Irreversible Processes

University Physics is designed for the two- or three-semester calculus-based physics course. The text has been developed to meet the scope and sequence of most university physics courses and provides a foundation for a career in mathematics, science, or engineering. The book provides an important opportunity for students to learn the core concepts of physics and understand how those concepts apply to their lives and to the world around them. Due to the comprehensive nature of the material, we are offering the book in three volumes for flexibility and efficiency. Coverage and Scope Our University Physics textbook adheres to the scope and sequence of most two- and three-semester physics courses nationwide. We have worked to make physics interesting and accessible to students while maintaining the mathematical rigor inherent in the subject. With this objective in mind, the content of this textbook has been developed and arranged to provide a logical progression from fundamental to more advanced concepts, building upon what students have already learned and emphasizing connections between topics and between theory and applications. The goal of each section is to enable students not just to recognize concepts, but to work with them in ways that will be useful in later courses and future careers. The organization and pedagogical features were developed and vetted with feedback from science educators dedicated to the project. VOLUME II Unit 1: Thermodynamics Chapter 1: Temperature and Heat Chapter 2: The Kinetic Theory of Gases Chapter 3: The First Law of Thermodynamics Chapter 4: The Second Law of Thermodynamics Unit 2: Electricity and Magnetism Chapter 5: Electric Charges and Fields Chapter 6: Gauss's Law Chapter 7: Electric Potential Chapter 8: Capacitance Chapter 9: Current and Resistance Chapter 10: Direct-Current Circuits Chapter 11: Magnetic Forces and Fields Chapter 12: Sources of Magnetic Fields Chapter 13: Electromagnetic Induction Chapter 14: Inductance Chapter 15: Alternating-Current Circuits Chapter 16: Electromagnetic Waves

The book presents a clear exposition of the basic formalism applicable to nonlinear thermodynamic processes at a mathematical level accessible to physicists and theoretically inclined chemists and biologists. Examples are given to show how the formalism may be applied in a variety of physical and biological situations.

Kinetic Theory, Volume 2: Irreversible Processes deals with the kinetic theory of gases and the irreversible processes they undergo. It includes the two papers by James Clerk Maxwell and Ludwig Boltzmann in which the basic equations for transport processes in gases are formulated, together with the first derivation of Boltzmann's "H-theorem" and a discussion of this theorem, along with the problem of irreversibility. Comprised of 10 chapters, this volume begins with an introduction to the fundamental nature of heat and of gases, along with Boltzmann's work on the kinetic theory of gases and statistical mechanics. Energy dissipation, the statistical nature of the second law of thermodynamics, and the eternal return and the recurrence paradox are also considered. The first chapter examines the dynamical theory of gases and its application to the explanation of various properties of gases; the known chemical relation between the density of a gas and its equivalent weight, commonly called the Law of Equivalent Volumes; and the diffusion of one gas through another. Subsequent chapters focus on the thermal equilibrium of gas molecules; the three-body problem and the equations of dynamics; the mechanical theory of heat; and the relation of a general mechanical theorem to the second law of thermodynamics. A mechanical explanation of irreversible processes is also offered. This book will be useful for students of physics at the advanced undergraduate or beginning postgraduate level.

Despite a long history of almost 180 years stretching back to the times of Carnot and, later, Clausius and Lord Kelvin, amongst others following him, the subject of thermodynamics has not as yet seen its full maturity, in the sense that the theory of irreversible processes has remained incomplete. The works of L. Onsager, J. Meixner, I. Prigogine on the thermodyn- ics of linear irreversible processes are, in effect, the early efforts toward the desired goal of giving an adequate description of irreversible processes, but their theory is confined to near-equilibrium phenomena. The works in recent years by various research workers on the extension of the aforem- tioned thermodynamic theory of linear irreversible processes are further efforts toward the goal mentioned. The present work is another of such efforts and a contribution to the subject of generalizing the thermodyn- ics of reversible processes, namely, equilibrium thermodynamics, to that of irreversible processes—non-equilibrium thermodynamics, without being restricted to linear irreversible processes. In this context the terms ‘far - moved from equilibrium’ is often used in the literature, and such states of macroscopic systems and non-linear irreversible phenomena in them are the objects of interest in this work. The thermodynamics of processes, either reversible or irreversible, is a continuum mechanical theory of matter and energy and their exchange between different parts of the system, and as such it makes no direct r- erence to the molecules constituting the substance under consideration.

Statistical mechanics has been proven to be successful at describing physical systems at thermodynamic equilibrium. Since most natural phenomena occur in nonequilibrium conditions, the present challenge is to find suitable physical approaches for such conditions: this book provides a pedagogical pathway that explores various perspectives. The use of clear language, and explanatory figures and diagrams to describe models, simulations and experimental findings makes the book a valuable resource for undergraduate and graduate students, and also for lecturers organizing teaching at varying levels of experience in the field. Written in three parts, it covers basic and traditional concepts of nonequilibrium physics, modern aspects concerning nonequilibrium phase transitions, and application-orientated topics from a modern perspective. A broad range of topics is covered, including Langevin equations, Levy processes, directed percolation, kinetic roughening and pattern formation.

These Proceedings contain invited lectures presented at the third Interna tional Conference on "Irreversible Processes and Dissipative Structures" in Kiihlungsborn (German Democratic Republic) in March, 1985. These con ferences, the first of which was held in Rostock in 1977 and the second in Berlin in 1982, are devoted to the study of irreversible processes far from thermal equilibrium and to the phenomena of selforganization. The meet ing in Kiihlungsborn brought together some 160 mathematicians, physicists, chemists and biologists from 10 countries, who are all interested in the inter disciplinary field of synergetics. The main topics of the conference were basic concepts of selforganization and evolution, such as entropy, instabilities, nucleation, dissipative struc tures, chaos and turbulence. The contributions cover methods from ther modynamics, the theory of dynamic systems, stochastic and statistic theory, the method of Green's functions, the fluctuation-dissipation theorem, etc. Several problems are studied in more detail, e.g., the kinetics of nucleation especially in finite systems, the dynamics of interfaces, reaction-diffusion sys tems, chemical and biochemical pattern formation and information process ing. Further, several contributions are devoted to the development of the concepts of chaos and turbulence. The editors hope that the contributions collected in this volume will pro vide some new information about the field of selforganization, which is in full development now.

Covering essential areas of thermal physics, this book includes kinetic theory, classical thermodynamics, and quantum thermodynamics. The text begins by explaining fundamental concepts of the kinetic theory of gases, viscosity, conductivity, diffusion, and the laws of thermodynamics and their applications. It then goes on to discuss applications of thermodynamics to problems of physics and engineering. These applications are explained with the help of P-V and P-S-H diagrams where necessary and are followed by a large number of solved examples and unsolved exercises. The book includes a dedicated chapter on the applications of thermodynamics to chemical reactions. Each application is explained by taking the example of an appropriate chemical reaction, where all technical terms are explained and complete mathematical derivations are worked out in steps starting from the first principle.