Supercritical Water Processing Technologies For Environment Energy And Nanomaterial Applications

This book systematically presents the technical aspects of supercritical water oxidation and supercritical water gasification for energy and environmental applications, which include reactor design, construction materials, corrosion, salt precipitation, etc. The book provides a comprehensive introduction to the properties of supercritical water, and the industrial applications, reaction mechanisms and reaction kinetics of supercritical water oxidation (SCWO) and supercritical water gasification (SCWG). The reactions occurring in supercritical water are complex, and studying their reaction mechanisms is of great importance for the development of supercritical water processing technologies. Accordingly, the book explains the oxidative mechanisms and kinetics of organic matter in supercritical water in detail. However, the harsh reaction conditions in supercritical water can easily create severe reactor corrosion and salt deposition problems. Therefore, the book also comprehensively reports on the mechanism analysis, state of research, and development trends regarding these two problems. Lastly, the book summarizes the development of supercritical water processing technologies, including studies on SCWO and SCWG, as well as near-zero-emission systems of pollutants based on SCWO technology. In short, the book provides a wealth of valuable information for all readers who are interested in using SCWO for organic waste treatment, and in using SCWG for hydrogen production with wet biomass.

The book provides fundamental chemistry and properties of near-critical water (NCW) and supercritical water (SCW), criteria and challenges/solutions in reactor design for NCW and SCW processes, and up-to-date reviews and practice of a wide range of their applications in bio refineries including: production of hydrochars from biomass, SCW oxidation (SCWO) for waste treatment, SCW gasification (SCWG) of biomass and waste for hydrogen and methane production, hydrothermal liquefaction of biomass, production of chemicals and SCWO of biofuels for energy. It also presents techno-economic analysis of hydrogen production via SCWG of biomass. The book will be highly essential for both academic researchers and industrial practitioners for developing novel bio refinery technologies and processes employing NCW or SCW for treatment of various organic waste streams and production of bio-energy and bio-based chemicals from bio-renewable resources. Prof. Dr. Zhen Fang is leader and founder of biomass group, Xishuangbanna Tropical Botanical Garden, Chinese Academy of Sciences, China. Dr. Chunbao (Charles) Xu is currently an Associate Professor of Chemical Engineering and NSERC/FP Innovations Industrial Research Chair in Forest Bio refinery at Western University, Canada.

This book covers remarkable contemporary nanomaterials such as carbon nanomaterials, nanoclays, quantum dots, MXene, and metal-organic frameworks. Each chapter discusses the synthesis techniques, characterization methods, properties, and the nanomaterials’ use in different aspects of biomedical, energy, polymers, material construction, biosensors, coatings, and catalysis. Moreover, commercialization challenges and environmental risks of nanomaterials are also covered in depth. The book provides an understanding of the fundamental properties, limitations and challenges in nanomaterials synthesis, serving as a valuable resource for researchers, graduate students, academicians, and consultants working with nanomaterials for engineering applications.

Supercritical Fluid Technology for Energy and Environmental Applications covers the fundamental principles involved in the preparation and characterization of supercritical fluids (SCFs) used in the energy production and other environmental applications. Energy production from diversified resources — including renewable materials — using clean processes can be accomplished using technologies like SCFs. This book is focused on critical issues scientists and engineers face in applying SCFs to energy production and environmental protection, the innovative solutions they have found, and the challenges they need to overcome. The book also covers the basics of sub- and supercritical fluids, like the thermodynamics of phase and chemical equilibria, mathematical modeling, and process calculations. A supercritical fluid is any substance at a temperature and pressure above its critical point where distinct liquid and gas phases do not exist. At this state the compound demonstrates unique properties, which can be "fine-tuned," making them suitable as organic solvents in a range of industrial and laboratory processes. This volume enables readers to select the most appropriate medium for a specific situation. It helps instructors prepare course material for graduate and postgraduate courses in the area of chemistry, chemical engineering, and environmental engineering. And it helps professional engineers learn supercritical fluid-based technologies and use them in solving the increasingly challenging environmental issues. Relates theory, chemical characteristics, and properties of the particular supercritical fluid to its various applications Covers the fundamentals of supercritical fluids, like thermodynamics of phase and chemical equilibria, mathematical modeling, and process calculations Includes the most recent applications of supercritical fluids, including energy generation, materials synthesis, and environmental protection

