Theory Of Corrosion And Protection Of Metals

Introduction and Scope-During the last few decades, an enormous effort has been made to understand corrosion phenomena and their mechanisms, and to elucidate the causes that dramatically influence the service lifetime of metal materials. The performance of metal materials in aggressive environments is critical for a sustainable society. The failure of the material in service impacts the economy, the environment, health, and society. In this regard, corrosion-based economic losses due to maintenance, repair, and the replacement of existing structures and infrastructure account for up to 4% of gross domestic product (GDP) in well developed countries. One of the biggest issues in corrosion engineering is estimating service lifetime. Corrosion prediction has become very difficult, as there is no direct correlation with service lifetime and experimental lab results, usually as a result of discrepancies between accelerated testing and real corrosion processes. It is of major interest to forecast the impact of corrosion-based losses on society and the global economy, since existing structures and infrastructure are becoming old, and crucial decisions now need to be made to replace them. On the other hand, environmental protocols seek to reduce greenhouse effects. Therefore, low emission policies, in force, establish regulations for the next generation of materials and technologies. Advanced technologies and emergent materials will enable us to get through the next century. Great advances are currently in progress for the development of corrosion-resistant metal materials for different sectors, such as energy, transport, construction, and health. This Special Issue on the corrosion and protection of metals is focused on current trends in corrosion science, engineering, and technology, ranging from fundamental to applied research, thus covering subjects related to corrosion mechanisms and modelling, protection and inhibition processes, and mitigation strategies.

The objectives of this book are to give technical information about anodic pro tection, explain how economic analyses are made to determine whether or not it should be used, and describe some of the applications and equipment. Lim itations of the technique will be pointed out. Technological changes that have resulted in higher temperatures, pres sures, and velocities increase corrosion rates and markedly influence materials selection and design decisions. Continuous cycle systems impose increased demands on system reliability. New processes require more sophisticated equipment made of costlier metals which are often in short supply and subject to the vagaries of international commerce. The impact of continuing inflation influences decisions related to capital expenditures and maintenance costs. Some problems caused by these considerations can be solved, or solutions simplified, by the use of anodic protection. Technical and scientific information is presented on applications to industrial equipment, economics, design and installation, operation and maintenance, electrochemical principles, laboratory tests and procedures. A historical summary, patent list, glossary of terms, and a subject index are included. It is important to acknowledge that much of the information has been from the original work of others, including the publications of many friends.

Electrocorrosion, the corrosion of metallic constructions by external currents, is the most significant factor in conductive aggressive environments. Corrosion of underground and underwater metal constructions by stray currents has been comprehensively studied in the past decades and is considered here only in the form of a review. The primary attention is on corrosion, by external anodic (mainly) and cathodic currents, of metal constructions in the highly aggressive environments typical for electrochemical plants, where penetration of the external currents (leakage currents) from the electrolytic baths into metal constructions is unavoidable. A new approach to the problem of electrocorrosion protection of passive structural metals is considered in this book, keeping the metals attacked by external currents in the boundaries of their passive field. The systems, developed in accordance with this approach, are based on the modification of existing and elaboration of new methods of electrocorrosion protection. These systems take into account corrosion and electrochemical characteristics of the aggressive media (redox potential, conductivity etc.) and of the passive metal (corrosion and activation potentials, current density in a passive state, etc) as well as the sizes and distribution character of the external currents. The book covers analysis of leakage current distributions in electrochemical plants, their influence, methods to estimate corrosion stability of metallic structures subject to external currents and presents many concrete examples of the successful introduction of corrosion protection systems in operating plants. A new approach to protection from electrocorrosion, taking into account the passive state of the metal in aggressive media Newly developed and modifications of well known methods of electrocorrosion protection are presented Systematized data on electrocorrosion and protection of metals, especially in electrochemical plants, allow corrosion engineers, researchers and personnel maintaining the equipment of electrochemical plants to analyze the corrosion state of metallic equipment and prevent electrocorrosion

This book introduces corrosion mechanisms and protection technologies for metallic and non-metallic materials. A focus lies on the protection of high-tech materials with applications in space and environments exposed to unclear radiation and biological hazards. The determination, measurement and control of different corrosion mechanisms are discussed in detail. Combining theories with case studies, it is an essential reference for material scientists and engineers.

PRINCIPLES OF MODERN CHEMISTRY has dominated the honors and high mainstream general chemistry courses and is considered the standard for the course. The fifth edition is a substantial revision that maintains the rigor of previous editions but reflects the exciting modern developments taking place in chemistry today. Authors David W. Oxtoby and H. P. Gillis provide a unique approach to learning chemical principles that emphasizes the total scientific process'from observation to application'placing general chemistry into a complete perspective for serious-minded science and engineering students. Chemical principles are illustrated by the use of modern materials, comparable to equipment found in the scientific industry. Students are therefore exposed to chemistry and its applications beyond the classroom. This text is perfect for those instructors who are looking for a more advanced general chemistry textbook.

This comprehensive handbook covers all aspects of cathodic protection in terms of both practice and theory.

Principles of Metal Surface Treatment and Protection deals with the principles of metal surface treatment and protection. Topics covered range from electrodeposition and hot dip coating to diffusion and non-metallic coatings, as well as oxide and conversion coatings. The theory of corrosion protection is also discussed. Comprised of eight chapters, this volume begins with an overview of the corrosion of metals and the scope of protection against corrosion, followed by a detailed treatment of electrodeposition. The discussion then turns to the principles of hot dipping as a coating method; the formation of a diffusion coating; and the role of a non-metallic coating in corrosion protection. Subsequent chapters focus on the protection of oxide films against corrosion by means of anodizing, phosphatizing, and the use of tin free steel; testing and selection of a particular coating for corrosion resistance applications; and the theory of corrosion protection. This book is intended for metal-finishing scientists and students of metallurgy and metal finishing.