Kinetics In Nanoscale Materials

As the ability to produce nanomaterials advances, it becomes more important to understand how the energy of the atoms in these materials is affected by their reduced dimensions. Written by an acclaimed author team, Kinetics in Nanoscale Materials is the first book to discuss simple but effective models of the systems and processes that have recently been discovered. The text, for researchers and graduate students, combines the novelty of nanoscale processes and systems with the transparency of mathematical models and generality of basic ideas relating to nanoscience and nanotechnology.

The Advances in Chemical Physics series—the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Kinetics and thermodynamics of fluctuation-induced transitions in multistable systems (G. Nicolis and C. Nicolis) Dynamical rare event simulation techniques for equilibrium and nonequilibrium systems (Titus S. van Erp) Confocal depolarized dynamic light scattering (M. Potenza, T. Sanvito, V. Degiorgio, and M. Giglio) The two-step mechanism and the solution-crystal spinodal for nucleation of crystals in solution (Peter G. Vekilov) Experimental studies of two-step nucleation during two-dimensional crystallization of colloidal particles with short-range attraction (John R. Savage, Liquan Pei, and Anthony D. Dinsmore) On the role of metastable intermediate states in the homogeneous nucleation of solids from solution (James F. Lutsko) Effects of protein size on the high-concentration/low-concentration phase transition (Patrick Grosfils) Geometric constraints in the self-assembly of mineral dendrites and platelets (John J. Kozak) What can mesoscopic level in situ observations teach us about kinetics and thermodynamics of protein crystallization? (Mike Sleutel, Dominique Maes, and Alexander Van Driessche) The ability of silica to induce biomimetic crystallization of calcium carbonate (Matthias Kellermeier, Emilio Melero-GarcÍa, Werner Kunz, and Juan Manuel GarcÍa-Ruiz)

Supported by over 90 illustrations, this timely resource offers you a broad introduction to nanomaterials, covering basic principles, technology, and cutting-edge applications. From quantum mechanics, band structure, surface chemistry, thermodynamics, and kinetics of nanomaterials, to nanomaterial characterization, nanoparticle synthesis, nanoelectronics, NEMS, and Nano-Bio materials, this groundbreaking volume offers you a solid understanding of a wide range of fundamental topics and brings you up-to-date with the latest developments in the field.

A comprehensive reference on nanoscale materials chemistry—now revised and updated. This extensive text provides twenty-two revised chapters on the preparations, applications, and characterization as well as the environmental and toxicological aspects of nanoscale materials, with an emphasis on the chemistry component. This Second Edition contains core topics including: New synthetic methods for nanomaterials Nanostructured solids Organized two- and three-dimensional nanocrystals Nanotubes, ribbons, and sheets Nanocatalysts, sorbents, and energy applications Unique physical properties of nanomaterials Photochemistry of nanomaterials Biological and environmental aspects of nanomaterials With input from top experts in the field, such as Bruce Dunn, Vicki Grassian, Warren Ford, and Chris Sorensen, among others, Nanoscale Materials in Chemistry presents a balanced survey of different topics in basic nanoparticle science, and includes helpful end-of-chapter questions and answers. Significantly expanded, the Second Edition remains a key text for understanding the fundamentals of nanoscale materials chemistry and a reliable resource for scientists and researchers.

The book on Advanced Chemical Kinetics gives insight into different aspects of chemical reactions both at the bulk and nanoscale level and covers topics from basic to high class. This book has been divided into three sections: (i) "Kinetics Modeling and Mechanism," (ii) "Kinetics of Nanomaterials," and (iii) "Kinetics Techniques." The first section consists of six chapters with a variety of topics like activation energy and complexity of chemical reactions; the measurement of reaction routes; mathematical modeling analysis and simulation of enzyme kinetics; mechanisms of homogeneous charge compression ignition combustion for the fuels; photophysical processes and photochemical changes; the mechanism of hydroxyl radical, hydrate electron, and hydrogen atom; and acceptorless alcohol dehydrogenation. The understanding of the kinetics of nanomaterials, to bridge the knowledge gap, is presented in the second section. The third section highlights an overview of experimental techniques used to study the mechanism of reactions.

Since its emergence in the 1980s, nanoscience and nanotechnology research areas are rapidly expanding. It contributes to a broad range of fields from chemistry, physics, biology, and materials science to various engineering. Nowadays, nanomaterials have already come into almost every field of our lives, such as electronics, energy converting and storage, and biomedicines. Especially, after graphene was discovered in 2004, two-dimensional (2D) materials attracted an increased interest. There is a boost in the research on controlling nanostructures and manipulating their properties. The bottom-up approach using individual atoms and molecules as building blocks to construct nanoscale materials and structures offers an opportunity to create new 2D structures or phases that don't exist in the bulk. A generic synthetic method with structure control and property engineering is highly desired for exploring 2D materials' unique properties. The air-water interface is an ideal 2D environment for the controllable synthesis of 2D materials. By employing a monolayer of self-assembled ionized amphiphilic molecules as a soft template at the air-water interface, 2D nanocrystals form in the electrical double-layer confined region and grow epitaxially directed by soft template packings. Therefore, this synthesis technique was named the ionic layer epitaxy (ILE). This dissertation focuses on the study of this 2D materials synthesis system at the air-water interface, including the growth kinetics and mechanism investigations, facet and thickness control, element and defect manipulation, and the advanced application of these 2D materials in electrochemical, physical and biological fields.

