Pseudocapacitors For Energy Storage

Fluctuation in the demand for electrical power and the intermittent nature of the supply of energy from renewable sources like solar and wind have made the need for energy storage a dire necessity. Current storage technologies like batteries and supercapacitors fall short either in terms of power output or in their ability to store sufficient energy. Pseudocapacitors combine features of both and offer an alternative to stabilize the power supply. They possess high rates of charge and discharge and are capable of storing much more energy in comparison to a supercapacitor. In the quest for solutions that are economical and feasible, we have investigated Prussian Blue in aqueous electrolytes for its use as a pseudocapacitor. Two different active materials based on Prussian Blue were prepared; one that has just Prussian Blue and the other that contains a mixture of Prussian Blue and carbon nanotubes (CNTs). Four electrolytes differing in the valence of the cation were employed for the study. Cyclic voltammetry and galvanostatic charge-discharge were used to characterize the electrodes. Our experiments have shown specific capacitances of Prussian Blue electrodes in the range of 140-720 F/g and that of Prussian Blue-CNT electrodes in the range of ~52 F/g. The remarkable capacity of charge storage in Prussian Blue electrodes is attributed to its electrochemical activity ensuring surface redox and its tunnel-like structure allowing ease of entry and exit for ions like Potassium. Simple methods of synthesis have yielded specific capacitances of the order of hundreds of Farads per gram showing that Prussian Blue has promise as an electrode material for applications needing high rates of charge-discharge.

Advances in Supercapacitor and Supercapattery: Innovations in Energy Storage Devices provides a deep insight into energy storage systems and their applications. The first two chapters cover the detailed background, fundamental charge storage mechanism and the various types of supercapacitor. The third chapter give details about the hybrid device (Supercapattery) which comprises of battery and capacitive electrode. The main advantages of Supercapattery over batteries and supercapacitor are discussed in this chapter. The preceding three chapters cover the electrode materials used for supercapattery. The electrolyte is a major part that significantly contributes to the performance of the device. Therefore, different kinds of electrolytes and their suitability are discussed in chapter 6 and 7. The book concludes with a look at the potential applications of supercapattery, challenges and future prospective. This book is beneficial for research scientists, engineers and students who are interested in the latest developments and fundamentals of energy storage mechanism and clarifies the misleading concepts in this field. Presents the three classes of energy storage devices and clarifies the difference between between pseudocapacitor and battery grade material Covers the synthesis strategies to enhance the overall performance of the supercapacitor device (including power density) Explains the energy storage mechanism based on the fundamental concept of physics and electrochemistry

The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.

Metal Oxides in Supercapacitors addresses the fundamentals of metal oxide-based supercapacitors and provides an overview of recent advancements in this area. Metal oxides attract most of the materials scientists use due to their excellent physico-chemical properties and stability in electrochemical systems. This justification for the usage of metal oxides as electrode materials in supercapacitors is their potential to attain high capacitance at low cost. After providing the principles, the heart of the book discusses recent advances, including: binary metal oxides-based supercapacitors, nanotechnology, ternary metal oxides, polyoxometalates and hybrids. Moreover, the factors affecting the charge storage mechanism of metal oxides are explored in detail. The electrolytes, which are the soul of supercapacitors and a mostly ignored character of investigations, are also exposed in depth, as is the fabrication and design of supercapacitors and their merits and demerits. Lastly, the market status of supercapacitors and a discussion pointing out the future scope and directions of next generation metal oxides based supercapacitors is explored, making this a comprehensive book on the latest, cutting-edge research in the field. Explores the most recent advances made in metal oxides in supercapacitors Discusses cutting-edge nanotechnology for supercapacitors Includes fundamental properties of metal oxides in supercapacitors that can be used to guide and promote technology development Contains contributions from leading international scientists active in supercapacitor research and manufacturing

