Chemical Modification Properties And Usage Of Lignin

One of the most significant challenges facing mankind in the twenty-first century is the development of a sustainable global economy. Within the scientific community, this calls for the development of processes and technologies that will allow the sustainable production of materials from renewable natural resources. Plant material, in particular lignin, is one such resource. During the annual production of about 100 million metric tons of chemical wood pulps worldwide, approximately 45 and 2 million metric tons/year of kraft lignin and lignosulfonates, respectively, are also generated. Although lignosulfonates have found many applications outside the pulp and paper industry, the majority of kraft lignin is being used internally as a low-grade fuel for the kraft pulping operation. A surplus of kraft lignin will become available as kraft mills increase their pulp production without expanding the capacity of their recovery boilers that utilize lignin as a fuel. There is a tremendous opportunity and an enormous economic incentive to find better uses of kraft lignin, lignosulfonates and other industriallignins. The pulp and paper industry not only produces an enormous amount of lignins as by products of chemical wood pulps, but it also utilizes about 10 million metric tons of lignin per year as a component of mechanical wood pulps and papers. Mechanical wood pulps, produced in a yield of 90-98% with the retention of lignin, are mainly used to make low-quality, non-permanent papers such as newsprint and telephone directories because of the light-induced photooxidation of lignin and the yellowing of the papers.

Lignin Chemistry and Application systematically discusses the structure, physical and chemical modification of lignin, along with its application in the field of chemicals and materials. It presents the history of lignin chemistry and lignin-modified materials, describes recent progresses, applications and studies, and prospects the development direction of high value applications of lignin in the field of material science. In addition to covering the basic theories and technologies relating to the research and application of lignin in polymer chemistry and materials science, the book also summarizes the latest applications in rubber, engineering plastics, adhesives, films and hydrogels. Systematically discusses the structure, physical and chemical modification of lignin and its application in materials Presents the latest research results in the field of lignin Indicates the development direction of high value applications of lignin in a range of fields, including petrochemicals, household applications, medicine, agriculture, and more

This book presents a comprehensive overview on origin, structure, properties, modification strategies and applications of the biopolymer lignin. It is organized into four themed parts. The first part focuses on the analysis and characterization of the second most abundant biopolymer. The following part is devoted to the biological aspects of lignin such as biosynthesis and degradation. In the third part, chemical modification strategies and the preparation of composites as well as nano- and microparticles are discussed.The final part addresses the industrial application of lignin and its derivatives, as well as lignin materials. The usage for synthesis of biofuels, fine chemicals and in agriculture and food industry is covered. This book is a comprehensive source for researchers, scientists and engineers working in the field of biopolymers as well as renewable materials and sources.

This book presents an overview of various types of lignin and their unique structures and properties, as well as utilizations of crude or modified technical lignin for high-value bioproducts such as lignin-based PF resins/adhesives, epoxy resins, PF foams, PU foams, rubber reinforcement and carbon fibers and as dispersants in drilling fluids in the oil and gas industry. It subsequently discusses various thermal/chemical modification techniques (pyrolysis, direct liquefaction and de-polymerization) for converting lignin into oils and chemical feedstocks, and the utilization of crude lignin, lignin-derived oils or depolymerized lignins (DLs) of reduced molecular weights and improved reactivity to produce lignin-based PF resins/adhesives, PF/PU foams and epoxy resins. The book will interest and benefit a broad readership (graduate students, academic researchers, industrial researchers and practitioners) in various fields of science and technology (chemical engineering, biotechnology, chemistry, material science, forestry, etc.). Chunbao (Charles) Xu, PhD, is currently a Professor of Chemical Engineering and NSERC/FPInnovations Industrial Research Chair in Forest Biorefinery at the University of Western Ontario, Canada. Fatemeh Ferdosian, PhD, is currently a postdoctoral fellow at the University of Waterloo, Canada.

