Hydrogen Production Technologies

Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.

Science and Engineering of Hydrogen-Based Energy Technologies explores the generation of energy using hydrogen and hydrogen-rich fuels in fuel cells from the perspective of its integration into renewable energy systems using the most sound and current scientific knowledge. The book first examines the evolution of energy utilization and the role expected to be played by hydrogen energy technologies in the world’s energy mix, not just for energy generation, but also for carbon capture, storage and utilization. It provides a general overview of the most common and promising types of fuel cells, such as PEMFCs, SOFCs and direct alcohol fuel cells. The co-production of chemical and electrolysis cells, as well as the available and future materials for fuel cells production are discussed. It then delves into the production of hydrogen from biomass, including waste materials, and from excess electricity produced by other renewable energy sources, such as solar, wind, hydro and geothermal. The main technological approaches to hydrogen storage are presented, along with several possible hydrogen energy engineering applications. Science and Engineering of Hydrogen-Based Energy Technologies’s unique approach to hydrogen energy systems makes it useful for energy engineering researchers, professionals and graduate students in this field. Policy makers, energy planning and management professionals, and energy analysts can also benefit from the comprehensive overview that it provides. Presents engineering fundamentals, commercially deployed technologies, up-and-coming developments and applications through a systemic approach Explores the integration of hydrogen technologies in renewable energy systems, including solar, wind, bioenergy and ocean energy Covers engineering standards, guidelines and regulations, as well as policy and social aspects for large-scale deployment of these technologies

Advances in Hydrogen Production, Storage and Distribution reviews recent developments in this key component of the emerging "hydrogen economy," an energy infrastructure based on hydrogen. Since hydrogen can be produced without using fossil fuels, a move to such an economy has the potential to reduce greenhouse gas emissions and improve energy security. However, such a move also requires the advanced production, storage and usage techniques discussed in this book. Part one introduces the fundamentals of hydrogen production, storage, and distribution, including an overview of the development of the necessary infrastructure, an analysis of the potential environmental benefits, and a review of some important hydrogen production technologies in conventional, bio-based, and nuclear power plants. Part two focuses on hydrogen production from renewable resources, and includes chapters outlining the production of hydrogen through water electrolysis, photocatalysis, and bioengineered algae. Finally, part three covers hydrogen production using inorganic membrane reactors, the storage of hydrogen, fuel cell technology, and the potential of hydrogen as a fuel for transportation. Advances in Hydrogen Production, Storage and Distribution provides a detailed overview of the components and challenges of a hydrogen economy. This book is an invaluable resource for research and development professionals in the energy industry, as well as academics with an interest in this important subject. Reviews developments and research in this dynamic area Discusses the challenges of creating an infrastructure to store and distribute hydrogen Reviews the production of hydrogen using electrolysis and photo-catalytic methods

The fields covered by the hydrogen energy topic have grown rapidly, and now it has become clearly multidisciplinary. In addition to production, hydrogen purification and especially storage are key challenges that could limit the use of hydrogen fuel. In this book, the purification of hydrogen with membrane technology and its storage in "solid" form using new hydrides and carbon materials are addressed. Other novelties of this volume include the power conditioning of water electrolyzers, the integration in the electric grid of renewable hydrogen systems and the future role of microreactors and micro-process engineering in hydrogen technology as well as the potential of computational fluid dynamics to hydrogen equipment design and the assessment of safety issues. Finally, and being aware that transportation will likely constitute the first commercial application of hydrogen fuel, two chapters are devoted to the recent advances in hydrogen fuel cells and hydrogen-fueled internal combustion engines for transport vehicles. Hydrogen from water and biomass considered Holistic approach to the topic of renewable hydrogen production Power conditioning of water electrolyzers and integration of renewable hydrogen energy systems considered Subjects not included in previous books on hydrogen energy Micro process technology considered Subject not included in previous books on hydrogen energy Applications of CFD considered Subject not included in previous books on hydrogen energy Fundamental aspects will not be discussed in detail consciously as they are suitably addressed in previous books Emphasis on technological advancements Chapters written by recognized experts Up-to date approach to the subjects and relevant bibliographic references

The announcement of a hydrogen fuel initiative in the President's 2003 State of the Union speech substantially increased interest in the potential for hydrogen to play a major role in the nation's long-term energy future. Prior to that event, DOE asked the National Research Council to examine key technical issues about the hydrogen economy to assist in the development of its hydrogen R&D program. Included in the assessment were the current state of technology; future cost estimates; CO2 emissions; distribution, storage, and end use considerations; and the DOE RD&D program. The report provides an assessment of hydrogen as a fuel in the nation's future energy economy and describes a number of important challenges that must be overcome if it is to make a major energy contribution. Topics covered include the hydrogen end-use technologies, transportation, hydrogen production technologies, and transition issues for hydrogen in vehicles.