The book will describe various technologies that use pressurized solvents for synthesis and processing of nanomaterials, including hydrothermal, solvothermal and supercritical fluid technologies. Written by two world-renowned experts in the area, the book will provide information on: Pressurized solvents technologies: principles of technologies (hydrothermal, solvothermal, and supercritical fluids), the systems, reactions, established applications; Pressurized solvents technologies in processing of nanomaterials: importance, technological advantages, principles, and system requirements controlling factors: physical, chemical and hydrodynamic factors, thermodynamic principles, solubility and kinetics of crystallization equipment: reactors and reactor design, and safety issues engineering considerations: process design for various applications

Smart materials are used to develop more cost-effective and high-performance water treatment systems as well as instant and continuous ways to monitor water quality. Smart materials in water research have been extensively utilized for the treatment, remediation, and pollution prevention. Smart materials can maintain the long term water quality, availability and viability of water resource. Thus, water via smart materials can be reused, recycled, desalinized and also it can detect the biological and chemical contamination whether the source is from municipal, industrial or man-made waste. The 15 state-of-the-art review chapters contained in this book cover the recent advancements in the area of waste water, as well as the prospects about the future research and development of smart materials for the waste water applications in the municipal, industrial and manmade waste areas. Treatment techniques (nanofiltration, ultrafiltration, reverse osmosis, adsorption and nano-reactive membranes) are also covered in-depth. The chapters are divided into three groups: The first section includes the various carbon nanomaterials (such as carbon nanotubes, mixed oxides) with a focus on use of carbon at nanoscale applied for waste water research. The second section focuses on synthetic nanomaterials for pollutants removal. The third section highlights the bio-polymeric nanomaterials where the authors have used the natural polymers matrices in a composite and nanocomposite material for waste treatment. The large number of researchers working in the area will benefit from the fundamental concepts, advanced approaches and application of the various smart materials towards waste water treatment that are described in the book. It will also provide a platform for the researchers and graduate students to carry out advanced research and understand the building blocks.

One technology for environmental control and waste remediation which has great potential is contaminant removal and separation with supercritical fluids (SCFs) or supercritical fluid extraction. In order to take advantage of this technology, both a fundamental understanding of phase equilibria and applicable engineering design data are required. This report documents an extensive study into both aspects culminating in the design and economic evaluation of an SCF regeneration process for granular activated carbon. Results include: solubility of model compounds, cosolvent effects on solubility, vapor pressure measurements, spectroscopic measurements, and models for SCF phase equilibria. Charts, tables and graphs.

Encyclopedia of Renewable Energy, Sustainability and the Environment, Four Volume Set comprehensively covers all renewable energy resources, including wind, solar, hydro, biomass, geothermal energy, and nuclear power, to name a few. In addition to covering the breadth of renewable energy resources at a fundamental level, this encyclopedia delves into the utilization and ideal applications of each resource and assesses them from environmental, economic, and policy standpoints. This book will serve as an ideal introduction to any renewable energy source for students, while also allowing them to learn about a topic in more depth and explore related topics, all in a single resource. Instructors, researchers, and industry professionals will also benefit from this comprehensive reference. Covers all renewable energy technologies in one comprehensive resource“/li> Details renewable energies’ processes, from production to utilization in a single encyclopedia Organizes topics into concise, consistently formatted chapters, perfect for readers who are new to the field Assesses economic challenges faced to implement each type of renewable energy Addresses the challenges of replacing fossil fuels with renewables and covers the environmental impacts of each renewable energy