"Kinetics and Dynamics" on molecular modeling of dynamic processes opens with an introductory overview before discussing approaches to reactivity of small systems in the gas phase. Then it examines studies of systems of increasing complexity up to the dynamics of DNA. This title has interdisciplinary character presenting wherever possible an interplay between the theory and the experiment. It provides basic information as well as the details of theory and examples of its application to experimentalists and theoreticians interested in modeling of dynamic processes in chemical and biochemical systems. All contributing authors are renowned experts in their fields and topics covered in this volume represent the forefront of today’s science.

The Advances in Chemical Physics series—the cuttingedge of research in chemical physics The Advances in Chemical Physics series provides thechemical physics and physical chemistry fields with a forum forcritical, authoritative evaluations of advances in every area ofthe discipline. Filled with cutting-edge research reported in acohesive manner not found elsewhere in the literature, each volumeof the Advances in Chemical Physics series presents contributionsfrom internationally renowned chemists and serves as the perfectsupplement to any advanced graduate class devoted to the study ofchemical physics. This volume explores: Kinetics and thermodynamics of fluctuation-induced transitionsin multistable systems (G. Nicolis and C. Nicolis) Dynamical rare event simulation techniques for equilibrium andnonequilibrium systems (Titus S. van Erp) Confocal depolarized dynamic light scattering (M. Potenza, T.Sanvito, V. Degiorgio, and M. Giglio) The two-step mechanism and the solution-crystal spinodal fornucleation of crystals in solution (Peter G. Vekilov) Experimental studies of two-step nucleation duringtwo-dimensional crystallization of colloidal particles withshort-range attraction (John R. Savage, Liquan Pei, and Anthony D.Dinsmore) On the role of metastable intermediate states in the homogeneousnucleation of solids from solution (James F. Lutsko) Effects of protein size on thehigh-concentration/low-concentration phase transition (PatrickGrosfils) Geometric constraints in the self-assembly of mineral dendritesand platelets (John J. Kozak) What can mesoscopic level in situ observations teach us aboutkinetics and thermodynamics of protein crystallization? (MikeSleutel, Dominique Maes, and Alexander Van Driessche) The ability of silica to induce biomimetic crystallization ofcalcium carbonate (Matthias Kellermeier, Emilio Melero-GarcÍa,Werner Kunz, and Juan Manuel GarcÍa-Ruiz)

An outstanding feature of this book is a collection of state-of-the-art reviews written by leading researchers in the nanomechanics of carbon nanotubes, nanocrystalline materials, biomechanics and polymer nanocomposites. The structure and properties of carbon nanotubes, polycrystalline metals, and coatings are discussed in great details. The book is an exceptional resource on multi-scale modelling of metals, nanocomposites, MEMS materials and biomedical applications. An extensive bibliography concerning all these topics is included. Highlights on bio-materials, MEMS, and the latest multi-scale methods (e.g., molecular dynamics and Monte Carlo) are presented. Numerous illustrations of inter-atomic potentials, nanotube deformation and fracture, grain rotation and growth in solids, ceramic coating structures, blood flows and cell adhesion are discussed. This book provides a comprehensive review of latest developments in the analysis of mechanical phenomena in nanotechnology and bio-nanotechnology.

A multidisciplinary approach that explores the diverse properties, functions, and applications of nanomaterials Drawing together the many scientific and engineering disciplines underlying the development of nanomaterials, Nanoscale Multifunctional Materials provides a multidisciplinary review of the diverse properties, functions, and applications of nanomaterials. The book examines both nanoparticles, which have larger-scale equivalents, and uniquely assembled nanomaterials, which do not have larger-scale equivalents. Readers will gain a tremendous appreciation of the versatility of nanomaterials as well as an understanding of how the same nanomaterial can have several distinct applications across a broad range of fields and industries. Nanoscale Multifunctional Materials is divided into three sections: Section I, Overview, describes the scientific phenomena underlying the special properties of nanomaterials, making them desirable as novel materials and different from conventional solids. Next, readers will learn about the effect of nanomaterials on contemporary society as well as future trends in nanomaterials production and use. Section II, Processing and Analysis, explores several experimental approaches in nanomaterial fabrication and characterization as well as in theoretical approaches in modeling and simulation. Section III, Applications, offers detailed examples of nanomaterial applications in alternative energy, thermal management, environmental cleanup, water treatment, and biomedicine. Each chapter has been written by one or more leading experts in the science, engineering, and application of nanomaterials. Within each chapter, readers will find a thorough review of the current literature, with references to facilitate further investigation of individual topics. Underscoring the multidisciplinary and multifunctional characteristics of nanomaterials, this book is recommended for students and professionals in science and engineering who need a broad perspective on both the nature and application of nanomaterials. The text also sets the stage for the development of new nanomaterials and new applications.