Platinum Group Element And Magmatic Sulfide Deposits

This book is written by a leading authority on the subject of magmatic sulfide deposits. An overview of deposit types, accompanied by a summary of the resources of nickel, copper and platinum-group elements in the world’s principal known deposits, is followed by a summary of the relevant physical chemistry. The core of the book comprises a discussion about the geology and geochemistry of each of the deposit types in turn, accompanied by the implications of this data to the origin of the deposits in the light of our understanding of the chemical processes involved. A final chapter focuses on the use of the genetic concepts in exploration.

Provides an overview of tin deposits worldwide and its geological aspects.

Platinum-group elements (PGE) are important as petrogenetic tracers, but owing to their low abundances and complex behaviour they are among the least understood elements in geochemistry. This study investigates the mechanisms of PGE fractionation in ultramafic systems (komatiites, komatiitic basalts, ferro-picrites) and focuses on the role of chromite. Samples from a range of occurrences have been analysed to assess potential controls on PGE behaviour, such as geochemical affinities (Munro-type and Karasjok-type), age (2.0 and 2.7 Ga), emplacement styles, metamorphic grade and nickel-sulphide mineralisation endowment and style. -- Data obtained by in-situ laser ablation ICP-MS analysis provide the first direct evidence that Ru can exist in solid solution in chromite with concentrations up to several hundred ppb. The data show that the behaviour of Ru is dominantly controlled by the sulphide-saturation state. In systems that did not equilibrate with a sulphide liquid, chromites have distinctly higher Ru concentrations than chromites from systems that interacted with a sulphur-source during crystallisation. Carius tube digestion isotope dilution ICP-MS analyses of chromite separates confirm the accuracy of the in-situ study and also show that Ir is weakly compatible in chromite. Anomalously high Pt and Pd concentrations in chromite separates reflect the presence of platinum-group minerals (PGM) and suggest that PGM are common accessory phases in komatiites. A study of the PGE-mineralogy shows that PGM in komatiites can be of magmatic and post-magmatic origin and that they often remain undetected due to grain sizes less than 5 urn. As a consequence, the presence of PGE minerals has to be taken into account when whole-rock PGE signatures are interpreted. -- The association of Ru-poor chromites with Ni mineralisation and Ru-rich chromites with barren systems provides a new tool for the exploration for nickel-sulphide deposits. This model applies to all magma types and is independent of the age, the geochemical affinity, and other sample characteristics.

Processes and Ore Deposits of Ultramafic-Mafic Magmas through Space and Time focuses on the fundamental processes that control the formation of ore deposits from ultramafic-mafic magmas, covering chromite, platinum-group element (PGE), Ni-sulfides and Ti-V-bearing magnetite. The exploration, exploitation and use of these magmatic ores are important aspects of geology and directly linked to the global economy. Magmatic ores form from ultramafic-mafic magmas and crystallize at high-temperature after emplacement into crustal magma chambers, and are genetically linked to the evolution of the parental magmas through space and time. This book features recent developments in the field of magmatic ore deposits, and is an essential resource for both industry professionals and those in academia. Elucidates the relationships between tectonic settings and magmatic ore mineralization Provides the links between magma generation in the mantle and ore mineralization at crustal levels Features the latest research on changing patterns in magmatic ore mineralization through time and their bearing on the chemical evolution of the Earth’s mantle

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This book is written by a leading authority on the subject of magmatic sulfide deposits. An overview of deposit types, accompanied by a summary of the resources of nickel, copper and platinum-group elements in the world’s principal known deposits, is followed by a summary of the relevant physical chemistry. The core of the book comprises a discussion about the geology and geochemistry of each of the deposit types in turn, accompanied by the implications of this data to the origin of the deposits in the light of our understanding of the chemical processes involved. A final chapter focuses on the use of the genetic concepts in exploration.