Development Of An Advanced Groundwater Remediation Technology For The Removal Of Chlorinated Hydrocarbons With High Density Chc By Alcohol Injection Part A Hydraulic Control Of A Targeted Alcohol Injection Part B Solubilisation And Controlled Mobilization Of Chc

As we transition into the 21st century, it is apparent that this is an exciting time for environmental engineers and scientists studying remediation technologies. There has been a rapid development of new ways to clean-up polluted groundwater. Research activities of the past and next 10 years will have a dramatic impact on the quality of the subsurface environment for the next century. In 20, or even 10 years from now, our approach to subsurface remediation will probably be vastly different than it is today. Many of the emerging technologies presented in this book will form the basis of standard remediation practices of the future. Physicochemical Groundwater Remediation presents detailed information on multiple emerging technologies for the remediation of the contaminated subsurface environment. All of these technologies apply our knowledge of physical and chemical processes to clean up ground water and the unsaturated zone, and many (if not all) of these emerging technologies will help define standard practices in the future. These technologies include in situ sorptive and reactive treatment walls, surfactant-enhanced aquifer remediation, optimization analyses for remediation system design, chemical, electrochemical, and biochemical remediation processes, and monitored natural attenuation. You will learn how palladium catalyzes the dehalogenation of chlorinated solvents. You will find out how barometric pumping can naturally remove significant quantities of volatile organic pollutants from shallow ground water and the unsaturated zone. You can learn about mobilizing non-aqueous phase liquids (NAPLs) without risking significant downward migration of the NAPL. You can find out how processes such as electroosmosis and electromigration can be exploited for groundwater remediation purposes and how zero-valent iron and zeolite treatment walls can be used in situ to treat and control contaminant plume migration. Contributors to this book are experts in groundwater remediation processes, and they represent industry, consulting, academia, and government. If your work involves the clean up of contaminated soil and groundwater, this book is an essential reference to keep you up to date on the most promising new developments in remediation research.

Across the United States, thousands of hazardous waste sites are contaminated with chemicals that prevent the underlying groundwater from meeting drinking water standards. These include Superfund sites and other facilities that handle and dispose of hazardous waste, active and inactive dry cleaners, and leaking underground storage tanks; many are at federal facilities such as military installations. While many sites have been closed over the past 30 years through cleanup programs run by the U.S. Department of Defense, the U.S. EPA, and other state and federal agencies, the remaining caseload is much more difficult to address because the nature of the contamination and subsurface conditions make it difficult to achieve drinking water standards in the affected groundwater. Alternatives for Managing the Nation's Complex Contaminated Groundwater Sites estimates that at least 126,000 sites across the U.S. still have contaminated groundwater, and their closure is expected to cost at least $110 billion to $127 billion. About 10 percent of these sites are considered "complex," meaning restoration is unlikely to be achieved in the next 50 to 100 years due to technological limitations. At sites where contaminant concentrations have plateaued at levels above cleanup goals despite active efforts, the report recommends evaluating whether the sites should transition to long-term management, where risks would be monitored and harmful exposures prevented, but at reduced costs.

This monograph consists of manuscripts submitted by invited speakers who participated in the symposium "Industrial Environmental Chemistry: Waste Minimization in Industrial Processes and Remediation of Hazardous Waste," held March 24-26, 1992, at Texas A&M University. This meeting was the tenth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The program was developed by an academic-industrial steering committee consisting of the co-chairmen, Professors Donald T. Sawyer and Arthur E. Martell of the Texas A&M University Chemistry Department, and members appointed by the sponsoring companies: Bernie A. Allen, Jr., Dow Chemical USA; Kirk W. Brown, Texas A&M University; Abraham Clearfield, Texas A&M University; Greg Leyes, Monsanto Company; Jay Warner, Hoechst-Celanese Corporation; Paul M. Zakriski, BF Goodrich Company; and Emile A. Schweikert, Texas A&M University (IUCCP Coordinator). The subject of this conference reflects the interest that has developed in academic institutions and industry for technological solutions to environmental contamination by industrial wastes. Progress is most likely with strategies that minimize waste production from industrial processes. Clearly the key to the protection and preservation of the environment will be through R&D that optimizes chemical processes to minimize or eliminate waste streams. Eleven of the papers are directed to waste minimization. An additional ten papers discuss chemical and biological remediation strategies for hazardous wastes that contaminate soils, sludges, and water.