Solar Hydrogen Production: Processes, Systems and Technologies presents the most recent developments in solar-driven hydrogen generation methods. The book covers different hydrogen production routes, from renewable sources, to solar harvesting technologies. Sections focus on solar energy, presenting the main thermal and electrical technologies suitable for possible integration into solar-based hydrogen production systems and present a thorough examination of solar hydrogen technologies, ranging from solar-driven water electrolysis and solar thermal methods, to photo-catalytic and biological processes. All hydrogen-based technologies are covered, including data regarding the state-of-the art of each process in terms of costs, efficiency, measured parameters, experimental analyses, and demonstration projects. In the last part of the book, the role of hydrogen in the integration of renewable sources in electric grids, transportation sector, and end-user applications is assessed, considering their current status and future perspectives. The book includes performance data, tables, models and references to available standards. It is thus a key-resource for engineering researchers and scientists, in both academic and industrial contexts, involved in designing, planning and developing solar hydrogen systems. Offers a comprehensive overview of conventional and advanced solar hydrogen technologies, including simulation models, cost figures, R&D projects, demonstration projects, test standards, and safety and handling issues Encompasses, in a single volume, information on solar energy and hydrogen systems Includes detailed economic data on each technology for feasibility assessment of different systems

This brief covers novel techniques for clean hydrogen production which primarily involve sodium hydroxide as an essential ingredient to the existing major hydrogen production technologies. Interestingly, sodium hydroxide plays different roles and can act as a catalyst, reactant, promoter or even a precursor. The inclusion of sodium hydroxide makes these processes both kinetically and thermodynamically favorable. In addition possibilities to produce cleaner hydrogen, in terms of carbon emissions, are described. Through modifications of steam methane reformation methods and coal-gasification processes, from fossil as well as non-fossil energy sources, the carbon dioxide emissions of these established ways to produce hydrogen can significantly be reduced. This brief is aimed at those who are interested in expanding their knowledge on novel techniques and materials to produce clean hydrogen and capture carbon dioxide at a large-scale. The detailed thermodynamic analysis, experimental findings and critical analysis of such techniques are well discussed in this brief. Therefore, this book will be of great interest and use to students, engineers and researchers involved in developing the hydrogen economy as well as mitigating carbon dioxide emissions at a large-scale.

Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems

This work presents a comprehensive investigation of the most significant renewable hydrogen production processes. Technical, economic and ecological studies are described for the processes of steam reforming of ethanol, natural gas and biogas; water electrolysis with energy from renewable sources (wind power, photovoltaic and hydroelectric), and hydrogen production using algae. Aimed at mechanical and chemical engineering graduate students and researchers involved in environmental sciences, sustainable energy and bioenergy research, this book introduces readers to the latest developments in the field and provides essential reference material for future research. The book first presents a comprehensive literature review of the processes studied. Subsequently, it provides a technical report on assessing the energetic efficiency for each hydrogen production process, as well as an economic study of the respective hydrogen production costs. Lastly, the ecological efficiency of each process is addressed. Over the past few decades, the UNESP’s Group of Optimization of Energetic Systems, headed by Professor José Luz Silveira, has been pursuing research in the field of renewable energy generation. A major part of the group’s research focuses on the production of hydrogen as a fuel and its important contribution to mitigating the environmental impacts caused by pollutant emissions.

Hydrogen has been an important feedstock for various industries, and its global market is already valued at hundreds of billions of dollars per year. It is also playing additional roles as a clean alternative energy carrier for power generation and as a crucial feedstock in the bioeconomy. This Special Issue “Hydrogen Production Technologies” highlights different thermochemical, electrochemical, and biological technologies such as high- and low-temperature electrolyzers, microchannel reactors, sorption-enhanced reactors, multi-tubular solar reactors, and anaerobic digestors. It also covers other aspects ranging from reactor design, hydrogen storage, and process analysis of different alternatives.