries to introduce and develop new liquid fuels as jet fuels and propellants for propulsion purposes. Different aspects should be considered for the selection of a good candidate such as combustion performance, desired physical properties, noncarcinogenic and less toxicity. New synthetic hydrocarbon fuels with favorable combustion performance and physical properties have been considered as desirable jet fuels. They can be used in aircrafts such as military jets because of their higher volumetric energy density. A liquid-propellant rocket uses liquid propellants for propulsion. Liquid propellants should have the desirable properties of high energy density per unit mass, high specific impulse, and short ignition delays. Hypergolic propellants as important classes of liquid propellants are characterized by spontaneous reaction upon fuel and oxidizer mixing and high energy yield. Moreover, they should be relatively ignitable and have a small ignition time delay. This book reviews some efforts that have been done to introduce new candidates to replace conventional hydrazine fuels because they are acutely toxic and suspected carcinogens, costly safety precautions and handling procedures are required. This book reviews the latest advances in liquid fuels, which may be used as jet fuels and liquid propellants. Important properties for assessment of a suitable liquid are demonstrated. This book can be used for graduate students in the field of chemistry and chemical engineering. It may also be useful for scientists and researchers who work on the development of new liquid fuels with high performance as well as those that are noncarcinogenic or have less toxicity.

Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells