Reagents For Silicon Mediated Organic Synthesis
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Author | : Philip L. Fuchs |
Publisher | : John Wiley & Sons |
Total Pages | : 859 |
Release | : 2011-11-07 |
Genre | : Technology & Engineering |
ISBN | : 0470710233 |
Download Reagents for Silicon-Mediated Organic Synthesis Book in PDF, Epub and Kindle
Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization. 2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relay stratagem'. A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.
Author | : William P. Weber |
Publisher | : Springer Science & Business Media |
Total Pages | : 446 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 3642686613 |
Download Silicon Reagents for Organic Synthesis Book in PDF, Epub and Kindle
Author | : Leo A. Paquette |
Publisher | : Wiley-Blackwell |
Total Pages | : 0 |
Release | : 2010-03-01 |
Genre | : Science |
ISBN | : 9780470748725 |
Download Sulfur-Containing Reagents Book in PDF, Epub and Kindle
There are a lot of books available about the chemistry and biology of sulfur. However, this is the first book with a compilation of all relevant Sulfur containing reagents. Synthetic chemists, most particularly in the medicinal and pharmaceutical chemists, are often called upon to prepare compounds that contain Sulfur as a key structural feature. In the past, this seemed to be a domain for specialists; today every synthetic chemist working in these area is expected to synthesize compounds containing sulfides, sulfates, sulfones, etc. This book offers an important source of information for the selection and handling of the right reagents.
Author | : Ernest W. Colvin |
Publisher | : |
Total Pages | : 184 |
Release | : 1988 |
Genre | : Science |
ISBN | : |
Download Silicon Reagents in Organic Synthesis Book in PDF, Epub and Kindle
This work provides a full coverage of organosilicon chemistry, with pertinent references to more detailed treatment given at appropriate points in the book.
Author | : Helmut Vorbrueggen |
Publisher | : John Wiley & Sons |
Total Pages | : 378 |
Release | : 2006-03-06 |
Genre | : Science |
ISBN | : 3527605924 |
Download Silicon-mediated Transformations of Functional Groups Book in PDF, Epub and Kindle
In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods. The compact form and clear structure of this monograph make this a long-awaited ready reference. From the contents: Introduction * Techniques of Preparative Silylations-Desilylations * Preparation and Properties of Siliconoxy-Leaving Groups * Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide * Reactions of Aldehydes and Ketones * Reactions of Alcohols, Ethers and Epoxides * Reaction of N-O Systems * Reactions of S-O and Se-O Systems * Cyclizations and Ring Enlargements * Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions * Formation of Carbon-Phosphorous Double- and Triple Bonds * Reductions and Oxidations * Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds * Formation of Polymers
Author | : Ernest W. Colvin |
Publisher | : Butterworth-Heinemann |
Total Pages | : 361 |
Release | : 2013-10-22 |
Genre | : Science |
ISBN | : 148314223X |
Download Silicon in Organic Synthesis Book in PDF, Epub and Kindle
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1999 |
Genre | : |
ISBN | : |
Download Handbook of Reagents for Organic Synthesis Book in PDF, Epub and Kindle
Author | : Uwe Schneider |
Publisher | : Royal Society of Chemistry |
Total Pages | : 431 |
Release | : 2020-10-30 |
Genre | : Technology & Engineering |
ISBN | : 178801118X |
Download Catalysis with Earth-abundant Elements Book in PDF, Epub and Kindle
Considering the limited resources of our planet, earth-abundant elements will have to be explored increasingly in the future. This book highlights the uses of the most earth-abundant elements in catalysis and will be of interest to graduates, academic researchers and practitioners in catalysis.
Author | : WP. WEBER |
Publisher | : |
Total Pages | : |
Release | : 1983 |
Genre | : |
ISBN | : |
Download Silicon Reagents for Organic Synthesis Book in PDF, Epub and Kindle
Author | : Philip L. Fuchs |
Publisher | : John Wiley & Sons |
Total Pages | : 640 |
Release | : 2016-07-19 |
Genre | : Science |
ISBN | : 1119279836 |
Download Essential Reagents for Organic Synthesis Book in PDF, Epub and Kindle
From Boron Trifluoride to Zinc, the 52 most widely used reagents in organic synthesis are described in this unique desktop reference for every organic chemist. The list of reagents contains classics such as N-Bromosuccinimide (NBS) and Trifluoromethanesulfonic Acid side by side with recently developed ones like Pinacolborane and Tetra-n-propylammonium Perruthenate (TPAP). For each reagent, a concise article provides a brief description of all important reactions for which the reagent is being used, including yields and reaction conditions, an overview of the physical properties of the reagent, its storage conditions, safe handling, laboratory synthesis and purification methods. Advantages and disadvantages of the reagent compared to alternative synthesis methods are also discussed. Reagents have been hand-picked from among the 5000 reagents contained in EROS, the Encyclopedia of Reagents for Organic Synthesis. Every organic chemist should be familiar with these key reagents that can make almost every reaction work.