Lignin is one of the most abundant plant-derived feedstock on earth and qualifies as a renewable material. However, lignin is widely recognized as waste byproduct of the cellulosic ethanol and pulp and paper industry. How to properly modify lignin and develop it into functional polymers is a huge challenge, but an attractive research topic in both industry and academia. This book brings together leading engineering approaches to address the challenges of lignin valorization. It presents the chemistry and properties of different types of lignin, and explores the cutting-edge approaches of lignin modifications. Unlike any existing texts, this book not only summarizes the traditional ways of using lignin, but also presents various potential applications of lignin materials together with advanced processing techniques. The basis of lignin (its chemistry, types and properties) is described, as are different approaches to modify it. The features of lignin and its copolymers are explored and aligned with their potential applications. In addition to the carbon materials from lignin, the advanced fabrication approaches to engineer lignin-based micro/nano-structural materials are summarized.

This volume emphasizes the growing need for wood products with advanced engineering properties. It details the fundamental principles of cellulose technology and presents current techniques to modifying the basic chemistry of lignocellulosic materials. The work: discusses the cost-efficient use of cellulose derivatives in a variety of commodities; highlights the chemical modification of wood by methods such as etherification, esterification and thermoplasticization; considers recent progress in the lignocellulosic liquefaction of wood; and more.

Lignin-based Materials for Biomedical Applications: Preparation, Characterization, and Implementation explores the emerging area of lignin-based materials as a platform for advanced biomedical applications, guiding the reader from source through to implementation. The first part of the book introduces the basics of lignin, including extraction methods, chemical modifications, structure and composition, and properties that make lignin suitable for biomedical applications. In addition, structural characterization techniques are described in detail. The next chapters focus on the preparation of lignin-based materials for biomedical applications, presenting methodologies for lignin-based nanoparticles, hydrogels, aerogels, and nanofibers, and providing in-depth coverage of lignin-based materials with specific properties—including antioxidant properties, UV absorbing capability, antimicrobial properties, and colloidal particles with tailored properties—and applications, such as drug and gene delivery, and tissue engineering. Finally, future perspectives and possible new applications are considered. This is an essential reference for all those with an interest in lignin-based materials and their biomedical applications, including researchers and advanced students across bio-based polymers, polymer science, polymer chemistry, biomaterials, nanotechnology, materials science and engineering, drug delivery, and biomedical engineering, as well as industrial R&D and scientists involved with bio-based polymers, specifically for biomedical applications. Unlocks the potential of lignin-based materials with advanced properties for cutting-edge applications in areas such as drug delivery, gene delivery and tissue engineering Presents state-of-the-art methodologies used in the development of lignin-based nanoparticles, hydrogels, aerogels and nanofibers Explains the fundamentals of lignin, including structure and composition, extraction and isolation methods, types and properties, chemical modifications, and characterization techniques

"Chapters will specifically focus on the production of fuels and chemicals from lignin."--Page [4] of cover.

As naturally occurring and abundant sources of non-fossil carbon, lignin and lignans offer exciting possibilities as a source of commercially valuable products, moving away from petrochemical-based feedstocks in favour of renewable raw materials. Lignin can be used directly in fields such as agriculture, livestock, soil rehabilitation, bioremediation and the polymer industry, or it can be chemically modified for the fabrication of specialty and high-value chemicals such as resins, adhesives, fuels and greases. Lignin and Lignans as Renewable Raw Materials presents a multidisciplinary overview of the state-of-the-art and future prospects of lignin and lignans. The book discusses the origin, structure, function and applications of both types of compounds, describing the main resources and values of these products as carbon raw materials. Topics covered include: • Structure and physicochemical properties • Lignin detection methods • Biosynthesis of lignin • Isolation methods • Characterization and modification of lignins • Applications of modified and unmodified lignins • Lignans: structure, chemical and biological properties • Future perspectives This book is a comprehensive resource for researchers, scientists and engineers in academia and industry working on new possibilities for the application of renewable raw materials. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

This volume emphasizes the growing need for wood products with advanced engineering properties. It details the fundamental principles of cellulose technology and presents current techniques to modifying the basic chemistry of lignocellulosic materials. The work: discusses the cost-efficient use of cellulose derivatives in a variety of commodities; highlights the chemical modification of wood by methods such as etherification, esterification and thermoplasticization; considers recent progress in the lignocellulosic liquefaction of wood; and more.