Distributed Feedback Quantum Cascade Lasers Emitting In The 9 Iu Im Band With Inp Top Cladding Layers

Achieving overlapped beams at extended distances can be important for a number of applications envisioned for DFB-QCL arrays, particularly remote sensing. Using the technique of spectral beam combining, the total angular divergence of the DFB-QCL array was reduced to less than 2 milliradians, which is 40 times better than without beam combining. Using the beam-combined array, absorption spectroscopy was performed at a distance of 6 m from the laser chip. An ultra-broadband DFB-QCL array was developed to further increase the coverage and tuning range. The array emitted in a range over 220 cm -1 near 9 μm wavelength, operated pulsed at room temperature.

This thesis presents the first comprehensive analysis of quantum cascade laser nonlinear dynamics and includes the first observation of a temporal chaotic behavior in quantum cascade lasers. It also provides the first analysis of optical instabilities in the mid-infrared range. Mid-infrared quantum cascade lasers are unipolar semiconductor lasers, which have become widely used in applications such as gas spectroscopy, free-space communications or optical countermeasures. Applying external perturbations such as optical feedback or optical injection leads to a strong modification of the quantum cascade laser properties. Optical feedback impacts the static properties of mid-infrared Fabry–Perot and distributed feedback quantum cascade lasers, inducing power increase; threshold reduction; modification of the optical spectrum, which can become either single- or multimode; and enhanced beam quality in broad-area transverse multimode lasers. It also leads to a different dynamical behavior, and a quantum cascade laser subject to optical feedback can oscillate periodically or even become chaotic. A quantum cascade laser under external control could therefore be a source with enhanced properties for the usual mid-infrared applications, but could also address new applications such as tunable photonic oscillators, extreme events generators, chaotic Light Detection and Ranging (LIDAR), chaos-based secured communications or unpredictable countermeasures.

A new approach to achieve high-power, symmetric beam-pattern, single-mode THz emission from metal-metal waveguide quantum-cascade laser is proposed and implemented. Several surface-emitting distributed feedback terahertz lasers are coupled through the connection phase sectors between them. Through carefully choosing the length of phase sectors, each laser will be in-phase locked with each other and thus create a tighter beam-pattern along the phased-array direction. A clear proof of phase-locking phenomenon has been observed and the array can be operated in either in-phase or out-of-phase mode at different phase sector length. The phase sector can also be individually biased to provide another frequency tuning mechanism through gain-induced optical index change. A frequency tuning range of 1:5 GHz out of 3:9 THz was measured. Moreover, an electronically controlled "beam steering" device is also proposed based on the result of this work. This thesis focuses on the design, fabrication and measurement of the surface-emitting distributed feedback terahertz quantum-cascade phase-locked laser arrays.

When using conventional substrates, such as InP and GaAs, the materials constituting the superlattice (SL) core region of the quantum cascade laser (QCL) are constrained by strain-induced critical-thickness limitations. Metamorphic buffer layers (MBLs) can serve as "virtual substrates" with a designer-chosen surface lattice constant, thus expanding the compositional-design space for a variety of device structures, including short-wavelength QCLs. An optimized short-wavelength (3.4 [mu]m) single-phonon-resonant (SPR)+ miniband extraction QCL design, grown on an [InxGa1-xAs] MBL, is presented along with the optical and thermal device considerations in play. MBLs can be grown with a variety of graded regions such as linear composition grade from GaAs to [InxGa1-xAs] or by employing dislocation filters between Si substrate and InP. QCL and test superlattices' regrowth on these MBLs with the corresponding materials and device analysis, is presented in this work. In addition to the materials limitation for the design of QCL devices, the requirement to have the constituent layers (1-5 nm) to be precisely controlled in the various compositions and thicknesses, is a challenge. Interfacial grading in strained SLs is studied via atom probe tomography for SLs with various layer thicknesses and relative lattice strains. The tip reconstructions are analyzed by fitting the interfaces to diffusion profiles. Mechanisms possible for the observed interdiffusion profile, such as surface segregation and/or bulk diffusion, are discussed. With an understanding of the compositional gradient at the interfaces, together with optimized QCL designs and regrowth on the MBLs, short-wavelength QCLs with high performances can be achieved.

The mid-infrared domain is a promising optical domain because it holds two transparency atmospheric windows, as well as the fingerprint of many chemical compounds. Quantum cascade lasers (QCLs) are one of the available sources in this domain and have already been proven useful for spectroscopic applications and free-space communications. This thesis demonstrates how to implement a private free-space communication relying on mid-infrared optical chaos and this requires an accurate cartography of non-linear phenomena in quantum cascade lasers. This private transmission is made possible by the chaos synchronization of two twin QCLs. Chaos in QCLs can be generated under optical injection or external optical feedback. Depending on the parameters of the optical feedback, QCLs can exhibit several non-linear phenomena in addition to chaos. Similarities exist between QCLs and laser diodes when the chaotic dropouts are synchronized with an external modulation, and this effect is known as the entrainment phenomenon. With a cross-polarization reinjection technique, QCLs can generate all-optical square-waves. Eventually, it is possible to trigger optical extreme events in QCLs with tilted optical feedback. All these experimental results allow a better understanding of the non-linear dynamics of QCLs and will extend the potential applications of this kind of semiconductor lasers.