Characterization And Analysis Of Highly Diagonal Terahertz Quantum Cascade Lasers

The as yet unattained milestone of room-temperature operation is essential for establishing Terahertz Quantum Cascade Lasers (THz QCLs) as practical sources of THz radiation. Temperature performance is hypothesized to be limited by upper laser level lifetime reduction due to non-radiative scattering, particularly by longitudinal optical phonons. To address this issue, this work studies highly "diagonal" QCLs, where the upper and lower laser level wave functions are spatially separated to preserve upper laser level lifetime, as well as several other issues relevant to high temperature performance. The highly diagonal devices of this work performed poorly, but the analysis herein nevertheless suggest that diagonality as a design strategy cannot yet be ruled out. Other causes of poor performance in the lasers are identified, and suggestions for future designs are made.

Quantum cascade laser (QCL), as a unipolar semiconductor laser based on intersubband transitions in quantum wells, covers a large portion of the Mid and Far Infrared electromagnetic spectrum. The frequency of the optical transition can be determined by engineering the layer sequence of the heterostructure. The focus of this work is on Terahertz (THz) frequency range (frequency of 1 - 10 THz and photon energy of ~ 4 - 40 meV), which is lacking of high power, coherent, and efficient narrowband radiation sources. THz QCL, demonstrated in 2002, as a perfect candidate of coherent THz source, is still suffering from the empirical operating temperature limiting factor of T [ap] h̳[omega]/kB, which allows this source to work only under a cryogenic system. Most of high performance THz QCLs, including the world record design which lased up to ~ 200 K, are based on a resonant phonon (RP) scheme, whose population inversion is always less than 50%. The indirectly-pumped (IDP) QCL, nicely implemented in MIR frequency, starts to be a good candidate to overcome the aforementioned limiting factor of RP-QCL. A rate equation (RE) formalism, which includes both coherent and incoherent transport process, will be introduced to model the carrier transport of all presented structures in this thesis. The second order tunneling which employed the intrasubband roughness and impurity scattering, was implemented in our model to nicely predict the behavior of the QCL designs. This model, which is easy to implement and fast to calculate, could help us to engineer the electron wavefunctions of the structure with optimization tools. We developed a new design scheme which employs the phonon scattering mechanism for both injecting carrier to the upper lasing state and extracting carrier from lower lasing state. Since there is no injection/extraction state to be in resonance with lasing states, this simple design scheme does not suffer from broadening due to the tunneling. Finally, three different THz IDP-QCLs, based on phonon-photon-phonon (3P) scheme were designed, grown, fabricated, and characterized. The performance of those structures in terms of operating temperature, threshold current density, maximum current density, output optical power, lasing frequency, differential resistance at threshold, intermediate resonant current before threshold, and kBT/h̳[omega] factor will be compared. We could improve the kBT/h̳[omega] factor of the 3P-QCL design from 0.9 in first iteration to 1.3 and the output optical power of the structure from 0.9 mW in first design to 3.4 mW. The performance of the structure in terms of intermediate resonant current and the change in differential resistance at threshold was improved.

Quantum cascade lasers (QCLs) are attractive for high-resolution spectroscopy because they can provide high power and a narrow linewidth. They are particularly promising in the terahertz (THz) range since they can be used as local oscillators for heterodyne detection as well as transmitters for direct detection. However, THz QCL-based technologies are still under development and are limited by the lack of frequency tunability as well as the frequency and output power stability for free-running operation. In this dissertation, frequency tuning and linewidth of THz QCLs are studied in detail by using rotational spectroscopic features of molecular species. In molecular spectroscopy, the Doppler eff ect broadens the spectral lines of molecules in the gas phase at thermal equilibrium. Saturated absorption spectroscopy has been performed that allows for sub-Doppler resolution of the spectral features. One possible application is QCL frequency stabilization based on the Lamb dip. Since the tunability of the emission frequency is an essential requirement to use THz QCL for high-resolution spectroscopy, a new method has been developed that relies on near-infrared (NIR) optical excitation of the QCL rear-facet. A wide tuning range has been achieved by using this approach. The scheme is straightforward to implement, and the approach can be readily applied to a large class of THz QCLs. The frequency and output stability of the local oscillator has a direct impact on the performance and consistency of the heterodyne spectroscopy. A technique has been developed for a simultaneous stabilization of the frequency and output power by taking advantage of the frequency and power regulation by NIR excitation. The results presented in this thesis will enable the routine use of THz QCLs for spectroscopic applications in the near future.