Although recognized as an important component of all energy storage and conversion technologies, electrochemical supercapacitators (ES) still face development challenges in order to reach their full potential. A thorough examination of development in the technology during the past decade, Electrochemical Supercapacitors for Energy Storage and Delivery: Fundamentals and Applications provides a comprehensive introduction to the ES from technical and practical aspects and crystallization of the technology, detailing the basics of ES as well as its components and characterization techniques. The book illuminates the practical aspects of understanding and applying the technology within the industry and provides sufficient technical detail of newer materials being developed by experts in the field which may surface in the future. The book discusses the technical challenges and the practical limitations and their associated parameters in ES technology. It also covers the structure and options for device packaging and materials choices such as electrode materials, electrolyte, current collector, and sealants based on comparison of available data. Supplying an in depth understanding of the components, design, and characterization of electrochemical supercapacitors, the book has wide-ranging appeal to industry experts and those new to the field. It can be used as a reference to apply to current work and a resource to foster ideas for new devices that will further the technology as it becomes a larger part of main stream energy storage.

This edited volume Supercapacitors: Theoretical and Practical Solutions is a collection of reviewed and relevant research chapters, offering a comprehensive overview of recent developments in the field of electronic devices and materials. The book comprises single chapters authored by various researchers and is edited by a group of experts. Each chapter is complete in itself but united under a common research study topic. This publication aims at providing a thorough overview of the latest research efforts by international authors on electronic devices and materials and opens new possible research paths for further novel developments.

With its inclusion of the fundamentals, systems and applications, this reference provides readers with the basics of micro energy conversion along with expert knowledge on system electronics and real-life microdevices. The authors address different aspects of energy harvesting at the micro scale with a focus on miniaturized and microfabricated devices. Along the way they provide an overview of the field by compiling knowledge on the design, materials development, device realization and aspects of system integration, covering emerging technologies, as well as applications in power management, energy storage, medicine and low-power system electronics. In addition, they survey the energy harvesting principles based on chemical, thermal, mechanical, as well as hybrid and nanotechnology approaches. In unparalleled detail this volume presents the complete picture -- and a peek into the future -- of micro-powered microsystems.

Metal Oxides in Energy Technologies provides, for the first time, a look at the wide range of energy applications of metal oxides. Topics covered include metal oxides materials and their applications in batteries, supercapacitors, fuel cells, solar cells, supercapacitors, and much more. The book is written by an experienced author of over 240 papers in peer-reviewed journals who was also been recognized as one of Thomson Reuter’s “World’s Most Influential Scientific Minds in 2015. This book presents a unique work that is ideal for academic researchers and engineers. Presents an authoritative overview on metal oxides in energy technologies as written by an expert author who has published extensively in the area Offers up-to-date coverage of a large, rapidly growing and complex literature Focuses on applications, making it an ideal resource for those who want to apply this knowledge in industry

Supercapacitors are a relatively new energy storage system that provides higher energy density than dielectric capacitors and higher power density than batteries. They are particularly suited to applications that require energy pulses during short periods of time, e.g., seconds or tens of seconds. They are recommended for automobiles, tramways, buses, cranes, fork-lifts, wind turbines, electricity load leveling in stationary and transportation systems, etc. Despite the technological maturity of supercapacitors, there is a lack of comprehensive literature on the topic. Many high performance materials have been developed and new scientific concepts have been introduced. Taking into account the commercial interest in these systems and the new scientific and technological developments now is the ideal time to publish this book, capturing all this new knowledge. The book starts by giving an introduction to the general principles of electrochemistry, the properties of electrochemical capacitors, and electrochemical characterization techniques. Electrical double layer capacitors and pseudocapacitors are then discussed, followed by the various electrolyte systems. Modelling, manufacture of industrial capacitors, constraints, testing, and reliability as well as applications are also covered. 'Supercapacitors - Materials, Systems, and Applications' is part of the series on Materials for Sustainable Energy and Development edited by Prof. G.Q. Max Lu. The series covers advances in materials science and innovation for renewable energy, clean use of fossil energy, and greenhouse gas mitigation and associated environmental technologies.