Laser Spectroscopy V

The Fifth International Conference on Laser Spectroscopy or VICOLS, was held at Jasper Park Lodge, in Jasper, Canada, June 29 to July 3, 1981. Following the tradition of the previous conferences in Vail, Megeve, Jackson Lake, and Rottach-Egern, it was hoped that VICOLS would provide an opportunity for act ive scientists to meet in an informal atmosphere for discussions of recent developments and applications in laser spectroscopy. The excellent conference facilities and remote location of Jasper Park Lodge in the heart of the Canadian Rockies, amply fulfilled these expectations. The conference was truly international, with 230 scientists from 19 countries participating. The busy program of invited talks lasted four days, with two evening sessions, one a panel discussion on Rydberg state spectro scopy, the other a lively poster session of approximately 60 post-deadline papers. We wish to thank all of the participants for their outstanding contribu tions and for preparation of their papers, now available to a wider audience. Our thanks go to the members of the International Steering Committee for their suggestions and recommendations. We are especially pleased to have held this conference under the auspices of the International Union of Pure and Applied Physics. VICOLS would not have been possible with out the financial support of the Natural Sciences and Engineering Research Council of Canada, and the Office of Naval Research and Air Force Office of Scientific Research of the United States* of America.

With contributions by numerous experts

Principles of Laser Spectroscopy and Quantum Optics is an essential textbook for graduate students studying the interaction of optical fields with atoms. It also serves as an ideal reference text for researchers working in the fields of laser spectroscopy and quantum optics. The book provides a rigorous introduction to the prototypical problems of radiation fields interacting with two- and three-level atomic systems. It examines the interaction of radiation with both atomic vapors and condensed matter systems, the density matrix and the Bloch vector, and applications involving linear absorption and saturation spectroscopy. Other topics include hole burning, dark states, slow light, and coherent transient spectroscopy, as well as atom optics and atom interferometry. In the second half of the text, the authors consider applications in which the radiation field is quantized. Topics include spontaneous decay, optical pumping, sub-Doppler laser cooling, the Heisenberg equations of motion for atomic and field operators, and light scattering by atoms in both weak and strong external fields. The concluding chapter offers methods for creating entangled and spin-squeezed states of matter. Instructors can create a one-semester course based on this book by combining the introductory chapters with a selection of the more advanced material. A solutions manual is available to teachers. Rigorous introduction to the interaction of optical fields with atoms Applications include linear and nonlinear spectroscopy, dark states, and slow light Extensive chapter on atom optics and atom interferometry Conclusion explores entangled and spin-squeezed states of matter Solutions manual (available only to teachers)

Laser Photoionization Spectroscopy discusses the features and the development of photoionization technique. This book explores the progress in the application of lasers, which improve the characteristics of spectroscopic methods. Organized into 12 chapters, this book starts with an overview of the fundamentals of the method for atoms and molecules. This text then examines the photoionization spectroscopy, which is based on the laser resonant excitation of particles into high-lying quantum states that are easy to detect by ionization. Other chapters explain the various basic schemes of multistep excitation, which can be used for resonance photoionization of molecules. This book discusses as well the different applications of the resonance photoionization technique in atomic and molecular spectroscopy. The final chapter considers the two well-known types of microscopy, namely, wave and corpuscular. This book is a valuable resource for chemists, physicists, analysts, and geochemists who are interested in laser spectroscopy techniques to solve nontrivial problems.

Laser spectroscopy has been perfected over the last fifteen years to become a precise tool for the investigation of highly vibrationally excited molecules. Intense infrared laser radiation permits both the multiple-photon resonant excitation and the dissociation of polyatomic molecules. In this book, the latest results of some of the foremost Soviet researchers are published for the first time in the West. Laser Spectroscopy of Highly Vibrationally Excited Molecules contains a comprehensive study of both the experimental and theoretical aspects of the basic photophysical interactions that occur in these processes. The book first focuses on the nonlinear interaction between the resonant vibrational mode and the intense infrared field and then examines the nonlinear interaction between the vibrational modes themselves due to anharmonicity. These interrelated processes determine all the characteristics of polyatomic molecules in an infrared field. The book also discusses related phenomena such as spectra broadening, optical resonance, photon echoes, and dynamical chaos. It includes examples of multiple-photon resonant excitation such as the excitation of OsO4 by CO^O2 laser radiation, which is detected by the visible luminescence that results. This book will be of great interest to researchers and postgraduate students in infrared laser spectroscopy and the laser chemistry of molecules and applications of isotope separation.

Keeping abreast of the latest techniques and applications, this new edition of the standard reference and graduate text on laser spectroscopy has been completely revised and expanded. While the general concept is unchanged, the new edition features a broad array of new material, e.g., frequency doubling in external cavities, reliable cw-parametric oscillators, tunable narrow-band UV sources, more sensitive detection techniques, tunable femtosecond and sub-femtosecond lasers (X-ray region and the attosecond range), control of atomic and molecular excitations, frequency combs able to synchronize independent femtosecond lasers, coherent matter waves, and still more applications in chemical analysis, medical diagnostics, and engineering.

The impact of lasers on spectroscopy can hardly be overestimated. Lasers re present intense light sources with spectral energy densities which may exceed those of i ncoheren t sources by severa 1 orders of magnitude. Furthermore be cause of their extremely small bandwidth, single-mode lasers allow a spectral resolution which far exceeds that of conventional spectrometers. Many experi ments which could not be done before the application of lasers because of lack of intensity or insufficient resol ution are readily performed wi th lasers. Now several thousands of laser lines are known which span the whole spec tral range from the vacuum-ultraviolet to the far-infrared region. Of parti cular interest are the continuously tunable lasers which may in many cases replace wavelength-selecting elements, such as spectrometers or interferome ters. In combination with optical frequency mixing, techniques such conti nuously tunable monochromatic coherent light sources are available at nearly any desired wavelength above 100 nm.

Bringing together scattered literature from a range of sources, Laser Spectroscopy and ItsApplications clearly elucidates the tools and concepts of this dynamic area, and providesextensive bibliographies for further study.Distinguished experts in their respective fields discuss resonance photoionization, laser absorption,laser-induced breakdown, photodissociation, Raman scattering, remote sensing,and laser-induced fluorescence. The book also incorporates an overview of the semiclassicaltheory of atomic and molecular spectra.Combining background at an intermediate level with an in-depth discussion of specifictechniques, Laser Spectroscopy and Its Applications is essential reading for laser and opticalscientists and engineers; analytical chemists; health physicists; researchers in optical,chemical, pharmaceutical, and metallurgical industries. It will also prove useful for upperlevelundergraduate and graduate students of laser spectroscopy and its applications, andin-house seminars and short courses offered by firms and professional societies.