Supramolecular Chemistry Of Fullerenes And Carbon Nanotubes

Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.

The papers included in this issue of ECS Transactions were originally presented in the symposia ¿Electron Transfer and Applications of Fullerene and Nanostructured Materials, in Honor of David Schuster¿, ¿Molecular and Supramolecular Chemistry of Fullerenes and Carbon Nanotubes¿, ¿Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes¿, ¿Carbon Nanotubes and Nanostructures: Applications and Devices¿, ¿Solid-State Physics¿, ¿Porphyrins and Supramolecular Assemblies¿, and ¿Metallic and Semiconductor Nanoparticles¿, held during the 211th meeting of The Electrochemical Society, in Chicago, IL.

Yanfei Shen and Takashi Nakanishi Exotic Self-Organized Fullerene Materials Based on Uncommon Hydrophobic–Amphiphilic Approach Yuming Zhao and Guang Chen C60 Fullerene Amphiphiles as Supramolecular Building Blocks for Organized and Well-Defined Nano scale Objects Anna Troeger, Vito Sgobba and Dirk M. Guldi Multilayer Assembly for Solar Energy Conversion Delphine Felder-Flesch Self- or Induced Organization of [60]Fullerene Hexakisadducts Andrés de la Escosura, Olga Trukhina, and Tomás Torres Dual Role of Phthalocyanines in Carbon Nano structure-Based Organic Photovoltaics Riccardo Marega, Davide Giust and Davide Bonifazi Supramolecular Chemistry of Carbon Nano tubes at Interfaces: Toward Applications Stephanie Frankenberger, Johanna A. Januszewski and Rik R. Tykwinski Oligomers from sp-Hybridized Carbon: Cumulenes and Polyynes.

This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials. It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.

Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.

The papers included in this issue of ECS Transactions were originally presented in the symposia ¿Molecular and Supramolecular Chemistry of Fullerenes and Carbon Nanotubes¿; ¿Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes¿; ¿Carbon Nanotubes and Nanostructures: Applications and Devices¿; and ¿Nanostructures for Energy Conversion¿, held during the 217th meeting of The Electrochemical Society, in Vancouver, Canada, from April 25 to 30, 2010.

The papers included in this issue of ECS Transactions were originally presented in the symposia ¿Electron Transfer and Applications of Fullerene and Nanostructured Materials¿, ¿Molecular and Supramolecular Chemistry of Fullerenes and Carbon Nanotubes¿, ¿Carbon Nanotubes and Nanostructures: Fundamental Properties and Processes¿, ¿Carbon Nanotubes and Nanostructures: Applications and Devices¿, ¿Energetics and Structure and Solid-State Physics¿, ¿Carbon Nanotubes and Nanostructures: Medicine and Biology¿, and ¿Porphyrins and Supramolecular Assemblies¿ held during the 213th meeting of The Electrochemical Society, in Phoenix, Arizona from May 18 to 23, 2008.

During the last decade, fullerenes and carbon nanotubes have attracted special interest as new nanocarbons with novel properties. Because of their hollow caged structure, they can be used as containers for atoms and molecules, and nanotubes can be used as miniature test-tubes. Chemistry of Nanocarbons presents the most up-to-date research on chemical aspects of nanometer-sized forms of carbon, with emphasis on fullerenes, nanotubes and nanohorns. All modern chemical aspects are mentioned, including noncovalent interactions, supramolecular assembly, dendrimers, nanocomposites, chirality, nanodevices, host-guest interactions, endohedral fullerenes, magnetic resonance imaging, nanodiamond particles and graphene. The book covers experimental and theoretical aspects of nanocarbons, as well as their uses and potential applications, ranging from molecular electronics to biology and medicine.

Fullerenes and nanotubes are two classes of carbon structures or allotropes, which were discovered about 17 years ago. Since that time, many chemical derivatives have been synthesized using fullerenes and nanotubes as building blocks. Particularly promising was the theory that the chemical properties of fullerenes, and certain derivatives, made them likely candidates for anticancer drugs, inhibitors of viruses such as HIV, or even as anti-bacterials. Their cyctotoxicity can also be controlled by specific circumstances. In addition, the funtionalization of nanotubes has not only produced relatively simple derivatives, but also complex hybrids with biological macromolecules, which show unique supramolecular architecture and which are promising in many medical applications. The application of fullerenes and nanotubes in medicine is at the frontier of our knowledge, thus the work in this field represents the basis for future novel developments.