Eddy Covariance Observations Of The Atmosphere Biosphere Exchange Of Nitrogen Oxides

Oxidative forms of reactive nitrogen (NOy) impact air quality, nutrient dynamics, and climate. Our understanding of the sources and sinks of atmospheric NOy that result from exchange between the atmosphere and biosphere is poorly constrained due to the lack of adequate instrumentation. In this dissertation, I apply novel technologies to the question of NOy exchange and describe observations of fluxes at the atmosphere-forest interface. I use thermal-dissociation laser-induced fluorescence, chemiluminescence, and the micrometeorological eddy-covariance method. Simultaneous observations of the rate and magnitude of exchanges and vertically resolved concentration measurements of the NOy species (NO, NO2, RO2NO2, RONO2 and HNO3) were measured in addition to a wide suite of relevant parameters including canopy structures, meteorological parameters, and associated chemical species as part of the Biosphere Effects on AeRosols and Photochemistry EXperiment (BEARPEX), which took place June 15 - July 31, 2009 at a Ponderosa pine plantation on the western slope of Sierra Nevada Mountains in California. I present observational evidence for active within canopy chemistry resulting in simultaneous production and removal of NOX within a forest canopy. My observations provide direct evidence for a NOX canopy reduction factor and for an NO2 compensation point. I also establish that an unusual peroxynitrate is formed within the canopy and then emitted to the atmosphere above underscoring the importance of coupling between biogenic volatile organic compounds and NOX to the fluxes of NOX, NOy and BVOC.

This highly practical handbook is an exhaustive treatment of eddy covariance measurement that will be of keen interest to scientists who are not necessarily specialists in micrometeorology. The chapters cover measuring fluxes using eddy covariance technique, from the tower installation and system dimensioning to data collection, correction and analysis. With a state-of-the-art perspective, the authors examine the latest techniques and address the most up-to-date methods for data processing and quality control. The chapters provide answers to data treatment problems including data filtering, footprint analysis, data gap filling, uncertainty evaluation, and flux separation, among others. The authors cover the application of measurement techniques in different ecosystems such as forest, crops, grassland, wetland, lakes and rivers, and urban areas, highlighting peculiarities, specific practices and methods to be considered. The book also covers what to do when you have all your data, summarizing the objectives of a database as well as using case studies of the CarboEurope and FLUXNET databases to demonstrate the way they should be maintained and managed. Policies for data use, exchange and publication are also discussed and proposed. This one compendium is a valuable source of information on eddy covariance measurement that allows readers to make rational and relevant choices in positioning, dimensioning, installing and maintaining an eddy covariance site; collecting, treating, correcting and analyzing eddy covariance data; and scaling up eddy flux measurements to annual scale and evaluating their uncertainty.

Eddy covariance method is a modern high-precision technique for direct measurements of the movement of gases, water vapor, heat, and momentum between the surface and the atmosphere. It is used for measurements of carbon sequestration and emission rates in natural, agricultural, industrial, and urban environments, atmospheric exchange rates of greenhouse gases, direct mea­surements of evapotranspirative water loss, heat exchange, turbulence rates, and momentum fluxes. The wide range of applications includes numerous fundamental and applied sciences, regulatory and industrial monitoring, multiple aspects of agricultural management, as well as carbon trading and offsets, corporate sustainability and neutrality, among many others. The book “Eddy Covariance Method for Scientific, Regulatory, and Commercial Applications” has been created to familiarize the reader with the general theoretical principles, requirements, applica­tions, planning, processing, and analysis steps of the eddy covariance method. It is intended to assist readers in furthering their understanding of the method and provide refer­ences such as academic textbooks, flux network guidelines, and journal papers. In particular, it is designed to help scientific, industrial, agricultural, and regulatory projects and monitoring programs with experiment design and field deployment of the eddy covariance method. Some of the topics covered in “Eddy Covariance Method for Scientific, Regulatory, and Commercial Applications” include: · Overview of eddy covariance principles · Planning and design of an eddy covariance experiment · Implementation of an eddy covariance experiment · Processing and analysis of eddy covariance data · Networking multiple flux stations · Alternative flux methods · Useful resources, training and knowledge base · Example of planning, design and implementation of a comprehensive automated flux station

This book was written to familiarize beginners with general theoretical principles, requirements, applications, and processing steps of the Eddy Covariance method. It is intended to assist in further understanding the method, and provides references such as textbooks, network guidelines and journal papers. It is also intended to help students and researchers in field deployment of instruments used with the Eddy Covariance method, and to promote its use beyond micrometeorology.

When considering biosphere–atmosphere exchange of trace gases and volatile aerosols, significant advances have been made both from an experimental and modelling point of view and on several scales. This was particularly stimulated by the availability of new datasets generated from improvements in analytical methods and flux measurement techniques. Recent research advances allow us, not only to identify major mechanisms and factors affecting the exchanges between the biosphere and the atmosphere, but also to recognize several gaps in the methodologies used in accounting for emissions and deposition in landscape and global scale models. This work aims at (i) reviewing exchange processes and modelling schemes, parameterisations and datasets, (ii) presenting a common conceptual framework to model soil-vegetation-atmosphere exchange of reactive trace gases and aerosols accounting for in-canopy transfer chemical interactions and (iii) discussing the key elements of the agreed framework.

This open access book discusses the impact of human-induced global climate change on the regional climate and monsoons of the Indian subcontinent, adjoining Indian Ocean and the Himalayas. It documents the regional climate change projections based on the climate models used in the IPCC Fifth Assessment Report (AR5) and climate change modeling studies using the IITM Earth System Model (ESM) and CORDEX South Asia datasets. The IPCC assessment reports, published every 6–7 years, constitute important reference materials for major policy decisions on climate change, adaptation, and mitigation. While the IPCC assessment reports largely provide a global perspective on climate change, the focus on regional climate change aspects is considerably limited. The effects of climate change over the Indian subcontinent involve complex physical processes on different space and time scales, especially given that the mean climate of this region is generally shaped by the Indian monsoon and the unique high-elevation geographical features such as the Himalayas, the Western Ghats, the Tibetan Plateau and the adjoining Indian Ocean, Arabian Sea, and Bay of Bengal. This book also presents policy relevant information based on robust scientific analysis and assessments of the observed and projected future climate change over the Indian region.

The “Eddy Covariance Method for Scientific, Industrial, Agricultural and Regulatory Applications: A Field Book on Measuring Ecosystem Gas Exchange and Areal Emission Rates†book has been created to familiarize the reader with the general theoretical principles, requirements, applications, and planning and processing steps of the eddy covariance method. It is intended to assist readers in furthering their understanding of the method, and provide references such as micrometeorology textbooks, networking guidelines and journal papers. In particular, it is designed to help scientific, industrial, agricultural, and regulatory research projects and monitoring programs with field deployment of the eddy covariance method in applications beyond micrometeorology.Some of the topics covered in “Eddy Covariance Method for Scientific, Industrial, Agricultural and Regulatory Applications†include:Overview of eddy covariance principlesPlanning and design of an eddy covariance experiment Implementation of an eddy covariance experiment Processing eddy covariance dataAlternative flux methodsUseful resources, training and knowledge baseExample of planning, design and implementation of a complete eddy covariance station