Broadband Mid Infrared Quantum Cascade Lasers For Spectroscopic Applications In External Cavity

Quantum cascade lasers are unipolar semiconductor lasers based on intersubband transitions in heterostructures. These lasers, which have demonstrated continuous wave operation at room temperature in the mid-infrared spectral range, are well suited for the realization of compact, ultra-sensitive, trace-gas sensors based on absorption spectroscopy. Up to now, only distributed feedback (DFB) single-mode devices have been used for such applications. DFB quantum cascade lasers have proven to be effective for gas sensing, but their relatively narrow tuning range, smaller or equal to about 1% of the wavelength, makes them not very versatile and limits their usefulness for spectroscopic investigations. In this thesis we developed broadly tunable external cavity quantum cascade lasers. The main advantage of these sources compared with DFBs is their broader tuning range, which is limited only by the spectral bandwidth of the gain element. We particularly studied broad gain bandwidth active regions based on bound-to-continuum designs. With that kind of active region, we have demonstrated a tuning range equal to 15% of the center wavelength at l ~ 10 mm, which was three times broader than the best values reported in the literature at that time, as well as good performance in pulsed mode at room temperature. Using a strain-compensated bound-to-continuum design emitting near 5.2 mm, we have demonstrated for the first time continuous-wave operation of an external cavity quantum cascade laser on a thermoelectric cooler. The tuning range was comparable to that of pulsed devices, but with a much better side-mode suppression ratio and a much narrower linewidth. This continuous-wave device has successfully been applied to the spectroscopy of nitric oxide in collaboration with Prof. Tittel's Laser Science Group at Rice University. High resolution absorption spectra of that gas could be acquired over a large wavelength range. We also studied heterogeneous cascade structures, that is quan.

The mid-infrared domain is a promising optical domain because it holds two transparency atmospheric windows, as well as the fingerprint of many chemical compounds. Quantum cascade lasers (QCLs) are one of the available sources in this domain and have already been proven useful for spectroscopic applications and free-space communications. This thesis demonstrates how to implement a private free-space communication relying on mid-infrared optical chaos and this requires an accurate cartography of non-linear phenomena in quantum cascade lasers. This private transmission is made possible by the chaos synchronization of two twin QCLs. Chaos in QCLs can be generated under optical injection or external optical feedback. Depending on the parameters of the optical feedback, QCLs can exhibit several non-linear phenomena in addition to chaos. Similarities exist between QCLs and laser diodes when the chaotic dropouts are synchronized with an external modulation, and this effect is known as the entrainment phenomenon. With a cross-polarization reinjection technique, QCLs can generate all-optical square-waves. Eventually, it is possible to trigger optical extreme events in QCLs with tilted optical feedback. All these experimental results allow a better understanding of the non-linear dynamics of QCLs and will extend the potential applications of this kind of semiconductor lasers.

This thesis presents the first comprehensive analysis of quantum cascade laser nonlinear dynamics and includes the first observation of a temporal chaotic behavior in quantum cascade lasers. It also provides the first analysis of optical instabilities in the mid-infrared range. Mid-infrared quantum cascade lasers are unipolar semiconductor lasers, which have become widely used in applications such as gas spectroscopy, free-space communications or optical countermeasures. Applying external perturbations such as optical feedback or optical injection leads to a strong modification of the quantum cascade laser properties. Optical feedback impacts the static properties of mid-infrared Fabry–Perot and distributed feedback quantum cascade lasers, inducing power increase; threshold reduction; modification of the optical spectrum, which can become either single- or multimode; and enhanced beam quality in broad-area transverse multimode lasers. It also leads to a different dynamical behavior, and a quantum cascade laser subject to optical feedback can oscillate periodically or even become chaotic. A quantum cascade laser under external control could therefore be a source with enhanced properties for the usual mid-infrared applications, but could also address new applications such as tunable photonic oscillators, extreme events generators, chaotic Light Detection and Ranging (LIDAR), chaos-based secured communications or unpredictable countermeasures.

Learn how the rapidly expanding area of mid-infrared and terahertz photonics has been revolutionized in this comprehensive overview. State-of-the-art practical applications are supported by real-life examples and expert guidance. Also featuring fundamental theory enabling you to improve performance of both existing and future devices.

This collection of authoritative reviews by leading experts provides a broad and instructive introduction to the most advanced techniques for generating coherent light in the mid-infrared region of the spectrum. With a wealth of up-to-date references – also available online.

Covering fundamental principles and the state of the art, this is a collection of reviews from experts in mid-infrared (mid-IR) coherent sources. Among the sources covered are optical parametric oscillators, difference frequency generators, and the most recent broadband crystalline, quantum cascade, and fiber lasers. The authors show how advances in mid-IR science and technology make these sources indispensable for a variety of applications.

This book describes the physics, fabrication technology, and applications of the quantum cascade laser.

The performance of a rapidly swept external cavity quantum cascade laser (ECQCL) system combined with an open-path Herriott cell was evaluated for time-resolved measurements of chemical species with broad and narrow absorption spectra. A spectral window spanning 1278 - 1390 cm-1 was acquired at a 200 Hz acquisition rate, corresponding to a tuning rate of 2x104 cm-1/s, with a spectral resolution of 0.2 cm-1. The capability of the ECQCL to measure