Isotopic Constraints On Earth System Processes

Using isotopes as a tool for understanding Earth processes From establishing the absolute age of the Earth to providing a stronger understanding of the nexus between geology and life, the careful measurement and quantitative interpretation of minor variations in the isotopic composition of Earth’s materials has provided profound insight into the origins and workings of our planet. Isotopic Constraints on Earth System Processes presents examples of the application of numerous different isotope systems to address a wide range of topical problems in Earth system science. Volume highlights include: examination of the natural fractionation of non-traditional stable isotopes utilizing isotopes to understand the origin of magmas and evolution of volcanic systems application of isotopes to interrogate and understand Earth’s Carbon and Oxygen cycles examination of the geochemical and hydrologic processes that lead to isotopic fractionation application of isotopic reactive transport models to decipher hydrologic and biogeochemical processes The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals.

Using isotopes as a tool for understanding Earth processes From establishing the absolute age of the Earth to providing a stronger understanding of the nexus between geology and life, the careful measurement and quantitative interpretation of minor variations in the isotopic composition of Earth’s materials has provided profound insight into the origins and workings of our planet. Isotopic Constraints on Earth System Processes presents examples of the application of numerous different isotope systems to address a wide range of topical problems in Earth system science. Volume highlights include: examination of the natural fractionation of non-traditional stable isotopes utilizing isotopes to understand the origin of magmas and evolution of volcanic systems application of isotopes to interrogate and understand Earth’s Carbon and Oxygen cycles examination of the geochemical and hydrologic processes that lead to isotopic fractionation application of isotopic reactive transport models to decipher hydrologic and biogeochemical processes The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals.

Stable isotope ratio variation in natural systems reflects the dynamics of Earth systems processes and imparts isotope labels to Earth materials. Carbon isotope ratios of atmospheric CO2 record exchange of carbon between the biosphere and the atmosphere; the incredible journeys of migrating monarchs is documented by hydrogen isotopes in their wings; and water carries an isotopic record of its source and history as it traverses the atmosphere and land surface. Through these and many other examples, improved understanding of spatio-temporal isotopic variation in Earth systems is leading to innovative new approaches to scientific problem-solving. This volume provides a comprehensive overview of the theory, methods, and applications that are enabling new disciplinary and cross-disciplinary advances through the study of "isoscapes": isotopic landscapes. "This impressive new volume shows scientists deciphering and using the natural isotope landscapes that subtly adorn our spaceship Earth.", Brian Fry, Coastal Ecology Institute, Louisiana State University, USA "An excellent timely must read and must-have reference book for anybody interested or engaged in applying stable isotope signatures to questions in e.g. Anthropology, Biogeochemistry, Ecology, or Forensic Science regarding chronological and spatial movement, changes, or distribution relating to animals, humans, plants, or water.", Wolfram Meier-Augenstein, Centre for Anatomy & Human Identification, University of Dundee, UK "Natural resources are being affected by global change, but exactly where, how, and at what pace? Isoscapes provide new and remarkably precise answers.", John Hayes, Woods Hole Oceanographic Institution, USA "This exciting volume is shaping a new landscape in environmental sciences that is utilizing the remarkable advances in isotope research to enhance and extend the capabilities of the field.", Dan Yakir, Weizmann Institute of Science, Israel

The Earth formed some 4.5 Ga from the accumulation of dust, rocks and gas. The composition of these primitive materials is today recorded in meteorites. However, the origin of volatile elements within the atmosphere (e.g., H, C, N, O) remains poorly understood. By combining experimental approaches and the analysis of natural samples, I studied the composition of celestial objects comprising the ingredients required for the formation of the terrestrial atmosphere. These mainly correspond to volatile elements trapped in meteoritic organic materials and in the ice of cometary bodies. In order to better understand the timeline of Earth's formation and volatile accretion, I used noble gases (He, Ne, Ar, Kr, Xe) as tracers of the physical processes that occurred in the early Solar System and on primitive Earth. Whilst comets significantly contributed to the heavy noble gas budget of the terrestrial atmosphere (~20%), most of the other terrestrial volatile elements (including water, carbon and nitrogen) would have been supplied to Earth by chondrtitic bodies similar to meteorites. Once formed, the atmosphere evolved over geological periods of time, leading to the establishment of suitable environmental conditions for life to develop. The major processes that affected the mass and composition of the ancient atmosphere can be studied by investigating the isotopic evolution of atmospheric Xe, from 4.5 Ga to ~2 Ga. We investigate the possibility to bring constraints on the age of organic materials isolated from sedimentary ricks older than 2 Ga, using the isotopic signature of the Xe component that was trapped at the time of their formation. This method could have implications regarding the presumed age of the earliest remnants of organic life.

