Laser Ablation Icp Ms In The Earth Sciences

Accompanying CD-ROM titled: "Short course volume 29, 2001 (to accompany Short course 40, 2008)".

Accompanying CD-ROM titled: "Short course volume 29, 2001 (to accompany Short course 40, 2008)".

This book explores different aspects of LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry). It presents a large array of new analytical protocols for elemental or isotope analysis. LA-ICP-MS is a powerful tool that combines a sampling device able to remove very small quantities of material without leaving visible damage at the surface of an object. Furthermore, it functions as a sensitive analytical instrument that measures, within a few seconds, a wide range of isotopes in inorganic samples. Determining the elemental or the isotopic composition of ancient material is essential to address questions related to ancient technology or provenance and therefore aids archaeologists in reconstructing exchange networks for goods, people and ideas. Recent improvements of LA-ICP-MS have opened new avenues of research that are explored in this volume.

This volume brings together for the first time a collection of papers that specifically describe laser ablation, methods for data quantification, and applications to archaeological questions.

Edited by two very well-known and respected scientists in the field, this excellent practical guide is the first to cover the fundamentals and a wide range of applications, as well as showing readers how to efficiently use this increasingly important technique. From the contents: * The Isotopic Composition of the Elements * Single-Collector ICP-MS * Multi-Collector ICP-MS * Advances in Laser Ablation - Multi-Collector ICP-MS * Correction for Instrumental Mass Discrimination in Isotope Ratio Determination with Multi-Collector ICP-MS * Reference Materials in Isotopic Analysis * Quality Control in Isotope Ratio Applications * Determination of Trace Elements and Elemental Species Using Isotope Dilution ICP-MS * Geochronological Dating * Application of Multi-Collector ICP-MS to Isotopic Analysis in Cosmochemistry * Establishing the Basis for Using Stable Isotope Ratios of Metals as Paleoredox Proxies * Isotopes as Tracers of Elements Across the Geosphere-Biosphere Interface * Archaeometric Applications * Forensics Applications * Nuclear Applications * The Use of Stable Isotope Techniques for Studying Mineral and Trace Element Metabolism in Humans * Isotopic Analysis via Multi-Collector ICP-MS in Elemental Speciation A must-have for newcomers as well as established scientists seeking an overview of isotopic analysis via ICP-MS.

The first scientific volume to compile the modern analytical techniques for glass analysis, Modern Methods for Analysing Archaeological and Historical Glass presents an up-to-date description of the physico-chemical methods suitable for determining the composition of glass and for speciation of specific components. This unique resource presents members of Association Internationale pour l'Histoire du Verre, as well as university scholars, with a number of case studies where the effective use of one or more of these methods for elucidating a particular culturo-historical or historo-technical aspect of glass manufacturing technology is documented.

The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.

Petrochronology is a rapidly emerging branch of Earth science that links time (ages or rates) with specific rock-forming processes and their physical conditions. It is founded in petrology and geochemistry, which define a petrogenetic context or delimit a specific process, to which chronometric data are then linked. This combination informs Earth’s petrogenetic processes better than petrology or geochronology alone. This volume and the accompanying short courses address three broad categories of inquiry. Conceptual approaches chapters include petrologic modeling of multi-component chemical and mineralogic systems, and development of methods that include diffusive alteration of mineral chemistry. Methods chapters address four main analytical techniques, specifically EPMA, LA-ICP-MS, SIMS and TIMS. Mineral-specific chapters explore applications to a wide range of minerals, including zircon (metamorphic, igneous, and detrital/Hadean), baddeleyite, REE minerals (monazite, allanite, xenotime and apatite), titanite, rutile, garnet, and major igneous minerals (olivine, plagioclase and pyroxenes). These applications mainly focus on metamorphic, igneous, or tectonic processes, but additionally elucidate fundamental transdisciplinary progress in addressing mechanisms of crystal growth, the chemical consequences of mineral growth kinetics, and how chemical transport and deformation affect chemically complex mineral composites. Most chapters further recommend areas of future research.