Free Radicals In Organic Chemistry
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Author | : |
Publisher | : Elsevier |
Total Pages | : 271 |
Release | : 2004-01-14 |
Genre | : Science |
ISBN | : 0080524257 |
Download Advanced Free Radical Reactions for Organic Synthesis Book in PDF, Epub and Kindle
Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Author | : Jacques Fossey |
Publisher | : |
Total Pages | : 328 |
Release | : 1995-11-09 |
Genre | : Business & Economics |
ISBN | : |
Download Free Radicals in Organic Chemistry Book in PDF, Epub and Kindle
Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.
Author | : Malcolm D. Forbes |
Publisher | : John Wiley & Sons |
Total Pages | : 300 |
Release | : 2010-01-22 |
Genre | : Science |
ISBN | : 9780470584101 |
Download Carbon-Centered Free Radicals and Radical Cations Book in PDF, Epub and Kindle
Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Author | : Cheves Walling |
Publisher | : |
Total Pages | : 644 |
Release | : 2013-02 |
Genre | : |
ISBN | : 9781258592042 |
Download Free Radicals in Solution Book in PDF, Epub and Kindle
Author | : Jacques Fossey |
Publisher | : Wiley |
Total Pages | : 322 |
Release | : 1995-11-06 |
Genre | : Science |
ISBN | : 9780471954965 |
Download Free Radicals in Organic Chemistry Book in PDF, Epub and Kindle
Illustrious researchers offer an excellent introduction to the structure, formation and reactivity of free radicals. Contains a complete overview of the numerous and varied applications of free radicals within organic chemistry with special attention to reaction mechanisms and novel responses. Includes detailed accounts along with actual examples of the most recent developments in the field.
Author | : Andrew F. Parsons |
Publisher | : Wiley-Blackwell |
Total Pages | : 252 |
Release | : 2000-11-30 |
Genre | : Science |
ISBN | : 9780632052929 |
Download An Introduction to Free Radical Chemistry Book in PDF, Epub and Kindle
The past twenty years has seen an explosion of interest in free radicals, as their pivotal role in both chemistry and biology has come to light. This introductory textbook aims to capture this excitement for advanced level undergraduates, with particular emphasis on the importance of radical reactions in organic synthesis. The book provides a gentle, stepwise introduction to the subject, taking the student from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes, allowing the relevance of the subject to be grasped more easily. Suitable for advanced level undergraduates and postgraduates in chemistry and biochemistry, the book will also be invaluable for research level scientists requiring an update in the area.
Author | : E. T. Denisov |
Publisher | : John Wiley & Sons |
Total Pages | : 903 |
Release | : 2005-01-14 |
Genre | : Science |
ISBN | : 0471281832 |
Download Handbook of Free Radical Initiators Book in PDF, Epub and Kindle
Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Author | : Derek H. R. Barton |
Publisher | : Cambridge University Press |
Total Pages | : 180 |
Release | : 1993-04-15 |
Genre | : Science |
ISBN | : 9780521445801 |
Download Half a Century of Free Radical Chemistry Book in PDF, Epub and Kindle
This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.
Author | : José A. Martinho Simões |
Publisher | : Springer Science & Business Media |
Total Pages | : 313 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 9400900996 |
Download Energetics of Organic Free Radicals Book in PDF, Epub and Kindle
Author | : Bernd Giese |
Publisher | : C R C Press Reprints |
Total Pages | : 316 |
Release | : 1986 |
Genre | : Science |
ISBN | : |
Download Radicals in Organic Synthesis Book in PDF, Epub and Kindle