Global society in the 21st century is facing challenges of improving the quality of air, water, soil and the environment and maintaining the ecological balance. Environmental pollution, thus, has become a major global concern. The modern growth of industrialization, urbanization, modern agricultural development and energy generation has resulted in the indiscriminate exploitation of natural resources for fulfilling human desires and needs, which has contributed in disturbing the ecological balance on which the quality of our environment depends. Human beings, in the truest sense, are the product of their environment. The man-environment relationship indicates that pollution and deterioration of the environment have a social origin. The modern technological advancements in chemical processes/operations have generated new products, resulting in new pollutants in such abundant levels that they are above the self-cleaning capacity of the environment. One of the major issues in recent times is the threat tohuman lives due to the progressive deterioration of the environment from various sources. The impact of the pollutants on the environment will be significant when the accumulated pollutants load will exceed the carrying capacity of the receiving environment. Sustainable development envisages the use of natural resources, such as forests, land, water and fisheries, in a sustainable manner without causing changes in our natural world. The Rio de Janeiro-Earth Summit, held in Brazil in 1992, focused on sustainable development to encourage respect and concern for the use of natural resources in a sustainable manner for the protection of the environment. This book will be beneficial as a source of educational material to post-graduate research scholars, teachers and industrial personnel for maintaining the balance in the use of natural sources for sustainable development.

Microbes and their biosynthetic capabilities have been invaluable in finding solutions for several intractable problems mankind has encountered in maintaining the quality of the environment. They have, for example, been used to positive effect in human and animal health, genetic engineering, environmental protection, and municipal and industrial waste treatment. Microorganisms have enabled feasible and cost-effective responses which would have been impossible via straightforward chemical or physical engineering methods. Microbial technologies have of late been applied to a range of environmental problems, with considerable success. This survey of recent scientific progress in usefully applying microbes to both environmental management and biotechnology is informed by acknowledgement of the polluting effects on the world around us of soil erosion, the unwanted migration of sediments, chemical fertilizers and pesticides, and the improper treatment of human and animal wastes. These harmful phenomena have resulted in serious environmental and social problems around the world, problems which require us to look for solutions elsewhere than in established physical and chemical technologies. Often the answer lies in hybrid applications in which microbial methods are combined with physical and chemical ones. When we remember that these highly effective microorganisms, cultured for a variety of applications, are but a tiny fraction of those to be found in the world around us, we realize the vastness of the untapped and beneficial potential of microorganisms. At present, comprehending the diversity of hitherto uncultured microbes involves the application of metagenomics, with several novel microbial species having been discovered using culture-independent approaches. Edited by recognized leaders in the field, this penetrating assessment of our progress to date in deploying microorganisms to the advantage of environmental management and biotechnology will be widely welcomed.

At hundreds of thousands of commercial, industrial, and military sites across the country, subsurface materials including groundwater are contaminated with chemical waste. The last decade has seen growing interest in using aggressive source remediation technologies to remove contaminants from the subsurface, but there is limited understanding of (1) the effectiveness of these technologies and (2) the overall effect of mass removal on groundwater quality. This report reviews the suite of technologies available for source remediation and their ability to reach a variety of cleanup goals, from meeting regulatory standards for groundwater to reducing costs. The report proposes elements of a protocol for accomplishing source remediation that should enable project managers to decide whether and how to pursue source remediation at their sites.

A deeper insight into the complex processes involved in this field, covering the biological, chemical and engineering fundamentals needed to further develop effective methodologies. The book devotes detailed chapters to each of the four main areas of environmental biotechnology -- wastewater treatment, soil treatment, solid waste treatment, and waste gas treatment -- dealing with both the microbiological and process engineering aspects. The result is the combined knowledge contained in the extremely successful volumes 11a through 11c of the "Biotechnology" series in a handy and compact form.