Volume 16 of Reviews in Mineralogy inroduces to high-temperature stable isotope geochemistry and should provide an entry into the pertinent literature, as well as some understanding of the basic concepts and potential applications. The first three chapters focus on the theory and experimental data base for equilibrium, disequilibrium, and kinetics of stable isotope exchange reactions among geologically important minerals and fluids. The fourth chapter discusses the primordial oxygen isotope variations in the solar system prior to formation of the Earth, along with a discussion of isotopic anomalies in meteorites. The fifth chapter discusses isotopic variations in the Earth's mantle and the sixth chapter reviews the variations in the isotopic compositions of natural waters on our planet. In Chapters 7, 8, 9 and 10, these isotopic constraints and concepts are applied to various facets of the origin and evolution of igneous rocks, bringing in much material on radiogenic isotopes as well, because these problems require a multi-dimensional attack for their solution. In Chapters 11 and 12, the problems of hydrothermal alteration by meteoric waters and ocean water are considered, together with discussions of the physics and chemistry of hydrothermal systems and the 18O/16O history of ocean water. Finally, in Chapters 13 and 14, these concepts are applied to problems of metamorphic petrology and ore deposits, particularly with respect to the origins of the fluids involved in those processes.

Stable isotope ratio variation in natural systems reflects the dynamics of Earth systems processes and imparts isotope labels to Earth materials. Carbon isotope ratios of atmospheric CO2 record exchange of carbon between the biosphere and the atmosphere; the incredible journeys of migrating monarchs is documented by hydrogen isotopes in their wings; and water carries an isotopic record of its source and history as it traverses the atmosphere and land surface. Through these and many other examples, improved understanding of spatio-temporal isotopic variation in Earth systems is leading to innovative new approaches to scientific problem-solving. This volume provides a comprehensive overview of the theory, methods, and applications that are enabling new disciplinary and cross-disciplinary advances through the study of "isoscapes": isotopic landscapes. "This impressive new volume shows scientists deciphering and using the natural isotope landscapes that subtly adorn our spaceship Earth." Brian Fry, Coastal Ecology Institute, Louisiana State University, USA "An excellent timely must read and must-have reference book for anybody interested or engaged in applying stable isotope signatures to questions in e.g. Anthropology, Biogeochemistry, Ecology, or Forensic Science regarding chronological and spatial movement, changes, or distribution relating to animals, humans, plants, or water." Wolfram Meier-Augenstein, Centre for Anatomy & Human Identification, University of Dundee, UK "Natural resources are being affected by global change, but exactly where, how, and at what pace? Isoscapes provide new and remarkably precise answers." John Hayes, Woods Hole Oceanographic Institution, USA "This exciting volume is shaping a new landscape in environmental sciences that is utilizing the remarkable advances in isotope research to enhance and extend the capabilities of the field." Dan Yakir, Weizmann Institute of Science, Israel.

Published by the American Geophysical Union as part of the Geophysical Monograph Series, Volume 95. Publication of this monograph will coincide, to a precision of a few per mil, with the centenary of Henri Becquerel's discovery of "radiations actives" (C. R. Acad. Sci., Feb. 24, 1896). In 1896 the Earth was only 40 million years old according to Lord Kelvin. Eleven years later, Boltwood had pushed the Earth's age past 2000 million years, based on the first U/Pb chemical dating results. In exciting progression came discovery of isotopes by J. J. Thomson in 1912, invention of the mass spectrometer by Dempster (1918) and Aston (1919), the first measurement of the isotopic composition of Pb (Aston, 1927) and the final approach, using Pb-Pb isotopic dating, to the correct age of the Earth: close-2.9 Ga (Gerling, 1942), closer-3.0 Ga (Holmes, 1949) and closest-4.50 Ga (Patterson, Tilton and Inghram, 1953).

Handbook of Environmental Isotope Geochemistry, Volume 2: The Terrestrial Environment, B focuses on the processes, methodologies, principles, and approaches involved in isotope geochemistry. The selection first elaborates on mathematical models for the interpretation of environmental radioisotopes in groundwater systems; isotopes in cloud physics; and environmental isotopes in lake studies. Discussions focus on water balance studies of lakes, isotopic fractionations during evaporation of water, study of hailstone growth mechanisms by means of isotopic analyses, isotopic effects during growth of individual elements, and models and their hydrological significance. The text then takes a look at environmental isotope and anthropogenic tracers of lake sedimentation; stable isotope geochemistry of travertines; and isotope geochemistry of carbonates in the weathering zone. Topics include isotopic composition of carbonates in the weathering zone; reprecipitation processes in the weathering zone; isotopic composition of carbon and oxygen sources in the weathering zone; and geochemical conditions controlling travertine deposition. The manuscript also reviews radioactive noble gases in the terrestrial environment, isotope effects of nitrogen in the soil and biosphere, and oxygen and hydrogen isotope geochemistry of deep basin brines. The selection is a vital source of data for researchers interested in isotope geochemistry.

The emerging multidisciplinary field of earth system science sets out to improve our understanding functioning ecosystems, at a global level across the entire planet. Stable Isotopes and Biosphere - Atmosphere Interactions looks to one of its most powerful tools — the application of stable isotope analyses — to understanding biosphere-atmosphere exchange of the greenhouse gases, and synthesizes much of the recent progress in this work. Stable Isotopes and Biosphere - Atmosphere Interactions describes recent progress in understanding the mechanisms, processes and applications of new techniques. It makes a significant contribution to the emerging, multidisciplinary study of the Earth as an interacting system. This book will be an important reference for students and researchers in biology, ecology, biogeochemistry, meteorology, and atmospheric science and will be invaluable for anyone with any interest in the future of the planet. Describes applications of new stable isotope techniques to the emerging fields of earth system science and global change Illustrates advances in scaling of physiological processes from leaf/soil to the global scale Contains state-of-the-art, critical reviews written by international researchers and experts