Synthetic Diamond Films

The book gives an overview on the current development status of synthetic diamond films and their applications. Its initial part is devoted to discuss the different types of conductive diamond electrodes that have been synthesized, their preparation methods, and their chemical properties and characterization. The electrochemical properties of diamond films in different scientific areas, with special attention in electroanalysis, are further described. Different strategies to modify these electrodes are also discussed as important technologies with ability to change their electrochemical characteristics for a more specific electroanalytical use. The second part of the book deals with practical applications of diamond electrodes to the industry, organic electrosynthesis, electrochemical energy technology, and biotechnology. Special emphasis is made on the properties of these materials for the production of strong oxidizing species allowing the fast mineralization of organics and their use for water disinfection and decontamination. Recent biotechnological development on biosensors, microelectrodes, and nanostructured electrodes, as well as on neurochemistry, is also presented. The book will be written by a large number of internationally recognized experts and comprises 24 chapters describing the characteristics and theoretical fundaments of the different electrochemical uses and applications of synthetic diamond films.

Examines both mined and synthetic diamonds and diamond films. The text offers coverage on the use of diamond as an engineering material, integrating original research on the science, technology and applications of diamond. It discusses the use of chemical vapour deposition grown diamonds in electronics, cutting tools, wear resistant coatings, thermal management, optics and acoustics, as well as in new products.

A comprehensive presentation of the complete spectrum of methods for CVD-diamond deposition and an overview of the most important applications.

This work, written by leading international authorities, deals with nucleation growth and processing, characterization and electrical, thermal, optical and mechanical properties of thin film diamond. The final chapters are devoted to the broad range of applications of this material.

"Examines both mined and synthetic diamonds and diamond films. The text offers coverage on the use of diamond as an engineering material, integrating original research on the science, technology and applications of diamond. It discusses the use of chemical vapour deposition grown diamonds in electronics, cutting tools, wear resistant coatings, thermal management, optics and acoustics, as well as in new products."--Provided by publisher.

The Diamond Films Handbook is an important source of information for readers involved in the new diamond film technology, emphasizing synthesis technologies and diamond film applications. Containing over 1600 references, drawings, photographs, micrographs, equations, and tables, and contributions by experts from both industry and academia, it inclu

A riveting look at the science, technology and people involved in overcoming early impracticalities of the fledgling chemical vapor deposition (CVD) synthesis method and its development in today's state of commercial readiness. Provides insights into numerous vapor phase techniques. Surveys the synthesis, structure, properties and applications of diamondlike carbon. Details current and rapidly emerging applications, manufacturing and markets.

Discusses the most advanced techniques for diamond growth Assists diamond researchers in deciding on the most suitable process conditions Inspires readers to devise new CVD (chemical vapor deposition Ever since the early 1980s, and the discovery of the vapour growth methods of diamond film, heteroexpitaxial growth has become one of the most important and heavily discussed topics amongst the diamond research community. Kobashi has documented such discussions with a strong focus on how diamond films can be best utilised as an industrial material, working from the premise that crystal diamond films can be made by chemical vapour disposition. Kobashi provides information on the process and characterization technologies of oriented and heteroepitaxial growth of diamond films.

Diamond films grown by activated chemical vapor deposition have superlative thermal, mechanical, optical, and electronic properties combined with a very high degree of chemical inertness to most environments. These properties, together with the ability to fabricate films and shapes of considerable size, promise an exciting new material with many applications. Some applications are on the verge of commercialization but many await a few more technological developments. Diamond-like films are already employed in both commercial and military applications. The popular press, as well as the scientific and technological and industrial communities, are increasingly interested in the potential for future development of these materials. Although there are many technical papers and review articles published, there is no Single comprehensive introduction to these technologies. The Scientific Affairs Division of NATO recognized the need and the future importance of these technologies and authorized an Advanced Study Institute on diamond and diamond-like films. NATO Advanced Study Institutes are high level teaching activities at which a carefully defined subject is presented in a systematic and coherently structured program. The subject is treated in considerable depth by lecturers eminent in their fields and of international standing. The presentations are made to students who are scientists in the field or who possess an advanced general scientific background.

This document details a study of the fundamental physical and chemical processes occuring in hot filament and laser assisted synthetic diamond CVD processes. The chemical model developed in this program permits a detailed analysis of previous investigations. This model suggests that several factors will limit the attainable purity and utility of synthetic diamonds grown by plasma or hot filament CVD techniques. A diamond deposition process based upon selective laser production of the chemical species which give rise to the films is described. This technique holds the promise of growing essentially pure diamond at rates comparable to existing schemes, and should permit co-deposition of selected dopant species to make novel new optic and electro-optic devices. An experimental diamond CVD reactor has been designed, developed and tested to provide experimental verification of the model. The reactor has been run in two modes of operation; a hot filament CVD mode, and a laser-assisted hot filament mode. Films deposited in the hot filament mode of operation exhibit the physical characteristics and growth behavior expected for synthetic diamond films. The observed growth kinetics agree with predictions based upon the chemical model developed here. A study based upon a laser-assisted hot filament diamond CVD process suggests that the laser process results in an enhancement of the rate of film growth, although the extent of this enhancement was limited by the available laser power. Further investigation using greater laser powers will be required to confirm this result and expand upon the results.