Chemical Processes In Soils

A thorough presentation of analytical methods for characterizing soil chemical properties and processes, Methods, Part 3 includes chapters on Fourier transform infrared, Raman, electron spin resonance, x-ray photoelectron, and x-ray absorption fine structure spectroscopies, and more.

Soil is key to sustaining life—affecting air and water quality, the growth of plants and crops, and the health of the entire planet. Soil Chemistry 4e provides comprehensive coverage of the chemical interactions among organic and inorganic solids, air, water, microorganisms, and the plant roots in soil. The fourth edition of Soil Chemistry has been revised and updated throughout and provides a basic description of important research and fundamental knowledge in the field. The text covers chemical processes that occur in soils, including: distribution and species of nutrients and contaminants in soils; aqueous chemistry of soil solutions and mineral dissolution; oxidation and reduction reactions in soils; soil mineral formation processes and properties; the formation and reactivity of soil organic matter; surface chemistry and cation, anion, and organic compound adsorption reactions; modelling soil chemical reactions; and reactions in acid and salt affected soils. Although extensively revised with updated figures and tables, the fourth edition maintains the focus on introductory soil chemistry that has distinguished earlier editions. New chapters on properties of elements relevant to soil chemistry, and a chapter with special focus on soil surface characteristics have been added. Special Topics boxes are also included in the Fourth Edition that includes examples, noteworthy topics, and case studies. End of chapter questions are included as a resource for teaching.

As the author states in his Preface, this book is written at a time when scientific and lay communities recognize that knowledge of environmental chemistry is fundamental in understanding and predicting the fate of pollutants in soils and waters, and in making sound decisions about remediation of contaminated soils. Environmental Soil Chemistry presents the fundamental concepts of soil science and applies them to environmentally significant reactions in soil. Clearly and concisely written for undergraduate and beginning graduate students of soil science, the book is likewise accessible to all students and professionals of environmental engineering and science. Chapters cover background information useful to students new to the discipline, including the chemistry of inorganic and organic soil components, soilacidity and salinity, and ion exchange and redox phenomena. However, discussion also extends to sorption/desorption, oxidation-reduction of metals and organic chemicals, rates of pollutant reactions as well as technologies for remediating contaminated soils. Supplementary reading lists, sample problems, and extensive tables and figures make this textbook accessible to readers. Provides students with both sound contemporary training in the basics of soil chemistry and applications to real-world environmental concerns Timely and comprehensive discussion of important concepts including: Sorption/desorption, Oxidation-reduction of metals and organics, Effects of acidic deposition and salinity on contaminant reactions Boxed sections focus on sample problems and explanations of key terms and parameters Extensive tables on elemental composition of soils, rocks and sediments, pesticide classes, inorganic minerals, and methods of decontaminating soils Clearly written for all students and professionals in environmental science and environmental engineering as well as soil science

Soil Formation deals with qualitative and quantitative aspects of soil formation (or pedogenesis) and the underlying chemical, biological, and physical processes. The starting point of the text is the process - and not soil classification. Effects of weathering and new formation of minerals, mobilisation, transport, and breakdown or immobilisation of dissolved and suspended compounds are discussed. Soil processes and profiles are discussed in relation to the landscape, the geosphere, and the biosphere. Emphasis lies on the universality of soil-forming processes in past and present, and on the soil as a dynamic entity that forms part of the total environment. Complexity of genetic processes in time and space is given much attention. The text gives many examples from literature and places some in a new light. The reader is guided through the subject matter by a large number of questions and problems to help understand and synthesis the material. Answers to all questions are included. This second edition has been updated to reflect recent discoveries. Printing errors have been corrected, and new photographs support the text.

During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.

Provides comprehensive coverage of the chemical interactions among organic and inorganic solids, air, water, microorganisms, and the plant roots in soil This book focuses on the species and reaction processes of chemicals in soils, with applications to environmental and agricultural issues. Topics range from discussion of fundamental chemical processes to review of properties and reactions of chemicals in the environment. This new edition contains more examples, more illustrations, more details of calculations, and reorganized material within the chapters, including nearly 100 new equations and 51 new figures. Each section also ends with an important concepts overview as well as new questions for readers to answer. Starting with an introduction to the subject, Soil Chemistry, 5th Edition offers in-depth coverage of properties of elements and molecules; characteristics of chemicals in soils; soil water chemistry; redox reactions in soils; mineralogy and weathering processes in soils; and chemistry of soil clays. The book also provides chapters that examine production and chemistry of soil organic matter; surface properties of soil colloids; adsorption processes in soils; measuring and predicting sorption processes in soils; soil acidity; and salt-affected soils. Provides a basic description of important research and fundamental knowledge in the field of soil chemistry Contains more than 200 references provided in figure and table captions and at the end of the chapters Extensively revised with updated figures and tables Soil Chemistry, 5th Edition is an excellent text for senior-level soil chemistry students.

Environmental Chemistry of Soils provides an understanding of soil chemical properties and processes at a fundamental scientific level.

This book develops a unified, comprehensive account of the important chemical processes in soils that can be described by reactions. The perspective taken is that of chemical thermodynamics and kinetics applied to soil systems in detail in order to provide an understanding of phenomena ranging from complexation reactions to colloidal flocculation. Problem sets are included at the end of each chapter.

Kinetics of soil chemical reactions. Methods of obtaining and analyzin kinetic data. Relaxation methods for studying kinetics of soil chemical phenomena. Kinetics of ion sorptionon humic substances. Kinetics of sorption/desorption processes in soils. Modelling nonequilibrium reactions of inorganic solutes in soil columns. Sorption kinetics of organic chemicals: methods, models, and mechanisms.