Surface Dynamics

While much of traditional surface science has been concerned with equilibrium properties and simple kinetics, there is a growing effort in the area of dynamical processes at surfaces. This book draws together a series of chapters written by acknowledged experts in the field, which describe progress in a range of specific topics. The emphasis is on chemical reaction dynamics, including both theoretical and experimental approaches and covering work on low index single crystal surfaces, on stepped surfaces and on supported metal clusters. Other processes, such as surface diffusion are also addressed. Further chapters discuss dynamical processes in electronically-induced desorption, and in surface diffusion on semiconductors and metals. - Presents considerable advances in surface science field - Collection of expert reviews in surface dynamics

This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the ‘surface science’ approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level understanding of physical and chemical processes at surfaces, with particular emphasis on dynamical aspects. This book is a reference in the field.

Describes fluid flow, transport and contamination in rocks and sediments, for graduate students and professionals in hydrology, water resources, geochemistry.

The present volume is concerned with two of the central questions of chemical dynamics. What do we know about the energies of interaction of atoms and molecules with each other and with solid surfaces? How can such interaction energies be used to understand and make quantitative predictions about dynamical processes like scattering, energy transfer, and chemical reactions? It is becoming clearly recognized that the computer is leading to rapid progress in answering these questions. The computer allows probing dynamical mechanisms in fine detail and often allows us to answer questions that cannot be addressed with current experimental techniques. As we enter the 1980's, not only are more powerful and faster computers being used, but techniques and methods have been honed to a state where exciting and reliable data are being generated on a variety of systems at an unprecedented pace. The present volume presents a collection of work that illustrates the capabilities and some of the successes of this kind of computer-assisted research. In a 1978 Chemical Society Report, Frey and Walsh pointed out that "it is extremely doubtful if a calculated energy of activation for any unimolecular decomposition can replace an experimental deter mination. " However they also recorded that they "believe[d] that some of the elaborate calculations being performed at present do suggest that we may be approaching a time when a choice between reaction mechanisms will be helped by such [computational] work.

The aim of this book is to present selected theoretical topics on ocean wave dynamics, including basic principles and applications in coastal and offshore engineering, all from the deterministic point of view. The bulk of the material deals with the linearized theory.

Dynamics of Gas-Surface Scattering deals with the dynamics of scattering as inferred from known properties of gases and solids. This book discusses measurements of spatial distributions of scattered atomic and molecular streams, and of the energy and momentum which gas particles exchange at solid surfaces. It also considers two regimes of scattering, both of which are associated with a lower range of incident gas energies: the thermal and structure scattering regimes. Comprised of 10 chapters, this book opens with a brief historical overview of the early experiments that investigated the dynamics of scattering of gases by surfaces. The discussion then turns to some elements of the kinetic theory of gases; intermodular potentials and interaction regimes; and classical-mechanical lattice models used in gas-surface scattering theory. The applications of molecular beams to the study of gas-surface scattering phenomena are also described. The remaining chapters focus on experiments and theories on scattering of molecular streams by surfaces of solids, with emphasis on thermal and structure regimes of inelastic scattering; quantum theory of gas-surface scattering; and quantum mechanical scattering phenomena. This text concludes with an analysis of energy exchange processes that may occur when a solid surface is completely immersed in a still gas. This monograph will be a valuable resource for students and practitioners of physics, chemistry, and applied mathematics.

This volume comprises an outstanding variety of chapters on Earth Observation based time series analyses, undertaken to reveal past and current land surface dynamics for large areas. What exactly are time series of Earth Observation data? Which sensors are available to generate real time series? How can they be processed to reveal their valuable hidden information? Which challenges are encountered on the way and which pre-processing is needed? And last but not least: which processes can be observed? How are large regions of our planet changing over time and which dynamics and trends are visible? These and many other questions are answered within this book “Remote Sensing Time Series Analyses – Revealing Land Surface Dynamics”. Internationally renowned experts from Europe, the USA and China present their exciting findings based on the exploitation of satellite data archives from well-known sensors such as AVHRR, MODIS, Landsat, ENVISAT, ERS and METOP amongst others. Selected review and methods chapters provide a good overview over time series processing and the recent advances in the optical and radar domain. A fine selection of application chapters addresses multi-class land cover and land use change at national to continental scale, the derivation of patterns of vegetation phenology, biomass assessments, investigations on snow cover duration and recent dynamics, as well as urban sprawl observed over time.

Free-Surface Flow: Shallow-Water Dynamics presents a novel approach to this phenomenon. It bridges the gap between traditional books on open-channel flow and analytical fluid mechanics. Shallow-water theory is established by formal integration of the Navier-Stokes equations, and boundary resistance is developed by a rigorous construction of turbulent flow models for channel flow. In addition, the book presents a comprehensive description of shallow-water waves by mathematical analysis. These methods form the foundation for understanding flood routing, sudden water releases, dam and levee break, sluice gate dynamics and wave-current interaction. Bridges the gap between traditional books on open-channel flow and wave mechanics Presents a comprehensive description of shallow-water waves by characteristic and bicharacteristic analysis Presents techniques for wave control and active flood mitigation

This book is an expanded form of the monograph, Dropwise Condensation on Inclined Textured Surfaces, Springer, 2013, published earlier by the authors, wherein a mathematical model for dropwise condensation of pure vapor over inclined textured surfaces was presented, followed by simulations and comparison with experiments. The model factored in several details of the overall quasi-cyclic process but approximated those at the scale of individual drops. In the last five years, drop level dynamics over hydrophobic surfaces have been extensively studied. These results can now be incorporated in the dropwise condensation model. Dropwise condensation is an efficient route to heat transfer and is often encountered in major power generation applications. Drops are also formed during condensation in distillation devices that work with diverse fluids ranging from water to liquid metals. Design of such equipment requires careful understanding of the condensation cycle, starting from the birth of nuclei, followed by molecular clusters, direct growth of droplets, their coalescence, all the way to instability and fall-off of condensed drops. The model described here considers these individual steps of the condensation cycle. Additional discussions include drop shape determination under static conditions, a fundamental study of drop spreading in sessile and pendant configurations, and the details of the drop coalescence phenomena. These are subsequently incorporated in the condensation model and their consequences are examined. As the mathematical model is spread over multiple scales of length and time, a parallelization approach to simulation is presented. Special topics include three-phase contact line modeling, surface preparation techniques, fundamentals of evaporation and evaporation rates of a single liquid drop, and measurement of heat transfer coefficient during large-scale condensation of water vapor. We hope that this significantly expanded text meets the expectations of design engineers, analysts, and researchers working in areas related to phase-change phenomena and heat transfer.

Nanolayer Research: Methodology and Technology for Green Chemistry introduces the topic of nanolayer research and current methodology, from the basics, to specific applications for green science. Each chapter is written by a specialist in their specific research area, offering a deep coverage of the topic. Nanofilms are explained, along with their rapidly emerging applications in electronic devices for smart grids, units for cells, electrodes for batteries, and sensing systems for environmental purposes in applicable subjects. Readers will find this book useful not only as a textbook for basic knowledge, but also as a reference for practical research. Outlines basic principles of nanolayers Includes methodology and technology of nanolayers Contains numerous nanolayers applications