High Spectral Brightness Broad Area Quantum Cascade Lasers

Quantum cascade lasers are unipolar semiconductor lasers that offer a unique combination of compact size, high efficiency, high optical power, and flexibility to achieve a targeted emission wavelength with the same laser core material composition, employing so-called bandgap engineering. Since their invention in 1994, watt-level CW power with 5 to 20 % wallplug efficiency was demonstrated for QCLs throughout the entire 4 to 12 [micrometer] range, which makes QCLs very attractive for a number of practical applications. Our earlier work on broad-area QCLs emitting in the 4.6 [micrometer] to 5.7 [micrometer] spectral range demonstrated that CW power scaling with lateral device dimensions is an effective approach to increasing QCL power. First experimental and numerical data for short-wavelength (

Quantum Cascade Lasers are a novel semiconductor light source with the unique property of wavelength tunability over the mid-infrared and terahertz range of frequencies. Advances since their first demonstration in 1994 have led to highly efficient designs capable of continuous room temperature operation. In lieu of increased advances in laser core efficiency, power scaling with broad area quantum cascade lasers has demonstrated enhanced continuous power. This initial work is used as a starting point for continuing advances in average brightness of quantum cascade lasers. A figure of merit calculation reliably predicts to within parts in thousands the qualitative beam profile of continuously driven and high duty cycle devices. Further, a model is developed to project performance not only in continuously driven conditions, but also in variable duty cycles. This is combined with the figure of merit calculation to guide designs for optimized average brightness.

Quantum Cascade Lasers have recently gained considerable attention for their capability to emit infrared radiation in a broad infrared spectral region, very compact dimensions, and high optical power/efficiency. Increasing continuous wave optical power is one of the main research directions in the field. A straightforward approach to increasing optical power in the pulsed regime is to increase number of stages in the cascade structure. However, due to a low active region thermal conductivity, the increase in number of stages leads to active region overheating in continuous wave operation. In this work, an alternative approach to power scaling with device dimensions is explored: number of stages is reduced to reduce active region thermal resistance, while active region lateral size is increased for reaching high optical power level. Using this approach, power scaling for active region width increase from 10[micrometer] to 20[micrometer] is demonstrated for the first time. An analysis based on a simple semi-empirical model suggests that laser power can be significantly improved by increasing characteristic temperature T0 that describes temperature dependence of laser threshold current density.

Quantum cascade lasers (QCLs) are attractive for high-resolution spectroscopy because they can provide high power and a narrow linewidth. They are particularly promising in the terahertz (THz) range since they can be used as local oscillators for heterodyne detection as well as transmitters for direct detection. However, THz QCL-based technologies are still under development and are limited by the lack of frequency tunability as well as the frequency and output power stability for free-running operation. In this dissertation, frequency tuning and linewidth of THz QCLs are studied in detail by using rotational spectroscopic features of molecular species. In molecular spectroscopy, the Doppler eff ect broadens the spectral lines of molecules in the gas phase at thermal equilibrium. Saturated absorption spectroscopy has been performed that allows for sub-Doppler resolution of the spectral features. One possible application is QCL frequency stabilization based on the Lamb dip. Since the tunability of the emission frequency is an essential requirement to use THz QCL for high-resolution spectroscopy, a new method has been developed that relies on near-infrared (NIR) optical excitation of the QCL rear-facet. A wide tuning range has been achieved by using this approach. The scheme is straightforward to implement, and the approach can be readily applied to a large class of THz QCLs. The frequency and output stability of the local oscillator has a direct impact on the performance and consistency of the heterodyne spectroscopy. A technique has been developed for a simultaneous stabilization of the frequency and output power by taking advantage of the frequency and power regulation by NIR excitation. The results presented in this thesis will enable the routine use of THz QCLs for spectroscopic applications in the near future.

This book provides an introduction to quantum cascade lasers, including the basic underlying models used to describe the device. It aims at giving a synthetic view of the topic including the aspects of the physics, the technology, and the use of the device. It should also provide a guide for the application engineer to use this device in systems. The book is based on lecture notes of a class given for Masters and beginning PhD students. The idea is to provide an introduction to the new and exciting developments that intersubband transitions have brought to the use of the mid-infrared and terahertz region of the electromagnetic spectrum. The book provides an introductory part to each topic so that it can be used in a self-contained way, while references to the literature will allow deeper studies for further research.

This thesis presents the first comprehensive analysis of quantum cascade laser nonlinear dynamics and includes the first observation of a temporal chaotic behavior in quantum cascade lasers. It also provides the first analysis of optical instabilities in the mid-infrared range. Mid-infrared quantum cascade lasers are unipolar semiconductor lasers, which have become widely used in applications such as gas spectroscopy, free-space communications or optical countermeasures. Applying external perturbations such as optical feedback or optical injection leads to a strong modification of the quantum cascade laser properties. Optical feedback impacts the static properties of mid-infrared Fabry–Perot and distributed feedback quantum cascade lasers, inducing power increase; threshold reduction; modification of the optical spectrum, which can become either single- or multimode; and enhanced beam quality in broad-area transverse multimode lasers. It also leads to a different dynamical behavior, and a quantum cascade laser subject to optical feedback can oscillate periodically or even become chaotic. A quantum cascade laser under external control could therefore be a source with enhanced properties for the usual mid-infrared applications, but could also address new applications such as tunable photonic oscillators, extreme events generators, chaotic Light Detection and Ranging (LIDAR), chaos-based secured communications or unpredictable countermeasures.

