Aqueous Pretreatment Of Plant Biomass For Biological And Chemical Conversion To Fuels And Chemicals

Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.

This book is focused on the pretreatment of biomass, a necessary step for efficient conversion of the plant cell wall materials to fuels and other products. Pretreatment is required because it is difficult to access, separate, and release the monomeric sugars comprising the biopolymers within the biomass that can be further upgraded to products through chemical processes such as aqueous phase reforming or biological routes such as fermentation of the sugars to ethanol This resistance to degradation or difficulty to release the monomers (mostly sugars) is commonly referred to as recalcitrance. There are many methods to overcome plant recalcitrance, but the underlying cause of the recalcitrance lies in the complex combination of chemical and structural features of the plant cell walls.

Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.

In this book, 15 papers, covering some of the latest advances in pretreatment and bioconversion of crop residues, are presented. Research results dealing with wheat straw, corn stover, sweet sorghum bagasse, hazelnut shells, oil palm empty fruit bunch, olive tree pruning biomass, and other residues of crop harvest and processing are discussed. Pretreatment methods, such as auto-catalyzed and acid-catalyzed hydrothermal processing, steaming, alkaline methods, and different organosolv approaches, are reported. Bioconversion with enzymes and microbes for producing fermentable sugars, xylitol, and biomethane are also included.

This book includes 19 chapters contributed by the world's leading experts on pretreatment methods for biomass. It extensively covers the different types of biomass (e.g. molasses, sugar beet pulp, cheese whey, sugarcane residues, palm waste, vegetable oil, straws, stalks and wood), various pretreatment approaches (e.g. physical, thermal, chemical, physicochemical and biological) and methods that show the subsequent production of biofuels and chemicals such as sugars, ethanol, extracellular polysaccharides, biodiesel, gas and oil. In addition to traditional methods such as steam, hot-water, hydrothermal, diluted-acid, organosolv, ozonolysis, sulfite, milling, fungal and bacterial, microwave, ultrasonic, plasma, torrefaction, pelletization, gasification (including biogas) and liquefaction pretreatments, it also introduces and discusses novel techniques such as nano and solid catalysts, organic electrolyte solutions and ionic liquids. This book offers a review of state-of-the-art research and provides guidance for the future paths of developing pretreatment techniques of biomass for biofuels, especially in the fields of biotechnology, microbiology, chemistry, materials science and engineering. It intends to provide a systematic introduction of pretreatment techniques. It is an accessible reference work for students, researchers, academicians and industrialists in biorefineries. Zhen Fang is a Professor of Bioenergy and the leader and founder of the biomass group at the Xishuangbanna Tropical Botanical Garden of the Chinese Academy of Sciences. He is also an adjunct full Professor of Life Sciences at the University of Science and Technology of China.

A country's vision for developing renewable and sustainable energy resources is typically propelled by three important drivers – security, cost, and environmental impact. The U.S. currently accounts for a quarter of the world’s total oil consumption, with domestic demands necessitating – at an ever growing cost – a net import of more than 50% of the oil used in this country. At the same time, Brazil, because of its forward thinking on energy strategy, is today energy independent. As emerging economies around the world increase their petroleum use by large margins and as large fractions of that new consumption are necessarily supplied from unstable parts of the world, the inevitable repercussions on petroleum-driven economies will continue to escalate. In addition, there is an unequivocal imperative to take immediate and aggressive measures to reduce net greenhouse gas emissions by decreasing fossil fuel consumption and increasing our use of carbon-neutral or carbon-negative fuels as well as improving efficiency of fuel use. Economic growth and development worldwide depend increasingly on secure supplies of reliable, affordable, clean energy. Together with its counterpart societies, was convened the First Pan-American Congress on Plants and BioEnergy, which was held in June, 2008, in Mérida, Mexico. Sponsored by the American Society of Plant Biologists, this congress was designed to initiate Pan-American research collaborations in energy biosciences. At that congress, the organizational committee committed themselves to continue the meeting biennially, resulting in the 2nd Pan-American Congress on Plants and BioEnergy to be held with the endorsement of ASPB, July 6-10, 2010, in São Paulo, Brazil. Whereas the 1st congress covered a broad range of topics that bioenergy impacted, the second congress will focus more on the advances in plant biology: the genetic improvement of energy crop plants, their fit into regional environments, and the development of a sustainable energy agriculture.

Comprehensive resource highlighting the global significance of biogas and reviewing the current status of biogas production. Biogas Plants presents an overview of biogas production, starting from the substrates (characteristics, pretreatment, and storage), addressing technical and technological aspects of fermentation processes, and covering the environmental and agricultural significance of obtained digestate. Written by a team of experts with extensive theoretical and practical experience in the areas of bio-waste, biogas plants, and reduction of greenhouse gas emissions, Biogas Plants discusses keys topics including: Anaerobic digestion, including discussion of substrates and products Advantages of biogas plants, with emphasis on their future potential for stable and controlled renewable energy Global significance of the biogas sector, including its importance in electro-energy system stabilization, biogas plants for energy storage, bio-waste utilization, and biomethane production A thorough and complete resource on the subject, Biogas Plants will appeal to academic researchers and industry scientists and engineers working in the fields of biogas, bio-waste, bioenergy, renewable resources, waste management and carbon reduction, along with process engineers, environmental engineers, biotechnologists, and agricultural scientists. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

The biorefinery, integration of processes and technologies for biomass conversion, demands efficient utilization of all components. Hydrothermal processing is a potential clean technology to convert raw materials such as lignocellulosic and aquatic biomass into bioenergy and high added-value compounds. This book aims to show fundamental concepts and key technological developments that enabled industrial application of hydrothermal processing. The scope of this book is primarily for scientists working in the biorefinery field as well as engineers from industry and potential investors in biofuels. Therefore, the information in this book will provide an overview of this technology applied to lignocellulosic materials and aquatic biomass, and especially new knowledge. Critically, this book brings together experts in the application of hydrothermal processes on lignocellulosic and aquatic biomass.

Bio-butanol has gained wide recognition globally as an advanced biofuel, which can be used directly as a substitute for gasoline in internal combustion engines. This book provides readers with an in-depth knowledge of the various aspects and steps involved in butanol production. Further, the current global status, history, various technologies adopted for butanol production from different feedstocks, and the role of microorganisms in the production process are also covered. The book has 12 chapters, with each chapter dedicated to covering various aspects of butanol, from production to applications.

The book revisit in depth scope of agroindustrial waste for enhancement in biofuels production on practical ground. It explores and discusses various cellulose rich agro-wastes along with low cost, advance technology based options for sustainable biofuels production. Lignocellulosic biomasses are potential producer of biofuels due to renewable nature and huge occurrence. Cellulose is the main polymeric component of these biomasses apart from lignin and hemicellulose. It can be converted into fermentable sugars using cellulase enzyme which can be further converted into the renewable energy sources such as biohydrogen, bioethanol, biogas and butanol. Chapters in this title provide exclusive and critical analysis of specific biofuels production process only from lignocellulosic biomass, based on their type, property, availability, cost and most important sugar or cellulose content along with the simplest process search for converting these biomasses into biofuels to make overall process more simple and economical.It is a useful guide for academician and environmentalist who are working to explore feasible advantages associated with these kinds of waste management and their effective valorization. It is also a great resource for senior undergraduate and graduate students, researchers, professionals, and other interested individuals/groups working in the field of biofuel/bioenergy.