Statistical Thermodynamics For Pure And Applied Sciences

This textbook concerns thermal properties of bulk matter and is aimed at advanced undergraduate or first-year graduate students in a range of programs in science or engineering. It provides an intermediate level presentation of statistical thermodynamics for students in the physical sciences (chemistry, nanosciences, physics) or related areas of applied science/engineering (chemical engineering, materials science, nanotechnology engineering), as they are areas in which statistical mechanical concepts play important roles. The book enables students to utilize microscopic concepts to achieve a better understanding of macroscopic phenomena and to be able to apply these concepts to the types of sub-macroscopic systems encountered in areas of nanoscience and nanotechnology.

Statistical physics and thermodynamics describe the behaviour of systems on the macroscopic scale. Their methods are applicable to a wide range of phenomena, from neutron stars to heat engines, or from chemical reactions to phase transitions. The pertinent laws are among the most universal ones of all laws of physics.

The book guides the reader from the foundations of statisti- cal thermodynamics including the theory of intermolecular forces to modern computer-aided applications in chemical en- gineering and physical chemistry. The approach is new. The foundations of quantum and statistical mechanics are presen- ted in a simple way and their applications to the prediction of fluid phase behavior of real systems are demonstrated. A particular effort is made to introduce the reader to expli- cit formulations of intermolecular interaction models and to show how these models influence the properties of fluid sy- stems. The established methods of statistical mechanics - computer simulation, perturbation theory, and numerical in- tegration - are discussed in a style appropriate for newcom- ers and are extensively applied. Numerous worked examples illustrate how practical calculations should be carried out.

Nobel Laureate's brilliant attempt to develop a simple, unified standard method of dealing with all cases of statistical thermodynamics — classical, quantum, Bose-Einstein, Fermi-Dirac, etc.

Statistical mechanics: the bane of many a physics student, and traditionally viewed as a long parade of ensembles, partition functions, and partial derivatives. But the subject needn't be arcane. When pared back to its underlying concepts and built from the ground up, statistical mechanics takes on a charm of its own, and sheds light on all manner of physical phenomena. This book presents a straightforward introduction to the key concepts in statistical mechanics, following the popular style of the author's highly successful textbook "Explorations in Mathematical Physics". Offering a clear, conceptual approach to the subject matter, the book presents a treatment that is mathematically complete, while remaining very accessible to undergraduates. It commences by asking: why does an ink drop spread out in a bathtub of water? This showcases the importance of counting configurations, which leads naturally to ideas of microstates, energy, entropy, thermodynamics, and physical chemistry. With this foundation, the Boltzmann distribution writes itself in its fullest form, and this opens the door to the Maxwell distribution and related areas of thermal conductivity and viscosity. Quantum ideas then appear: bosons via Einstein's and Debye's theories of heat capacity, and fermions via electrical conduction and low-temperature heat capacity of metals. The text ends with a detailed derivation of blackbody radiation, and uses this to discuss the greenhouse effect, lasers, and cosmology. Suitable for use with core undergraduate courses in statistical mechanics and thermodynamics, this book concentrates on using solid mathematics, while avoiding cumbersome notation. All the necessary mathematical steps are included in the body of the text and in the worked examples. Reviews of Explorations in Mathematical Physics by Don Koks, 2006 "With enjoyable and sometimes surprising excursions along the way, the journey provides a fresh look at many familiar topics, as it takes us from basic linear mathematics to general relativity... look forward to having your geometric intuition nourished and expanded by the author's intelligent commentaries." (Eugen Merzbacher, University of North Carolina) "... an interesting supplement to standard texts for teaching mathematical methods in physics, as it will add alternative views that could serve as additional material." (S. Marcelja, Australian Journal of Physics) "... a tour through the main ideas forming the language of modern mathematical physics ...it is a difficult task for the author to decide what is a good balance between the topics and their presentation, but in this case it has been achieved. ...for those physicists who would like to be exposed to clear motivation and careful explanation of the basics of the present-day apparatus of mathematical physics." (Ivailo Mladenov, Mathematical Reviews).

The book presents a clear and unique approach to statistical thermodynamics based on Shannon's measure of information, and provides applications to problems of interest in the life sciences. There is no other book which presents the fundamentals of statistical thermodynamics on Information theory, yet also includes many applications which usually do not feature in such textbooks.

One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equilibrium part of the statistical mechanics. This text emphasises on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics. It provides an introduction to the simplest forms of Monte Carlo and molecular dynamics simulation (albeit only for simple spherical molecules) and user-friendly MATLAB programs for doing such simulations, and also some other calculations. The purpose of this text is to provide a readable introduction to statistical thermodynamics, show its utility and the way the results obtained lead to useful generalisations for practical application. The text also illustrates the difficulties that arise in the statistical thermodynamics of dense fluids as seen in the discussion of liquids.

A Course in Statistical Thermodynamics explores the physical aspects of the methodology of statistical thermodynamics without the use of advanced mathematical methods. This book is divided into 14 chapters that focus on a correct statement of the Gibbsian ensemble theory couched in quantum-mechanical terms throughout. The introductory chapters emphasize the concept of equilibrium, phase space, the principle of their quantization, and the fundamentals of quantum mechanics and spectroscopy. These topics are followed by an exposition of the statistical method, revealing that the structure of the physical theory is closely modeled on mathematical statistics. A chapter focuses on stationary ensembles and the restatement of the First, Second, and Third Law of Thermodynamics. The remaining chapters highlight the various specialized applications of statistical thermodynamics, including real and degenerate gases, simple solids, radiation, magnetic systems, nonequilibrium states, and fluctuations. These chapters also provide a rigorous derivation of Boltzmann's equation, the H-theorem, and the vexing paradox that arises when microscopic reversibility must be reconciled with irreversible behavior in the large. This book can be used for two semesters in the junior or senior years, or as a first-year graduate course in statistical thermodynamics.