Quantum cascade lasers are unipolar semiconductor lasers based on intersubband transitions in heterostructures. These lasers, which have demonstrated continuous wave operation at room temperature in the mid-infrared spectral range, are well suited for the realization of compact, ultra-sensitive, trace-gas sensors based on absorption spectroscopy. Up to now, only distributed feedback (DFB) single-mode devices have been used for such applications. DFB quantum cascade lasers have proven to be effective for gas sensing, but their relatively narrow tuning range, smaller or equal to about 1% of the wavelength, makes them not very versatile and limits their usefulness for spectroscopic investigations. In this thesis we developed broadly tunable external cavity quantum cascade lasers. The main advantage of these sources compared with DFBs is their broader tuning range, which is limited only by the spectral bandwidth of the gain element. We particularly studied broad gain bandwidth active regions based on bound-to-continuum designs. With that kind of active region, we have demonstrated a tuning range equal to 15% of the center wavelength at l ~ 10 mm, which was three times broader than the best values reported in the literature at that time, as well as good performance in pulsed mode at room temperature. Using a strain-compensated bound-to-continuum design emitting near 5.2 mm, we have demonstrated for the first time continuous-wave operation of an external cavity quantum cascade laser on a thermoelectric cooler. The tuning range was comparable to that of pulsed devices, but with a much better side-mode suppression ratio and a much narrower linewidth. This continuous-wave device has successfully been applied to the spectroscopy of nitric oxide in collaboration with Prof. Tittel's Laser Science Group at Rice University. High resolution absorption spectra of that gas could be acquired over a large wavelength range. We also studied heterogeneous cascade structures, that is quan.

Quantum Cascade Lasers are a novel source of coherent infrared light, unique in their tunability over the mid-infrared and terahertz range of frequencies. Advances in bandgap engineering and semiconductor processing techniques in recent years have led to the development of highly efficient quantum cascade lasers capable of room temperature operation. Recent work has demonstrated power scaling with broad area quantum cascade lasers by increasing active region width beyond the standard ~10 [micrometer]. Taking into account thermal effects caused by driving a device with electrical power, an experimentally fitted model is developed to predict the optical power output in both pulsed and continuous operation with varying device geometry and minor changes to quantum cascade laser active region design. The effects of the characteristic temperatures of threshold current density and slope efficiency, active region geometry, and doping, on output power are studied in the model. The model is then used to refine the active region design for increased power out in continuous operation for a broad area design. Upon testing the new design, new thermal effects on rollover current density are observed. The model is then refined to reflect the new findings and more accurately predict output power characteristics.

Advances in Spectroscopic Monitoring of the Atmosphere provides a comprehensive overview of cutting-edge technologies and monitoring applications. Concepts are illustrated by numerous examples with information on spectroscopic techniques and applications widely distributed throughout the text. This information is important for researchers to gain an overview of recent developments in the field and make informed selections among the most suitable techniques. This volume also provides information that will allow researchers to explore implementing and developing new diagnostic tools or new approaches for trace gas and aerosol sensing themselves. Advances in Spectroscopic Monitoring of the Atmosphere covers advanced and newly emerging spectroscopic techniques for optical metrology of gases and particles in the atmosphere. This book will be a valuable reference for atmospheric scientists, including those whose focus is applying the methods to atmospheric studies, and those who develop instrumentation. It will also serve as a useful introduction to researchers entering the field and provide relevant examples to researchers and students developing and applying optical sensors for a variety of other scientific, technical, and industrial uses. Overview of new applications including remote sensing by UAV, laser heterodyne radiometry, dual comb spectroscopy, and more Features in-situ observations and measurements for real-world data Includes content on leading edge optical sensors

Coherent power scaling of quantum cascade lasers (QCLs) for high-power, single-mode continuous-wave (CW) operation has proven to be quite a difficult task - while the device volume could be scaled for higher output power, many other factors such as beam quality and thermal resistance are negatively impacted if the device design is not carefully considered. The main objective of this work has been to develop methods for realizing high continuous-wave (CW) output power QCLs with high beam quality and minimal beam steering. One attractive approach for tackling this problem is the use of resonant leaky-wave-coupled antiguided phase-locked laser arrays. This dissertation focusses on two approaches to achieve high coherent power: 1) one alternate to the resonant leaky-wave-coupled antiguided phase-locked array concept, so called 'reverse-taper'laser; and 2) one combining grating-coupled surface-emitting lasers (GCSELs) with resonant leaky-wave-coupled antiguided phase-locked arrays, where each array element is coupled in both the lateral and longitudinal direction; thus, has a potential for multi-watt -CW surface-emitted output powers with good beam quality and narrow spectral linewidth. The novel geometry reverse-taper QCL device can scale the output power while maintaining good beam quality and beam stability - the tapered region scales the output power, while the emitting facet is located at the narrow-end taper section, which provides mode filtering by suppressing high-order spatial modes. A small degree of collimated-beam centroid movement (