Experimental Investigation And Modeling Of Lithium Ion Battery Cells And Packs For Electric Vehicles

The greatest challenge in the production of future generation electric and hybrid vehicle (EV and HEV) technology is the control and management of operating temperatures and heat generation. Vehicle performance, reliability and ultimately consumer market adoption are dependent on the successful design of the thermal management system. In addition, accurate battery thermal models capable of predicting the behavior of lithium-ion batteries under various operating conditions are necessary. Therefore, this work presents the thermal characterization of a prismatic lithium-ion battery cell and pack comprised of LiFePO4 electrode material. Thermal characterization is performed via experiments that enable the development of an empirical battery thermal model. This work starts with the design and development of an apparatus to measure the surface temperature profiles, heat flux, and heat generation from a lithium-ion battery cell and pack at different discharge rates of 1C, 2C, 3C, and 4C and varying operating temperature/boundary conditions (BCs) of 5oC, 15°C, 25°C, and 35°C for water cooling and ~22°C for air cooling. For this, a large sized prismatic LiFePO4 battery is cooled by two cold plates and nineteen thermocouples and three heat flux sensors are applied to the battery at distributed locations. The experimental results show that the temperature distribution is greatly affected by both the discharge rate and BCs. The developed experimental facility can be used for the measurement of heat generation from any prismatic battery, regardless of chemistry. In addition, thermal images are obtained at different discharge rates to enable visualization of the temperature distribution. In the second part of the research, an empirical battery thermal model is developed at the above mentioned discharge rates and varying BCs based on the acquired data using a neural network approach. The simulated data from the developed model is validated with experimental data in terms of the discharge temperature, discharge voltage, heat flux profiles, and the rate of heat generation profile. It is noted that the lowest temperature is 7.11°C observed for 1C-5°C and the highest temperature is observed to be 41.11°C at the end of discharge for 4C-35°C for cell level testing. The proposed battery thermal model can be used for any kind of Lithium-ion battery. An example of this use is demonstrated by validating the thermal performance of a realistic drive cycle collected from an EV at different environment temperatures. In the third part of the research, an electrochemical battery thermal model is developed for a large sized prismatic lithium-ion battery under different C-rates. This model is based on the principles of transport phenomena, electrochemistry, and thermodynamics presented by coupled nonlinear partial differential equations (PDEs) in x, r, and t. The developed model is validated with an experimental data and IR imaging obtained for this particular battery. It is seen that the surface temperature increases faster at a higher discharge rate and a higher temperature distribution is noted near electrodes. In the fourth part of the research, temperature and velocity contours are studied using a computational approach for mini-channel cold plates used for a water cooled large sized prismatic lithium-ion battery at different C-rates and BCs. Computationally, a high-fidelity turbulence model is also developed using ANSYS Fluent for a mini-channel cold plate, and the simulated data are then validated with the experimental data for temperature profiles. The present results show that increased discharge rates and increased operating temperature results in increased temperature at the cold plates. In the last part of this research, a battery degradation model of a lithium-ion battery, using real world drive cycles collected from an EV, is presented. For this, a data logger is installed in the EV and real world drive cycle data are collected. The vehicle is driven in the province of Ontario, Canada, and several drive cycles were recorded over a three-month period. A Thevenin battery model is developed in MATLAB along with an empirical degradation model. The model is validated in terms of voltage and state of charge (SOC) for all collected drive cycles. The presented model closely estimates the profiles observed in the experimental data. Data collected from the drive cycles show that a 4.60% capacity fade occurred over 3 months of driving.

This book focuses on the thermal management technology of lithium-ion batteries for vehicles. It introduces the charging and discharging temperature characteristics of lithium-ion batteries for vehicles, the method for modeling heat generation of lithium-ion batteries, experimental research and simulation on air-cooled and liquid-cooled heat dissipation of lithium-ion batteries, lithium-ion battery heating method based on PTC and wide-line metal film, self-heating using sinusoidal alternating current. This book is mainly for practitioners in the new energy vehicle industry, and it is suitable for reading and reference by researchers and engineering technicians in related fields such as new energy vehicles, thermal management and batteries. It can also be used as a reference book for undergraduates and graduate students in energy and power, electric vehicles, batteries and other related majors.

