Inorganic And Organometallic Polymers

This book has its origins in courses taught by the author to various und- graduate and graduate students at the Indian Institute of Technology, K- pur, India. The diversity of inorganic chemistry and its impact on polymer chemistry has been profound. This subject matter has grown considerably in the last decade and the need to present it in a coherent manner to young minds is a pedagogic challenge. The aim of this book is to present to the students an introduction to the developments in Inorganic and - ganometallic polymers. This book is divided into eight chapters. Chapter 1 provides a general overview on the challenges of Inorganic polymer synthesis. This is f- lowed by a survey of organic polymers and also includes some basic f- tures of polymers. Chapters 3-8 deal with prominent families of inorganic and organometallic polymers. Although the target group of this book is the undergraduate and graduate students of chemistry, chemical engineering and materials science it is also hoped that chemists and related scientists in industry would find this book useful. I am extremely thankful to my wife Sudha who not only encouraged me throughout but also drew all the Figures and Schemes of this book. I also thank my children Adithya and Aarathi for their constant concern on the progress of this book. I express my acknowledgment to the editorial team of Springer-Verlag for their cooperation.

The book covers silicon, phosphorus, sulfur, tin and germanium based inorganic polymers. It also includes chapters on organometallic polymers, transition metal based coordination polymers and geopolymers. The book is ideal for students and career starters in the industry.

A balanced and concise coverage of inorganic polymers Inorganic polymers contain elements other than carbon as part of their principal backbone structure and are known to exhibit a wide range of composition and structure. Emphasizing physical properties, chemical synthesis, and characterization of inorganic polymers, Inorganic and Organometallic Polymers presents valuable and informative coverage of the field. With numerous examples of real-world practical applications and end-of-chapter exercises, Inorganic and Organometallic Polymers is suitable for use as a text in special topics in organic and polymer chemistry courses. The book features useful sections on: Classification schemes for inorganic polymers Synthesis of inorganic polymers, including step-growth syntheses, chain polymerizations, ring-opening polymerizations, and reductive coupling reactions Practical inorganic polymer chemistry topics such as polymer elastomers, dental and medical polymers, lubricants, lithographic resists, pre-ceramics, and more Inorganic and Organometallic Polymers is a valuable one-volume introduction for professional and student inorganic chemists, polymer chemists, and materials scientists.

Proceedings of the NATO Advanced Research Workshop, Cap d'Agde, France, September 9-14, 1990

Inorganic and organometallic polymers feature many attractive properties that are useful for the design of diverse functional materials. Emphasising concepts that inform polymer design, synthesis and applications, readers of this book will gain a complete understanding of the introduction to inorganic and organometallic polymer science that will further their studies in materials science, chemistry and engineering. The first chapter lays down the core concepts that the book builds from, including polymerisation and naming conventions. It also reveals why some organometallic polymers are better suited than organic polymers in certain applications. Subsequent chapters discuss the chemistry of metals in particular the transition metals as they relate to polymer properties, before walking the reader through in-depth chapters on synthesis, structure, properties, characterization, and examples of inorganic and organometallic polymers. The final chapter presents applications of these polymers in diverse fields ranging from biomedicine, energy to catalysis. Worked examples and exercises are provided at the end of each chapter to assist students in assessing their understanding of these concepts, and journal references are included to direct students to published literature related to inorganic and organometallic polymers. Ideal for lecturers teaching a one semester advanced undergraduate and graduate courses in polymer science, as well as for self-study researchers and industrial chemists that are working with polymers, this book provides the user with a complete and expert grounding to the field.

The focus of the book is monocyclic inorganic ring systems of the p-block elements and the polymers that are, in many cases, derived from them. Bicyclic or polycyclic arrangements are considered when they are closely related to those of monocyclic systems.

This book Graph Theory is intended the typical-freshman or sophomore in computer science and related disciplines with a first exposure to the mathematical topics essential to their study of computer science or digital logic. There is an introduction of graph and tree in this book. This focus on the description of basic problems involving graph and tree and their applications. A major feature of this text is its versatility. Sufficient topics have been included to accommodate students with varied background. Contents: Graph Theory, Group Theory and Applications, Algebraic Systems, Trees and Probability.

Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells Foscuses on the fundamentals and their potential therapeutic and diagnostic applications Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents

Provides complete and undiluted knowledge on making inorganic polymers functional. This comprehensive book reflects the state of the art in the field of inorganic polymers, based on research conducted by a number of internationally leading research groups working in this area. It covers the synthesis aspects of synthetic inorganic polymers and looks at multiple inorganic monomers as building blocks, which exhibit unprecedented electronic, redox, photo-emissive, magnetic, self-healing and catalytic properties. It also looks at the applications of inorganic polymers in areas such as optoelectronics, energy storage, industrial chemistry, and biology. Beginning with an overview of the use of smart inorganic polymers in daily life, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences goes on to study the synthesis, properties, and applications of polymers incorporating different heteroelements such as boron, phosphorus, silicon, germanium, and tin. The book also examines inorganic polymers in flame-retardants, as functional materials, and in biology. An excellent addition to the polymer scientists' and synthetic chemists' toolbox Summarizes the state of the art on how to make and use functional inorganic polymers, from synthesis to applications Edited by the coordinator of a highly funded European community research program (COST action) that focuses specifically on the exploration of inorganic polymers Features contributions from top experts in the field Aimed at academics and industrial researchers in this field, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences will also benefit scientists who want to get a better overview on the state-of-the-art of this rapidly advancing area.