Plasma Kinetics In Atmospheric Gases

Emphasis is placed on the analysis of translational, rotational, vibrational and electronically excited state kinetics, coupled to the electron Boltzmann equation.

Describing non-equilibrium "cold" plasmas through a chemical physics approach, this book uses the state-to-state plasma kinetics, which considers each internal state as a new species with its own cross sections. Extended atomic and molecular master equations are coupled with Boltzmann and Monte Carlo methods to solve the electron energy distribution function. Selected examples in different applied fields, such as microelectronics, fusion, and aerospace, are presented and discussed including the self-consistent kinetics in RF parallel plate reactors, the optimization of negative ion sources and the expansion of high enthalpy flows through nozzles of different geometries. The book will cover the main aspects of the state-to-state kinetic approach for the description of nonequilibrium cold plasmas, illustrating the more recent achievements in the development of kinetic models including the self-consistent coupling of master equations and Boltzmann equation for electron dynamics. To give a complete portrayal, the book will assess fundamental concepts and theoretical formulations, based on a unified methodological approach, and explore the insight in related scientific problems still opened for the research community.

Chemical Kinetics relates to the rates of chemical reactions and factors such as concentration and temperature, which affects the rates of chemical reactions. Such studies are important in providing essential evidence as to the mechanisms of chemical processes. The book is designed to help the reader, particularly students and researchers of physical science, understand the chemical kinetics mechanics and chemical reactions. The selection of topics addressed and the examples, tables and graphs used to illustrate them are governed, to a large extent, by the fact that this book is aimed primarily at physical science (mainly chemistry) technologists. Undoubtedly, this book contains "must read" materials for students, engineers, and researchers working in the chemistry and chemical kinetics area. This book provides valuable insight into the mechanisms and chemical reactions. It is written in concise, self-explanatory and informative manner by a world class scientists in the field.

Filling the gap for a book that covers not only plasma in gases but also in liquids, this is all set to become the standard reference for this topic. It provides a broad-based overview of plasma-chemical and plasmacatalytic processes generated by electrical discharges in gases, liquids and gas/liquid environments in both fundamental and applied aspects by focusing on their environmental and green applications and also taking into account their practical and economic viability. With the topics addressed by an international group of major experts, this is a must-have for scientists, engineers, students and postdoctoral researchers specializing in this field.

Cold atmospheric plasma (CAP) is a promising and rapidly emerging technology for a wide range of applications, from daily life to industry. CAP’s key advantage is its unique ability to effectively deliver reactive species to subjects including biological materials, liquid media, aerosols, and manufactured surfaces. This book assesses the state-of-art in CAP research and implementation for applications including agriculture, medicine, environment, materials, catalysis, and energy. The mechanisms of generation and transport of the key reactive species in the plasma are introduced and examined in the context of their applications. Opportunities and challenges for novel technologies, fresh ideas/concepts, expanded multidisciplinary study, and new applications are discussed. The authors’ vision for the converging trends across diverse disciplines is proposed to stimulate critical discussions, research directions, and collaborations.

Plasma engineering is a rapidly expanding area of science and technology with increasing numbers of engineers using plasma processes over a wide range of applications. A current partial list would include: electronics, energetics, fuel conversion, ozone generation, treatment of polymers and othermaterials, synthesis of new materials, production of

Introduction to the molecular-transport equations of dilute gases / I. Oppenheim -- Derivation of hydrodynamic equations from the Boltzmann equation / Hans C. Andersen -- Transport in neutral gases / E.A. Mason -- Kinetic equations for fully ionized plasmas / C.M. Tschen -- The Boltzmann and Fokker-Planck equations / B. Lewis -- Calculations of transport coefficients in ionized gases / A.R. Hochstim and G.A. Massel -- Chemical reactions in high-temperature gases as collision processes / Felix T. Smith -- Rate coefficients, reaction cross sections, and microscopic reversibility / John Ross, John C. Light, and Kurt E. Schuler -- Triple collisions and termolecular reaction rates / Felix T. Smith -- Methods for calculating inelastic collision cross sections in low-energy collisions / Ernest Bauer.

In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.

This problems supplement to plasma physics textbooks covers plasma theory for both science and technology. Written by a renowned plasma scientist, experienced book author and skilled teacher, it treats all aspects of plasma theory in no fewer than 520 very detailed worked-out problems. With this systematic collection the reader will gain a sound understanding of plasma physics in all fields, from fusion and astrophysics to surface treatment. The book also includes the transport of particles as well as radiation in plasmas, and while designed for graduate students and young researchers, it can equally serve as a reference.