Battery System Modeling provides advances on the modeling of lithium-ion batteries. Offering step-by-step explanations, the book systematically guides the reader through the modeling of state of charge estimation, energy prediction, power evaluation, health estimation, and active control strategies. Using applications alongside practical case studies, each chapter shows the reader how to use the modeling tools provided. Moreover, the chemistry and characteristics are described in detail, with algorithms provided in every chapter. Providing a technical reference on the design and application of Li-ion battery management systems, this book is an ideal reference for researchers involved in batteries and energy storage. Moreover, the step-by-step guidance and comprehensive introduction to the topic makes it accessible to audiences of all levels, from experienced engineers to graduates. Explains how to model battery systems, including equivalent, electrical circuit and electrochemical nernst modeling Includes comprehensive coverage of battery state estimation methods, including state of charge estimation, energy prediction, power evaluation and health estimation Provides a dedicated chapter on active control strategies

Modeling and simulation of batteries, in conjunction with theory and experiment, are important research tools that offer opportunities for advancement of technologies that are critical to electric motors. The development of data from the application of these tools can provide the basis for managerial and technical decision-making. Together, these will continue to transform batteries for electric vehicles. This collection of nine papers presents the modeling and simulation of batteries and the continuing contribution being made to this impressive progress, including topics that cover: • Thermal behavior and characteristics • Battery management system design and analysis • Moderately high-fidelity 3D capabilities • Optimization Techniques and Durability As electric vehicles continue to gain interest from manufacturers and consumers alike, improvements in economy and affordability, as well as adoption of alternative fuel sources to meet government mandates are driving battery research and development. Progress in modeling and simulation will continue to contribute to battery improvements that deliver increased power, energy storage, and durability to further enhance the appeal of electric vehicles.

Batteries that can store electricity from solar and wind generation farms are a key component of a sustainable energy strategy. Featuring 15 peer-reviewed entries from the Encyclopedia of Sustainability Science and Technology, this book presents a wide range of battery types and components, from nanocarbons for supercapacitors to lead acid battery systems and technology. Worldwide experts provides a snapshot-in-time of the state-of-the art in battery-related R&D, with a particular focus on rechargeable batteries. Such batteries can store electrical energy generated by renewable energy sources such as solar, wind, and hydropower installations with high efficiency and release it on demand. They are efficient, non-polluting, self-contained devices, and their components can be recovered and used to recreate battery systems. Coverage also highlights the significant efforts currently underway to adapt battery technology to power cars, trucks and buses in order to eliminate pollution from petroleum combustion. Written for an audience of undergraduate and graduate students, researchers, and industry experts, Batteries for Sustainability is an invaluable one-stop reference to this essential area of energy technology.

The Handbook of Lithium-Ion Battery Pack Design: Chemistry, Components, Types and Terminology,?Second Edition provides a clear and concise explanation of EV and Li-ion batteries for readers that are new to the field. The second edition expands and updates all topics covered in the original book, adding more details to all existing chapters and including major updates to align with all of the rapid changes the industry has experienced over the past few years. This handbook offers a layman’s explanation of the history of vehicle electrification and battery technology, describing the various terminology and acronyms and explaining how to do simple calculations that can be used in determining basic battery sizing, capacity, voltage, and energy. By the end of this book the reader will have a solid understanding of the terminology around Li-ion batteries and be able to undertake simple battery calculations. The book is immensely useful to beginning and experienced engineers alike who are moving into the battery field. Li-ion batteries are one of the most unique systems in automobiles today in that they combine multiple engineering disciplines, yet most engineering programs focus on only a single engineering field. This book provides the reader with a reference to the history, terminology and design criteria needed to understand the Li-ion battery and to successfully lay out a new battery concept. Whether you are an electrical engineer, a mechanical engineer or a chemist, this book will help you better appreciate the inter-relationships between the various battery engineering fields that are required to understand the battery as an Energy Storage System. It gives great insights for readers ranging from engineers to sales, marketing, management, leadership, investors, and government officials. Adds a brief history of battery technology and its evolution to current technologies? Expands and updates the chemistry to include the latest types Discusses thermal runaway and cascading failure mitigation technologies? Expands and updates the descriptions of the battery module and pack components and systems?? Adds description of the manufacturing processes for cells, modules, and packs? Introduces and discusses new topics such as battery-as-a-service, cell to pack and cell to chassis designs, and wireless BMS?