Learn how the rapidly expanding area of mid-infrared and terahertz photonics has been revolutionized in this comprehensive overview. State-of-the-art practical applications are supported by real-life examples and expert guidance. Also featuring fundamental theory enabling you to improve performance of both existing and future devices.

Terahertz (THz) quantum cascade lasers (QCLs) are compact electrically pumped unipolar semiconductor laser which can produce a continuous wave radiation of high output power in the range of 1.2 to 5.6 THz. The QC vertical-external-cavity surface-emitting-laser (QC-VECSEL) is an external cavity configuration that supports high-power operation with excellent beam quality and broadband tunability. The key component of the QC-VECSEL is an amplifying reflectarray metasurface, based on a subwavelength array of surface-radiating metal-metal waveguide antenna elements loaded with QC-laser gain material. Despite its importance, up to now the spectral properties of the QC-metasurface have been designed by simulations and have only been verified indirectly through observation of the QC-VECSEL lasing characteristics, or by passive FTIR reflectance measurements at room temperature. Furthermore, design takes place using simulations based upon simplified models for the material loss and the QC-gain, where uncertain Drude model parameters for material losses are used, and the detailed interaction of the intersubband transition with the metasurface is neglected. In the past decade, THz time domain spectroscopy (THz-TDS) has been widely used to investigate gain spectra and laser dynamics of THz QC-lasers based on various ridge waveguide geometries. During my doctoral studies, I designed and built up a reflection-mode THz-TDS system to study amplifying quantum-cascade (QC) metasurface samples as a function of injected current density. The first direct spectral measurements were performed on QC-metasurfaces using reflection-mode THz-TDS. Several different kinds of metasurface were designed that were suitable for study by the THz-TDS system. Extremely strong absorption features for QC-metasurfaces whose resonance frequency designed below 3 THz is measured at zero bias, which is associated with coupling between the metasurface resonance and an intersubband transition within the QC material. In one case, nearly perfect absorption is observed due to the transition from weak to strong light-matter coupling condition. Increase in reflectance are observed as the devices are biased, both due to reduction in intersubband loss and the presence of intersubband gain. Significant phase modulation associated with the metasurface resonance is observed via electrical control for some certain metasurfaces, which may be useful for electrical tuning of QC-VECSEL. These results provide insight into the interaction between the intersubband QC-gain material and the metasurface and modify the design rules for QC-VECSELs for both biased and unbiased regions.

Terahertz Quantum Cascade Lasers (THz QCLs) are arguably the most promising technology today for the compact, efficient generation of THz radiation. Their main limitation is that they require cryogenic cooling, which dominates their ownership cost. Therefore, achieving room-temperature operation is essential for the widespread adoption of THz QCLs. This thesis analyzes the limitations of THz QCL maximum lasing temperature (Tmax) and proposes solutions. THz QCL Tmax is hypothesized to be limited by a fundamental trade-off between gain oscillator strength ful and upper-level lifetime [Tau]. This so-called "ful[Tau] tradeoff" is shown to explain the failure of designs which target [Tau] alone. A solution is proposed in the form of highly diagonal (low ful) active region design coupled with increased doping. Experimental results indicate the strategy to be promising, but heavily doped designs are shown to suffer band-bending effects which may deteriorate performance. In order to treat these band-bending effects, which are typically neglected in previous THz QCL designs, a fast transport simulation tool is developed. Scattering integrals are simplified using the assumption of thermalized sub bands. Results comparable to ensemble Monte Carlo are achieved at a fraction of the computational expense. Carrier leakages to continuum states are also investigated, although they are found to have little effect. Other work in this thesis includes the optimization of double-metal THz waveguides to enable Tmax ~ 200 K, a current world record. Furthermore, laser designs to investigate the leakages of carriers to high-energy subbands and continuum states were fabricated and tested; such parasitic leakages are suggested to be small. Finally, the design of gain media for applications is examined, notably the development of 4.7 THz gain media for OI line detection in astrophysics, and the development of broadband heterogeneous gain media for THz comb generation.