Operational Organic Chemistry

This comprehensive laboratory text provides a thorough introduction to all of the significant operations used in the organic lab and includes a large selection of traditional-scale and microscale experiments and minilabs. Its unique problem-solving approach encourages students to think in the laboratory by solving a scientific problem in the process of carrying out each experiment. The Second Edition contains a new introductory section, "Chemistry and the Environment," which includes a discussion of the principles of green chemistry. Several green experiments have been added, and some experiments from the previous editions have been revised to make them greener.

Preface To the Instructor Acknowledgments Introduction Problem Solving in the Organic Chemistry Laboratory Scientific Methodology Organization of This Book A Guide to Success in the Organic Chemistry Lab Laboratory Safety Safety Standards Protecting Yourself Preventing Laboratory Accidents Reacting to Accidents: First Aid Reacting to Accidents: Fire Chemical Hazards Finding and Using Chemical Safety Information Chemistry and the Environment Disposal of Hazardous Wastes Green Chemistry Part I Mastering the Operations 1 The Effect of pH on a Food Preservative 2 Separating the Components of ldquo;Panacetinrdquo; 3 Identifying a Constituent of ldquo;Panacetinrdquo; 4 Synthesis of Salicylic Acid from Wintergreen Oil 5 Preparation of Synthetic Banana Oil 6 Separation of Petroleum Hydrocarbons 7 A Green Synthesis of Camphor 8 Identification of a Petroleum Hydrocarbon 9 Isolation and Isomerization of Lycopene from Tomato Paste 10 Isolation and Identification of the Major Constituent of Clove Oil 11 Identification of Unknown Ketones 12 The Optical Activity of -Pinene: A Chemical Mystery Part II Correlated Laboratory Experiments 13 Investigation of a Chemical Bond by Infrared Spectrometry 14 Properties of Common Functional Groups 15 Thin-Layer Chromatographic Analysis of Drug Components 16 Separation of an Alkane Clathrate 17 Isomers and Isomerization Reactions 18 Structures and Properties of Stereoisomers 19 Bridgehead Reactivity in an S N 1 Solvolysis Reaction 20 Reaction of Iodoethane with Sodium Saccharin, an Ambident Nucleophile 21 Dehydration of Methylcyclohexanols and the Evelyn Effect 22 Testing Markovnikovrsquo;s Rule 23 Stereochemistry of Bromine Addition totrans-Cinnamic Acid 24 A Green Synthesis of Adipic Acid 25 Preparation of Bromotriphenylmethane and the Trityl Free Radical 26 Chain-Growth Polymerization of Styrene and Methyl Methacrylate 27 Synthesis of Ethanol by Fermentation 28 Reaction of Butanols with Hydrobromic Acid 29 Borohydride Reduction of Vanillin to Vanillyl Alcohol 30 Synthesis of Triphenylmethanol and the TritylCarbocation 31 An Unexpected Reaction of 2,3-Dimethyl-2,3-butanediol 32 Identification.

Organicum: Practical Handbook of Organic Chemistry focuses on the theory, laboratory practice, and aspects of technical use related to organic chemistry. This book discusses the standard apparatus for organic reactions, heating of inflammable liquids, performance of a simple distillation, and partition chromatography in separating columns. The time factor in organic chemical reactions, distribution of the electron density in organic molecules, and synthesis of ethers from alkoxides or phenoxides are also elaborated. This text likewise covers the mechanism of electrophilic aromatic substitution, quinones from aromatic hydrocarbons, and reduction of carbonyl compounds by means of complex hydrides. Other topics include the reaction with ammoniacal solution of a silver salt, preparation of the dimedone derivatives, and saturated aliphatic hydrocarbons. This publication is suitable for chemists and researchers conducting work in organic chemistry.

Detailing the latest rules and international practice, this new volume can be considered a guide to the essential organic chemical nomenclature, commonly described as the "Blue Book."

Environmental Organic Chemistry focuses on environmental factors that govern the processes that determine the fate of organic chemicals in natural and engineered systems. The information discovered is then applied to quantitatively assessing the environmental behaviour of organic chemicals. Now in its 2nd edition this book takes a more holistic view on physical-chemical properties of organic compounds. It includes new topics that address aspects of gas/solid partitioning, bioaccumulation, and transformations in the atmosphere. Structures chapters into basic and sophisticated sections Contains illustrative examples, problems and case studies Examines the fundamental aspects of organic, physical and inorganic chemistry - applied to environmentally relevant problems Addresses problems and case studies in one volume

In Organic Chemistry, 3rd Edition, Dr. David Klein builds on the phenomenal success of the first two editions, which presented his unique skills-based approach to learning organic chemistry. Dr. Klein’s skills-based approach includes all of the concepts typically covered in an organic chemistry textbook, and places special emphasis on skills development to support these concepts. This emphasis on skills development in unique SkillBuilder examples provides extensive opportunities for two-semester Organic Chemistry students to develop proficiency in the key skills necessary to succeed in organic chemistry.

This updated revision offers total coverage of organic laboratory experiments and techniques focusing on modern laboratory instrumentation, a strong emphasis on lab safety, additional concentration on sequential reaction sequences, excellent pre- and post-lab exercises, and multistep experiments which maximize the number of manipulations students perform per lab period. The microscale approach is low in cost, offers ease of doing experiments and uses minimal amounts of chemicals. A number of experiments include instructions for scaling up.