Fe Organoiron Compounds

The present volume, "Organoiron Compounds" B 17, systematically covers the literature through the end of 1987 for Sections 1.5.3 to 1.5.3.5, through the end of 1988 for Sections 1.5.4 to 1.5.6.7, and also includes many tater references. This volume continues Se ries B (volumes B 1 to B 15 al ready published) on the mononu clear organoiron compounds; Series A (volumes A 1 to A 9 already published) is devoted to the ferrocenes and Se ries C (volumes C 1 to C 5 and C 7 already published) treats organoiron com pounds with two or more Fe atoms in the molecule. Se ries B thus far includes the following mononuclear organoiron compounds: "Eisen-Organische Verbindungen" B 1 (1976), B 2 (1978, in English), B 3 (1979, partly in English) Sections 1 to 1.1.4.8 on 0 compounds and carbonyl compounds. "Eisen-Organische Verbindungen" B 4 (1978) Sections 1.1.5 to 1.2.3.2.3 on isonitrile and carbene compounds and on compounds with ligands bonded to the Fe atom by two C atoms eL ligands). "Eisen-Organische Verbindungen" B 5 (1978) Sections 1.3 to 1.3.6 on compounds with ligands bonded to the Fe atom by three C atoms (3L ligands).

"Organoiron Compounds" A, Ferrocene 8 systematically covers the Literature through the end of 1984 and even includes some references published more recently. A formula index for the volumes "Organoiron Compounds" A, Ferrocene 7 and 8 provides ready access to the compounds covered. 1 2 1 This volume continues the description of ferrocenes FeC HRR in which at least R 10 8 contains C, H, and 0. The description of these type of compounds started in "Organoiron Compounds" A, Ferrocene 7 (with alcohols and phenols, their esters, ethers and acetones, and aldehydes). Series Aso far comprises volumes A 1 to A 8, and it has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. VIII (next page). Additional remarks, if necessary, are given in the headings of the tables. Frankfurt Adolf Slawisch November 1985 VIII Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, and the dimensions are omitted for the sake of conciseness. This necessitates the following clarification: Temperstures are given in oc, otherwise K stands for Kelvin. Abbreviations used with temperatures are m.p. for melting point, b.p. for boiling point, dec. for decomposition, and sub!. for sublimation. The solvent in parentheses following the m.p. is the solvent from which the compound is recrystallized.

Volume Organoiron Compounds B 14 systematically covers the literature through the end of 1986 and includes most references from 1987 and some from 1988. The volume continues Series B (volumes B 1 to B 13 already published) on mononuclear organoiron compounds. Series A (volumes A 1 to A 8 already published) is devoted to the ferrocenes and Series C (volumes C 1 to C 5 and C 7 already published) treats organoiron compounds with two or more Fe atoms in the molecule. The present volume completes the description of C5H5Fe(CO)2R compounds. The volume is completed by a formula and ligand index covering both volumes B 13 and B 14.

The present volume, "Organoiron Compounds" B 17, systematically covers the literature through the end of 1987 for Sections 1.5.3 to 1.5.3.5, through the end of 1988 for Sections 1.5.4 to 1.5.6.7, and also includes many tater references. This volume continues Se ries B (volumes B 1 to B 15 al ready published) on the mononu clear organoiron compounds; Series A (volumes A 1 to A 9 already published) is devoted to the ferrocenes and Se ries C (volumes C 1 to C 5 and C 7 already published) treats organoiron com pounds with two or more Fe atoms in the molecule. Se ries B thus far includes the following mononuclear organoiron compounds: "Eisen-Organische Verbindungen" B 1 (1976), B 2 (1978, in English), B 3 (1979, partly in English) Sections 1 to 1.1.4.8 on 0 compounds and carbonyl compounds. "Eisen-Organische Verbindungen" B 4 (1978) Sections 1.1.5 to 1.2.3.2.3 on isonitrile and carbene compounds and on compounds with ligands bonded to the Fe atom by two C atoms eL ligands). "Eisen-Organische Verbindungen" B 5 (1978) Sections 1.3 to 1.3.6 on compounds with ligands bonded to the Fe atom by three C atoms (3L ligands).

"Organoiron Compounds" A, Ferrocene 10 systematicalty covers the literature through the end of 1986 and includes so me references published more recently. A formula index provides ready access to the compounds covered. This volume ends the description of mononuclear unbridged disubstituted ferrocenes, 1 2 FeC HRR . The description of the unbridged disubstituted ferrocenes was initiated with lO a 1 2 "Organoiron Compounds" A, Ferrocene 7 (starting with R and R containing C and Hand 1 containing halogen at least in R\ and continuing with compounds containing 0 at least in R to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was foltowed 1 by "Organoiron Compounds" A, Ferrocene 8 (with at least R containing 0). "Organoiron 1 Compounds" A, Ferrocene 9 treated compounds in wh ich at least R contains N, S, Se, B, or Si. This volume now comprises the rest of the disubstituted ferrocenes containing P, As, or a 1 metal at least in R . Beyond that it includes the description of alt the mononuclear unbridged trisubstituted ferrocenes, FeClOH7R1R2R3. Series A so far comprises volumes A 1 to A 10 and has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. X (next page). Additional remarks are given in the headings of the tables where necessary.

"Organoiron Compounds" A, Ferrocene 10 systematicalty covers the literature through the end of 1986 and includes so me references published more recently. A formula index provides ready access to the compounds covered. This volume ends the description of mononuclear unbridged disubstituted ferrocenes, 1 2 FeC HRR . The description of the unbridged disubstituted ferrocenes was initiated with lO a 1 2 "Organoiron Compounds" A, Ferrocene 7 (starting with R and R containing C and Hand 1 containing halogen at least in R\ and continuing with compounds containing 0 at least in R to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was foltowed 1 by "Organoiron Compounds" A, Ferrocene 8 (with at least R containing 0). "Organoiron 1 Compounds" A, Ferrocene 9 treated compounds in wh ich at least R contains N, S, Se, B, or Si. This volume now comprises the rest of the disubstituted ferrocenes containing P, As, or a 1 metal at least in R . Beyond that it includes the description of alt the mononuclear unbridged trisubstituted ferrocenes, FeClOH7R1R2R3. Series A so far comprises volumes A 1 to A 10 and has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. X (next page). Additional remarks are given in the headings of the tables where necessary.

The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of Patai’s Chemistry of Functional Groups each volume in this series treats all aspects of functional groups. Each volume contains chapters on a wide range of topics. Starting with theoretical aspects, this volume moves to analytical methods, such as thermochemistry, mass spectrometry and Mössbauer spectroscopy. This is followed by some general organic chemistry contributions on different classes of iron compounds such as Ferrocenes. This culminates in a range of articles hightlighting the use of organoiron compounds as reagents and as catalysts.