While the popularity of lithium-ion batteries (LIBs) has increased significantly in recent years, safety concerns due to the high thermal instability of LIBs limit their use in applications with zero tolerance for failure. A safety issue of particular interest is a scenario called thermal runaway in which several exothermic side-reactions occur at elevated temperature ranges and release heat, which can then trigger the next reaction. This matter worsens when multiple cells are installed in close proximity to each other as the released heat from an abused cell can activate the chain of reactions in a neighboring cell, causing an entire module to heat rapidly and vent or ignite. This body of work aims to study LIB thermal behavior using both modeling and experiments to determine design practices that improve the safety of LIB modules. Based on the results of single cell abuse testing, a numerical model of the side-reactions that occur during thermal runaway was developed. The results showed that cell form factor and ambient conditions influence abuse behavior significantly. These abuse tests were extended to multi-cell modules to determine the effect of cell spacing, electrical configuration, and protection materials on the propagation of thermal runaway from an abused cell to a surrounding one. Lastly, an electrochemically coupled thermal model of battery thermal management systems of various configurations was created. An optimum thermal management design was found that utilized both active and passive methods of cooling to keep cell temperatures and thermal gradients within safe limits. The work described herein is expected to provide insight into safe battery design practices. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155326

Toxic fire effluents are responsible for the majority of fire deaths, and an increasing large majority of fire injuries, driven by the widespread and increasing use of synthetic polymers. Fire safety has focused on preventing ignition and reducing flame spread through reducing the rate of heat release, while neglecting the important issue of fire toxicity. This is the first reference work on fire toxicity and the only scientific publication on the subject in the last 15 years. Assessment of toxic effects of fires is increasingly being recognised as a key factor in the assessment of fire hazards. This book raises important issues including the types of toxic effluents that different fires produce, their physiological effects, methods for generation and assessment of fire toxicity, current and proposed regulations and approaches to modelling the toxic impact of fires. The contributors to Fire toxicity represent an international team of the leading experts in each aspect of this challenging and important field. This book provides an important reference work for professionals in the fire community, including fire fighters, fire investigators, regulators, fire safety engineers, and formulators of fire-safe materials. It will also prove invaluable to researchers in academia and industry. Investigates the controversial subject of toxic effluents as the cause of the majority of fire deaths and injuries Describes the different types of toxic effluents and the specific fires that they produce, their physiological effects and methods for generation Provides an overview of national and international fire safety regulations including current and proposed regulations such as a standardized framework for prediction of fire gas toxicity

Advances in Battery Technologies for Electric Vehicles provides an in-depth look into the research being conducted on the development of more efficient batteries capable of long distance travel. The text contains an introductory section on the market for battery and hybrid electric vehicles, then thoroughly presents the latest on lithium-ion battery technology. Readers will find sections on battery pack design and management, a discussion of the infrastructure required for the creation of a battery powered transport network, and coverage of the issues involved with end-of-life management for these types of batteries. Provides an in-depth look into new research on the development of more efficient, long distance travel batteries Contains an introductory section on the market for battery and hybrid electric vehicles Discusses battery pack design and management and the issues involved with end-of-life management for these types of batteries