Catalysis At Surfaces

This unique book covers the latest surface science studies on model catalysts, including single crystals, non-colloidal nanocatalysts, and nanoparticles in various forms with the control of size, shape and composition. This book addresses the issue of bridging “materials and pressure gaps” and also discusses the important issue of metal-oxide interface and hot electron flows in heterogeneous catalysis. The current development of in-situ surface techniques that is relevant to bridging “pressure gaps” is also highlighted.

This text provides a balanced introduction to the principles and techniques of heterogeneous catalysis. Beginning with the basic chemistry and physics of catalysis, the book goes on to pay particular attention to the contribution that surface science is making to our understanding of catalysis. It concludes with chapters devoted to carefully chosen examples of real catalytic systems, including catalytic action by enzymes and industrial processes based on solid catalysis. Looking to the future, the book introduces many novel types of catalysis.

Among the topics covered are adhesion and tribological properties, friction, crack formation, and lubrication.

The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.

Surface chemistry is an essential and developing area of physical chemistry and one that has become increasingly interdisciplinary. The Second Edition of Surface Science: Foundations of Catalysis and Nanoscience has been fully revised and updated to reflect all the latest developments in the field and now includes an extensive discussion about nanoparticle growth and the quantum confinement effects in nanoscale systems. Two new chapters have been added and discuss The Liquid/Solid Interface and Non-Thermal Reactions, and Photon and Electron Stimulated Chemistry and Atom Manipulation. There are now many more worked examples included throughout to help students develop their problem-solving skills.

"Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.Among the 70 contributions received, the 56 accepted papers were selected on the basis of the reports of at least two international reviewers, according to standards comparable to those applied for other specialised journals. These papers are from 21 different countries.

This book is based on a graduate course and suitable as a primer for any newcomer to the field, this book is a detailed introduction to the experimental and computational methods that are used to study how solid surfaces act as catalysts. Features include: First comprehensive description of modern theory of heterogeneous catalysis Basis for understanding and designing experiments in the field Allows reader to understand catalyst design principles Introduction to important elements of energy transformation technology Test driven at Stanford University over several semesters

Illustrating developments in electrochemical nanotechnology, heterogeneous catalysis, surface science and theoretical modelling, this reference describes the manipulation, characterization, control, and application of nanoparticles for enhanced catalytic activity and selectivity. It also offers experimental and synthetic strategies in nanoscale surface science. This standard-setting work clariefies several practical methods used to control the size, shape, crystal structure, and composition of nanoparticles; simulate metal-support interactions; predict nanoparticle behavior; enhance catalytic rates in gas phases; and examine catalytic functions on wet and dry surfaces.

Wiley Series on Electrocatalysis and Electrochemistry Fuel Cell Catalysis A Surface Science Approach A Core reference on fuel cell catalysis Fuel cells represent an important alternative energy source and a very active area of research. Fuel Cell Catalysis brings together world leaders in this field, providing a unique combination of state-of-the-art theory and computational and experimental methods. With an emphasis on understanding fuel cell catalysis at the molecular level, this text covers fundamental principles, future challenges, and important current research themes. Fuel Cell Catalysis: Provides a molecular-level description of catalysis for low-temperature polymer-electrolyte membrane fuel cells, including both hydrogen-oxygen cells and direct alcohol cells Examines catalysis issues of both anode and cathode such as oxygen reduction, alcohol oxidation, and CO tolerance Features a timely and forward-looking approach through emphasis on novel aspects such as computation and bio-inspiration Reviews the use and potential of surface-sensitive techniques like vibrational spectroscopy (IR, Raman, nonlinear spectroscopy, laser), scanning tunneling microscopy, X-ray scattering, NMR, electrochemical techniques, and more Reviews the use and potential of such modern computational techniques as DFT, ab initio MD, kinetic Monte Carlo simulations, and more Surveys important trends in reactivity and structure sensitivity, nanoparticles, "dynamic" catalysis, electrocatalysis vs. gas-phase catalysis, new experimental techniques, and nontraditional catalysts This cutting-edge collection offers a core reference for electrochemists, electrocatalysis researchers, surface and physical chemists, chemical and automotive engineers, and researchers in academia, research institutes, and industry.

Catalysis is at the heart of the chemical industry, which uses solid catalysts for the large-scale production of commodity chemicals. Catalysis at surfaces is also the basis for the ongoing transition to a sustainable energy supply, which requires molecules such as hydrogen, ammonia or methanol to store energy in chemical bonds, and environmental protection equally relies on heterogeneous catalysis. Catalysis at surfaces is a truly interdisciplinary field, which requires profound knowledge from chemistry, physics and engineering as provided by this textbook. All essential tools are described ranging from the synthesis and modification of porous solids over bulk- and surface-sensitive characterization techniques to currently applied theoretical methods. A close-up to the important aspects of surface catalysis is provided, which comprises the established knowledge about mechanisms and active sites, promotors and poisons in redox and acid-base catalysis. This advanced textbook is recommended for Master and PhD students, for whom it provides the fundamentals and all relevant aspects of catalyst synthesis, characterization and application in suitable reactors. It is not only thermal catalysis that is covered in depth, but also photo- and electrocatalysis as emerging fields in the Energiewende.